相关论文: Interstellar triply deuterated ammonia
The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…
The formation of deuterated molecules is favoured at low temperatures and high densities. Therefore, the deuteration fraction D$_{frac}$ is expected to be enhanced in cold, dense prestellar cores and to decrease after protostellar birth.…
The binding energies (BE) of molecules on the interstellar grains are crucial in the chemical evolution of the interstellar medium (ISM). Both temperature programmed desorption (TPD) laboratory experiments and quantum chemistry computations…
Surprisingly large column densities of H3+ have been detected using infrared absorption spectroscopy in seven diffuse cloud sightlines (Cygnus OB2 12, Cygnus OB2 5, HD 183143, HD 20041, WR 104, WR 118, and WR 121), demonstrating that H3+ is…
The abundances of deuterated molecules with respect to their main isotopologue counterparts have been determined to be orders of magnitude higher than expected from the cosmic abundance of deuterium relative to hydrogen. The increasing…
The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We…
We investigate the presence of COMs in strongly UV-irradiated interstellar molecular gas. We have carried out a complete millimetre line survey using the IRAM30m telescope towards the edge of the Orion Bar photodissociation region (PDR),…
The first detection of ammonia (NH3) is reported from the Magellanic Clouds. Using the Australia Telescope Compact Array, we present a targeted search for the (J,K) = (1,1) and (2,2) inversion lines towards seven prominent star-forming…
We report experimental and theoretical evidence that solid molecular ammonia becomes unstable at room temperature and high pressures and transforms into an ionic crystalline form. This material has been characterised in both hydrogenated…
The primordial abundance of deuterium (D/H) yields a measure of the density of baryons in the universe and is an important complement to determinations from cosmic microwave background (CMB) experiments. Indeed, the current small sample of…
Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…
Deuterated molecules and their molecular D/H-ratios (RD(D)) are important diagnostic tools to study the physical conditions of star-forming regions. The degree of deuteration, RD(D), can be significantly enhanced over the elemental…
The ammonia (J,K) = (1,1), (2,2), (3,3), and (4,4) transitions at 23.7 -- 24.1 GHz region were searched for in a nearby galaxy Maffei 2 to study relation between molecular abundances and physical conditions in galaxies. The (1,1), (2,2),…
The standard interstellar ratio of deuterium to hydrogen (D/H) atoms is $\sim 1.5 \times 10^{-5}$. However, the deuterium fractionation is in fact found to be enhanced, to different degrees, in cold, dark cores, hot cores around massive…
In this work, we study deuterium fractionation in four starless cores in the low-mass star-forming region L1688 in the Ophiuchus molecular cloud. We study how the deuterium fraction ($R_D$) changes with environment, compare deuteration of…
The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…
Disentangling the different stages of the star-formation process, in particular in the high-mass regime, is a challenge in astrophysics. Chemical clocks could help alleviating this problem, but their evolution strongly depends on many…
We present the results of ammonia observations towards 66 massive star forming regions identified by the Red MSX source survey. We have used the Green Bank Telescope and the K-band focal plane array to map the ammonia NH3 (1,1) and (2,2)…
Understanding gas-grain chemistry of deuterium in star-forming objects may help to explain their history and present state. We aim to clarify how processes in ices affect the deuterium fractionation. In this regard, we investigate a…
This paper is the third in a series reporting on a study of carbon abundances in a carefully chosen sample of planetary nebulae representing a large range in progenitor mass and metallicity. We make use of the IUE Final Archive database…