相关论文: Why Are Verdazyl Radicals Non-Emissive? An Experim…
We have succeeded in synthesizing single crystals of the verdazyl radical beta-2,6-Cl2-V [= beta-3-(2,6-dichlorophenyl)-1,5-diphenylverdazyl]. The ab initio MO calculation indicated the formation of an S = 1/2 Heisenberg antiferromagnetic…
The tris(2,4,6-trichlorophenyl)methyl radical (TTM) has inspired the synthesis of several luminescent diradicals and diradicaloids, providing an extraordinary opportunity to control the nature of the low-lying excited states by fine-tuning…
The nature of electronic excited states has a deep impact on the dynamics of molecular spins, but remains poorly understood and characterized. Here we carry out a thorough multiconfigurational investigation for two prototypical molecular…
We present a model compound that forms a mixed-spin ferromagnetic chain. Our material design, based on the organic radicals, affords a verdazyl-based complex (p-Py-V)2[Mn(hfac)2]. The molecular orbital calculations of the compound indicate…
Tetraphenylpyrazine (TPP) and 2,3,4,5-tetraphenyl-1H-pyrrole (TePP) are closely related heterocycles bearing four phenyl substituents, whose structural similarity makes them a useful pair for comparing how intramolecular flexibility…
We successfully synthesized a verdazyl-based complex, ($m$-Py-V)$_3$[Ni(NO$_3$)$_2$], in which Ni$^{2+}$ ions and verdazyl radicals form a one-dimensional, triangular spin necklace consisting of spin-1/2 and spin-1 units. Molecular orbital…
In this work, we study the driven-dissipative dynamics of a coherently-driven spin ensemble with a squeezed, superradiant decay. This decay consists of a sum of both raising and lowering collective spin operators with a tunable weight. The…
In non-dilute colloidal suspensions, gradients in particle volume fraction result in gradients in electrical conductivity and permittivity. An externally applied electric field couples with gradients in electrical conductivity and…
Selected resonance states of the deuterated formyl radical in the electronic ground state ($\widetilde{X}\,{}^2A'$) are computed using our recently introduced dynamically pruned discrete variable representation (DP-DVR) [H. R. Larsson, B.…
We study gapless quantum spin chains with spin 1/2 and 1: the Fredkin and Motzkin models. Their entangled groundstates are known exactly but not their excitation spectra. We first express the groundstates in the continuum which allows for…
A single measurement of linear polarization of a nonthermal source provides direct information about the mean direction and level of ordering of the magnetic field. Monitoring of the polarization in blazars, combined with millimeter-wave…
An effusive pyrolysis source is described for generating a continuous beam of radicals under conditions appropriate for the helium droplet pick-up method. Rotationally resolved spectra are reported for the $\nu_1$ vibrational mode of the…
In many chemical reactions, short-lived radical intermediates play a crucial role, while detecting such short-lived species in-situ remains challenging. The optically readable electronic spin of nitrogen-vacancy (NV) centers in diamond is a…
Blazar emission is dominated by nonthermal radiation processes that are highly variable across the entire electromagnetic spectrum. Turbulence, which can be a major source of nonthermal particle acceleration, can widely exist in the blazar…
Molecules present a versatile platform for quantum information science, and are candidates for sensing and computation applications. Robust spin-optical interfaces are key to harnessing the quantum resources of materials. To date,…
We theoretically describe the phenomenon of non-adiabatic spin dynamics, which occurs in a gas cell filled by alkali vapor in presence of a strong alternating magnetic field and pump light. Steep increase of the spin polarization occurs if…
We study velocity statistics of electrostatically driven granular gases. For two different experiments: (i) non-magnetic particles in a viscous fluid and (ii) magnetic particles in air, the velocity distribution is non-Maxwellian, and its…
A wide range of physical and biological systems, including colloidal magnets, granular spinners, and starfish embryos, are characterized by strongly rotating units that give rise to odd viscosity and odd elasticity. These active systems can…
In recent years, "composite" density-functional-theory-based methods comprising specially optimized combinations of functionals, basis sets, and empirical corrections have become widely used owing to their robustness and computational…
High-spin molecules allow for bottom-up qubit design and are promising platforms for magnetic sensing and quantum information science. Optical addressability of molecular electron spins has also been proposed in first-row transition metal…