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Constructed to satisfy all known exact constraints and appropriate norms for a semilocal density functional, the strongly constrained and appropriately normed (SCAN) meta-generalized gradient approximation functional has shown early promise…

材料科学 · 物理学 2018-06-26 Eric B. Isaacs , Chris Wolverton

We discuss, simplify, and improve the spin-dependent correction of L.A. Constantin et al., Phys. Rev. B 84, 233103, for atomization energies, and develop a density parameter of the form $v\propto |\nabla n|/n^{10/9}$, found from the…

化学物理 · 物理学 2013-02-01 L. A. Constantin , E. Fabiano , F. Della Sala

The Strongly Constrained and Appropriately Normed (SCAN) functional is a non-empirical meta-generalized-gradient approximation (meta-GGA) functional that satisfies all the known constraints that a meta-GGA functional can, but it also…

材料科学 · 物理学 2020-04-29 Yoh Yamamoto , Alan Salcedo , Carlos M. Diaz , Md Shamsul Alam , Tunna Baruah , Rajendra R. Zope

We investigated the effect of spin polarization on the structural properties and gradient of electric field (EFG) on Sn, In, and Cd impurity in RSn$_3$ (R=Sm, Eu, Gd) and RIn$_3$ (R=Tm, Yb, Lu) compounds. The calculations were performed…

强关联电子 · 物理学 2009-11-13 S. Jalali Asadabadi , H. Akbarzadeh

The ground-state energy, electron density, and related properties of ordinary matter can be computed efficiently when the exchange-correlation energy as a functional of the density is approximated semilocally. We propose the first meta-GGA…

材料科学 · 物理学 2015-06-25 Jianwei Sun , Adrienn Ruzsinszky , John P. Perdew

The prominence of density functional theory (DFT) in the field of electronic structure computation stems from its ability to usefully balance accuracy and computational effort. At the base of this ability is a functional of the electron…

The recently proposed rSCAN functional [J. Chem. Phys. 150, 161101 (2019)] is a regularized form of the SCAN functional [Phys. Rev. Lett. 115, 036402 (2015)] that improves SCAN's numerical performance at the expense of breaking constraints…

材料科学 · 物理学 2020-09-02 James W. Furness , Aaron D. Kaplan , Jinliang Ning , John P. Perdew , Jianwei Sun

The SCAN meta-GGA exchange-correlation functional [Phys. Rev. Lett. 115, 036402 (2015)] is constructed as a chemical environment-determined interpolation between two separate energy densities: one describes single orbital electron densities…

材料科学 · 物理学 2022-02-02 James W. Furness , Aaron D. Kaplan , Jinliang Ning , John P. Perdew , Jianwei Sun

Computationally-efficient semilocal approximations of density functional theory at the level of the local spin density approximation (LSDA) or generalized gradient approximation (GGA) poorly describe weak interactions. We show improved…

The strongly constrained and appropriately normed (SCAN) semilocal density functional [J. Sun, A. Ruzsinszky, J. P. Perdew \textit{Phys. Rev. Lett.} {\bf 115}, 036402 (2015)] obeys all 17 known exact constraints for…

材料科学 · 物理学 2016-09-28 J. G. Brandenburg , J. E. Bates , A. Ruzsinszky , J. Sun , J. P. Perdew

In modeling low-dimensional electronic nanostructures, the evaluation of the electron-electron interaction is a challenging task. Here we present an accurate and practical density-functional approach to the two-dimensional many-electron…

强关联电子 · 物理学 2010-10-29 S. Pittalis , E. Rasanen

We find the recently developed strongly constrained and appropriately normed (SCAN) functional, now widely used in calculations of many materials, is not able to reliably describe the properties of deep defects and small polarons in a set…

材料科学 · 物理学 2024-05-24 Darshana Wickramaratne , John L. Lyons

A spin angular gradient approximation for the exchange correlation magnetic field in the density functional formalism is proposed. The usage of such corrections leads to a consistent spin dynamical approach beyond the local approximation.…

强关联电子 · 物理学 2009-11-07 M. I. Katsnelson , V. P. Antropov

We show an application of the functional-renormalization-group aided density functional theory to the homogeneous electron gas with arbitrary spin polarization, which gives the energy density functional in the local spin density…

强关联电子 · 物理学 2022-01-12 Takeru Yokota , Tomoya Naito

We investigate coherent transport through open lateral quantum dots using recursive Green's function technique, incorporating exchange-correlation effects within local spin-density approximation (LSDA). At low electron densities the current…

介观与纳米尺度物理 · 物理学 2009-11-11 M. Evaldsson , I. V. Zozoulenko

We report tests of various density functionals for ferromagnetic, Fe, Co and Ni with a focus on characterizing the behavior of the so-called strongly constrained and appropriately normed (SCAN) functional. It is found that SCAN is closer in…

强关联电子 · 物理学 2019-07-19 Y. Fu , D. J. Singh

We report a series of calculations testing the predictions of the Tran-Blaha functional for the electronic structure and magnetic properties of condensed systems. We find a general improvement in the properties of semiconducting and…

材料科学 · 物理学 2010-11-08 David J. Singh

The recent major modification, r$^2$SCAN, of the SCAN (strongly constrained and appropriately normed) meta-GGA exchange-correlation functional is shown to give substantially better spin-crossover electronic energies (high spin minus low…

化学物理 · 物理学 2021-01-27 Daniel Mejia-Rodriguez , S. B. Trickey

Spin-orbit coupling induces a current density in the ground state, which consequently requires a generalization for meta-generalized gradient approximations. That is, the exchange-correlation energy has to be constructed as an explicit…

化学物理 · 物理学 2024-05-09 Yannick J. Franzke , Christof Holzer

The negative correlation energy per particle of a uniform electron gas of density parameter $r_s$ and spin polarization $\zeta$ is well known, but its spin resolution into up-down, up-up, and down-down contributions is not. Widely-used…

凝聚态物理 · 物理学 2009-11-10 Paola Gori-Giorgi , John P. Perdew
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