相关论文: Equation of state for the hard sphere fluids
A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first sixteen virial coefficients at the same time as giving very good accuracy when compared with computer…
The well-known Carnahan-Starling (CS) equation of state (EoS) [1] for the hard sphere (HS) fluid was derived from a quadratic relation between the integer portions of the virial coefficients, Bn, and their orders, n. Here we extend the…
The hard sphere system plays a basic role in condensed matter physics and related fields, and equation of state (EoS) is the ultimate solution to its thermodynamic properties (1-3). Dozens of EoSs have been proposed since van der Waals…
Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes…
The asymptotic expansion method is extended by using currently available accurate values for the first ten virial coefficients for hard sphere fluids. It is then used to yield an equation of state for hard sphere fluids, which accurately…
Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial…
Virial coefficients for the two-dimensional hard-disk fluid, when expressed in powers of density relative to maximum close packing, lead to an accurate closed equation-of-state for the equilibrium fluid, analogous to that recently found for…
Although many equations of state of hard-disk fluids have been proposed, none is capable of reproducing the currently calculated or estimated values of the first eighteen virial coefficients at the same time as giving very good accuracy…
A closed virial equation-of-state for the low density fluid phase of hard disks is obtained from the known virial coefficients. The equation exhibits 6-figure accuracy for the thermodynamic (MD) pressure up to the reduced number density ~…
We propose a new semi empirical expression of the virial coefficients for a hard sphere fluid which is valid in the disordered phase over the whole density range. The results are in good agreement with the numerical data and better than…
A new analytical approach to derive an approximate equation of state and the virial coefficients for simple fluids is presented. Starting from the usual expression of the partition function, we first perform a Fourier transformation, and…
New proposals for the equation of state of four- and five-dimensional hard-hypersphere mixtures in terms of the equation of state of the corresponding monocomponent hard-hypersphere fluid are introduced. Such proposals (which are…
We present a new equation of state (EOS) for dense hydrogen/helium mixtures which covers a range of densities from $10^{-8}$ to $10^6$ g.cm$^{-3}$, pressures from $10^{-9}$ to $10^{13}$ GPa and temperatures from $10^{2}$ to $10^{8}$ K. The…
Equations of State (EoS) for fluids have been a staple of engineering design and practice for over a century. Available EoS are based on the fitting of a closed-form analytical expression to suitable experimental data. The underlying…
The equation of state for five-dimensional hard hyperspheres arising as a weighted average of the Percus-Yevick compressibility (3/5) and virial (2/5) equations of state is considered. This Carnahan-Starling-like equation turns out to be…
Wide range equation of state (EOS) for liquid hydrogen is ultimately built by combining two kinds of density functional theory (DFT) molecular dynamics simulations, namely, first-principles molecular dynamics simulations and orbital-free…
Following the work of Leutheusser [Physica A 127, 667 (1984)], the solution to the Percus-Yevick equation for a seven-dimensional hard-sphere fluid is explicitly found. This allows the derivation of the equation of state for the fluid…
The compressibility equation of state for a multicomponent fluid of particles interacting via an infinitely narrow and deep potential, is considered within the mean spherical approximation (MSA). It is shown that for a class of models…
Numerical simulations of compressible fluid flows require an equation of state (EOS) to relate the thermodynamic variables of density, internal energy, temperature, and pressure. A valid EOS must satisfy the thermodynamic conditions of…
An alternative to the well-known complete form of the Mie-Gr\"uneisen equation of state (EOS) for water is suggested. A closed analytical description of the self-consistent EOS for an arbitrary medium based only on the first law of…