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Chiral crystals show promise for spintronic technologies on account of their high spin selectivity, which has led to significant recent interest in quantitative characterization and first-principles prediction of their spin-optoelectronics…

材料科学 · 物理学 2023-12-05 Christian Multunas , Andrew Grieder , Junqing Xu , Yuan Ping , Ravishankar Sundararaman

Chiral perovskites owing to their broken mirror symmetry exhibit selective absorption of circularly polarized light manifesting a strong circular dichroism (CD). CD spectroscopy has been a key technique to understand chiral perovskites and…

材料科学 · 物理学 2026-02-10 Reshna Shrestha , Wanyi Nie

Circular dichroism (CD), arising from spin-selective light-matter interactions controlled by chirality, is critical for advanced applications such as chiral imaging and ultrasensitive biosensing. However, CD of chiral natural materials is…

For the interpretation of spectra of magnetic stellar objects such as magnetic white dwarfs (WDs) highly accurate quantum chemical predictions for atoms and molecules in finite magnetic field are required. Especially the accurate…

化学物理 · 物理学 2024-10-01 Simon Blaschke , Marios-Petros Kitsaras , Stella Stopkowicz

Chiral metal halide perovskites have emerged as promising optoelectronic materials for emission and detection of circular polarized visible light. Despite chirality being realized by adding chiral organic cations or ligands, the chiroptical…

材料科学 · 物理学 2023-09-26 Sofia Apergi , Geert Brocks , Shuxia Tao

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

光学 · 物理学 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

Recently it was demonstrated (Schattschneider et al., Nature 441 (2006), 486), that an analogue of the X-ray magnetic circular dichroism (XMCD) experiment can be performed with the transmission electron microscope (TEM). The new phenomenon…

材料科学 · 物理学 2009-09-29 Jan Rusz , Stefano Rubino , Peter Schattschneider

The question of the correlation between magnetization, band splittings, and magnetic circular dichroism (MCD) in the fundamental gap region of dilute magnetic semiconductors is examined experimentally and theoretically taking the case of…

Topological invariants are crucial quantities for classifying materials with topological phases. Hence, their connections with experimentally measurable quantities are extremely important. In this context, circular dichroism (CD) provides a…

介观与纳米尺度物理 · 物理学 2024-05-27 Ipsita Mandal

Broken symmetry plays a pivotal role in determining the macroscopic electrical, optical, magnetic, and topological properties of materials. Circular dichroism (CD) has been widely employed to probe broken symmetry in various systems, from…

介观与纳米尺度物理 · 物理学 2024-11-14 Shu-Liang Ren , Simin Pang , Shan Guan , Yu-Jia Sun , Tian-Yu Zhang , Nai Jiang , Jiaqi Guo , Hou-Zhi Zheng , Jun-Wei Luo , Ping-Heng Tan , Chao Shen , Jun Zhang

Electronic circular dichroism (ECD) spectroscopy captures the chiroptical response of molecules, enabling absolute configuration assignment that is vital for enantioselective synthesis and drug design. The practical use of ECD spectra in…

量子物理 · 物理学 2026-02-04 Amandeep Singh Bhatia , Sabre Kais

Chirality introduces intriguing topological, electronic, and spin-optronic properties to molecules and solids. In this work, we provide a quantitative metric for the degree of chirality in solids, independent of the type of system and the…

材料科学 · 物理学 2025-09-18 Andrew Grieder , Shihao Tu , Yuan Ping

The ability to differentiate chiral molecules of different handedness is of great importance for chemical and life sciences. Since most of the relevant chiral molecules have their chiral transitions in the UV region, detecting their…

Higher-order electronic transitions of all inorganic lead halide perovskite quantum dots (QDs) (CsPbX$_3$: X = Cl, Br, I) are hardly detected by traditional spectroscopic techniques due to the condensed electronic level of QDs. This work…

材料科学 · 物理学 2023-11-22 Prasenjit Mandal , Ranjani Viswanatha

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

Polarization-dependent photon spectroscopy (dichroism) using signal-enhancing superchiral beams is shown to be sensitive to magnetic properties of the sample, whereas previous investigations explored charge-like electronic properties of…

材料科学 · 物理学 2019-03-06 S. W. Lovesey , J. T. Collins , S. P. Collins

Magnetic Circular Dichroism (MCD) is a standard technique for the study of magnetic properties of materials in synchrotron beamlines. We present here a new scattering geometry in the Transmission Electron Microscope through which MCD can be…

The measurement of circular dichroism (CD) has widely been exploited to distinguish the different enantiomers of chiral structures. It has been applied to natural materials (e.g. molecules) as well as to artificial materials (e.g.…

Chiral molecules show differences in their chemical and optical properties due to different spatial arrangements of the atoms in the two enantiomers. A common way to optically differentiate them is to detect the disparity in the absorption…

Using x-ray photoelectron diffraction (XPD) and angle-resolved photoemission spectroscopy, we study photoemission intensity changes related to changes in the geometric and electronic structure in the kagome metal CsV$_3$Sb$_5$ upon…

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