相关论文: Connections between Richardson-Gaudin States, Perf…

Geminal wavefunctions have been employed to model strongly-correlated electrons. These wavefunctions represent products of weakly-correlated pairs of electrons and reasonable approximations are computable with polynomial cost. In…

Electron pairs have an illustrious history in chemistry, from powerful concepts to understanding structural stability and reactive changes, to the promise of serving as building blocks of quantitative descriptions of the electronic…

The use of exactly-solvable Richardson-Gaudin (R-G) models to describe the physics of systems with strong pair correlations is reviewed. We begin with a brief discussion of Richardson's early work, which demonstrated the exact solvability…

We develop a bivariational principle for an antisymmetric product of nonorthogonal geminals. Special cases reduce to the antisymmetric product of strongly-orthogonal geminals (APSG), the generalized valence bond-perfect pairing (GVB-PP),…

Richardson-Gaudin (RG) states are employed as a variational wavefunction ansatz for strongly correlated isomers of H$_4$ and H$_{10}$. In each case a single RG state describes the seniority-zero sector quite well. Simple natural orbital…

A type of electron pairing model with spin-orbit interactions or Zeeman coupling is solved exactly in the framework of Richardson ansatz. Based on the exact solutions for the case with spin-orbit interactions, it is shown rigorously that…

Wave functions based on electron-pair states provide inexpensive and reliable models to describe quantum many-body problems containing strongly-correlated electrons, given that broken-pair states have been appropriately accounted for by,…

Starting from integrable $su(2)$ (quasi-)spin Richardson-Gaudin XXZ models we derive several properties of integrable spin models coupled to a bosonic mode. We focus on the Dicke-Jaynes-Cummings-Gaudin models and the two-channel…

Seniority-zero geminal wavefunctions are known to capture bond-breaking correlation. Among this class of wavefunctions, Richardson-Gaudin states stand out as they are eigenvectors of a model Hamiltonian. This provides a clear physical…

This chapter gives an overview of Richardson-Gaudin states which represent weakly correlated pairs of electrons. They are parametrized by sets of numbers obtained from non-linear equations. The best method to solve these equations is…

Scalar products and density matrix elements of closed-shell pair geminal wavefunctions are evaluated directly in terms of the pair amplitudes, resulting in an analogue of Wick's theorem for fermions or bosons. This expression is in general…

Numerous numerical studies have shown that geminal-based methods are a promising direction to model strongly correlated systems with low computational costs. Several strategies have been introduced to capture the missing dynamical…

Richardson-Gaudin states provide a basis of the Hilbert space for strongly correlated electrons. In this study, optimal expressions for the transition density matrix elements between Richardson-Gaudin states are obtained with a cost…

Many exactly solvable models are based on Lie algebras. The pairing interaction is important in nuclear physics and its exact solution for identical particles in non-degenerate single-particle levels was first given by Richardson in 1963.…

Geminal wavefunctions, introduced in the late 1950s, have long been recognized for their ability to compactly capture strong electron correlation. Despite their promise, they were historically overshadowed by more computationally efficient…

Single-reference methods such as Hartree-Fock-based coupled cluster theory are well known for their accuracy and efficiency for weakly correlated systems. For strongly correlated systems, more sophisticated methods are needed. Recent…

We construct a $\mathcal{PT}$-symmetric Richardson--Gaudin models for spin-$\tfrac{1}{2}$ systems by deforming the closed integrable Hamiltonian through complex-valued transverse magnetic fields and coupling constants. By defining parity as…

Motivated by recent proposals of correlation induced insensitivity of d-wave superconductors to impurities, we develop a simple pairing theory for these systems for up to a moderate strength of disorder. Our description implements the key…

Strong pairing correlations are responsible for superconductivity and off-diagonal long range order in the two-particle density matrix. The antisymmetrized geminal power wave function was championed many years ago as the simplest model that…

Eigenvectors of the reduced Bardeen-Cooper-Schrieffer Hamiltonian, Richardson-Gaudin (RG) states, are used as a variational wavefunction Ansatz for strongly-correlated electronic systems. These states are geminal products whose coefficients…