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We review different computational methods for the calculation of photoelectron spectra and angular distributions of atoms and molecules when excited by laser pulses using time-dependent density-functional theory (TDDFT) that are suitable…

化学物理 · 物理学 2017-03-28 Philipp Wopperer , Umberto De Giovannini , Angel Rubio

We present a numerical implementation of the time-dependent surface flux (tSURFF) method [New J. Phys. 14, 013021 (2012)], an efficient computational scheme to extract photoelectron energy spectra, to the time-dependent multiconfiguration…

原子物理 · 物理学 2019-08-07 Yuki Orimo , Takeshi Sato , Kenichi L. Ishikawa

Various ways to analyze the dynamical response of clusters and molecules to electromagnetic perturbations exist. Particularly rich information can be obtained from measuring the properties of electrons emitted in the course of the…

原子与分子团簇 · 物理学 2015-06-11 P. Wopperer , P. M. Dinh , P. -G. Reinhard , E. Suraud

The time dependent surface flux (t-SURFF) method is extended to single and double ionization of two electron systems. Fully differential double emission spectra by strong pulses at extreme UV and infrared wave length are calculated using…

原子物理 · 物理学 2014-05-19 Armin Scrinzi

The time-dependent surface flux (t-SURFF) method is introduced for computing of strong-field infrared photo-ionization spectra of atoms by numerically solving the time-dependent Schr\"odinger equation on minimal simulation volumes. The…

计算物理 · 物理学 2015-05-30 Liang Tao , Armin Scrinzi

We present a novel theoretical approach to simulate spin, time and angular-resolved photoelectron spectroscopy (ARPES) from first principles that is applicable to surfaces, thin films, few layer systems, and low-dimensional nanostructures.…

计算物理 · 物理学 2017-01-03 Umberto De Giovannini , Hannes Hübener , Angel Rubio

We theoretically investigate the interaction of near-infrared few cycle laser pulses of moderate intensity with nano-scale metal tips. Macroscopic field enhancement leads to coherent electron emission from the tip apex. Electron spectra are…

介观与纳米尺度物理 · 物理学 2015-03-23 G Wachter , C Lemell , J Burgdörfer

Molecular absorption and photo-electron spectra can be efficiently predicted with real-time time-dependent density-functional theory (TDDFT). We show here how these techniques can be easily extended to study time-resolved pump-probe…

原子与分子团簇 · 物理学 2013-01-10 Umberto De Giovannini , Gustavo Brunetto , Alberto Castro , Jessica Walkenhorst , Angel Rubio

We present a theoretical description of femtosecond laser induced dynamics of the hydrogen molecule and of singly ionised sodium dimers, based on a real-space, real-time, implementation of time-dependent density functional theory (TDDFT).…

凝聚态物理 · 物理学 2007-05-23 Alberto Castro , M. A. L. Marques , Julio A. Alonso , George F. Bertsch , Angel Rubio

Calculating strong-field, momentum-resolved photoelectron spectra (PES) from numerical solutions of the time-dependent Schr\"odinger equation (TDSE) is a very demanding task due to the large spatial excursions and drifts of electrons in…

原子物理 · 物理学 2017-11-21 Volker Mosert , Dieter Bauer

Spectroscopies that probe electronic excitations from core levels into unoccupied orbitals, such as X-ray absorption spectroscopy and electron energy loss spectroscopy, are widely used to gain insight into the electronic and chemical…

材料科学 · 物理学 2022-09-12 Marcus Annegarn , Juhan Matthias Kahk , Johannes Lischner

Time-dependent density functional theory (TDDFT) is a widely used method to investigate electron dynamics under external time-dependent perturbations such as laser fields. In this work, we present a machine learning approach to accelerate…

材料科学 · 物理学 2025-12-02 Karan Shah , Attila Cangi

Time-dependent density-functional theory (TDDFT) is widely used to describe electronic excitations in complex finite systems with large numbers of atoms, such as biomolecules and nanocrystals. The first part of this paper will give a simple…

材料科学 · 物理学 2008-08-15 C. A. Ullrich , V. Turkowski

The theoretical understanding of plasmon behavior is crucial for an accurate interpretation of inelastic scattering diagnostics in many experiments. We highlight the utility of linear-response time-dependent density functional theory…

材料科学 · 物理学 2021-03-17 Kushal Ramakrishna , Attila Cangi , Tobias Dornheim , Andrew Baczewski , Jan Vorberger

Time-dependent density functional theory (TDDFT) is a standard approach for calculating optical excitations of molecules and solids, while ensemble DFT (EDFT) is a promising alternative under development. We introduce ensemble TDDFT…

化学物理 · 物理学 2026-05-22 Kimberly J. Daas , Steven Crisostomo , Kieron Burke

The real-time-propagation formulation of time-dependent density-functional theory (RT-TDDFT) is an efficient method for modeling the optical response of molecules and nanoparticles. Compared to the widely adopted linear-response TDDFT…

材料科学 · 物理学 2019-01-15 Tuomas P. Rossi , Mikael Kuisma , Martti J. Puska , Risto M. Nieminen , Paul Erhart

We formulate a time-dependent density functional theory (TDDFT) in terms of the density matrix to study ultrafast phenomena in semiconductor structures. A system of equations for the density matrix components, which is equivalent to the…

介观与纳米尺度物理 · 物理学 2009-11-13 V. Turkowski , C. A. Ullrich

The real-time electronic dynamics on material surfaces is critically important to a variety of applications. However, their simulations have remained challenging for conventional methods such as the time-dependent density-functional theory…

化学物理 · 物理学 2015-06-16 Rulin Wang , Dong Hou , Xiao Zheng

The energy and the angular distributions of photoelectrons are shown to be tunable by choosing the time and the spatial phase structure of the driving fields. These conclusions are derived from quantum mechanical calculations done within a…

原子物理 · 物理学 2023-03-15 Jonas Wätzel , Johannes Hahn , Jamal Berakdar

Energy transfer processes from a high-intensity ultrashort laser pulse to electrons in simple dielectrics, silicon, diamond, and $\alpha$-quartz are theoretically investigated by first-principles calculations based on time-dependent density…

光学 · 物理学 2019-05-22 Atsushi Yamada , Kazuhiro Yabana
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