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Highly doped Poly(3,4-ethylenedioxythiophene) or PEDOT is a conductive polymer with a wide range of applications in energy conversion due to its ease of processing, optical properties and high conductivity. The latter is influenced by…

介观与纳米尺度物理 · 物理学 2017-01-04 David Gelbwaser-Klimovsky , Semion K. Saikin , Randall H. Goldsmith , Alán Aspuru-Guzik

We study the differences in electrical charge transport dynamics of the conductivity enhancement of poly(3,4-ethylenedioxythiophene) (PEDOT) derivatives under geometrical confinement. The results of polymer blend poly(3,4-ethylene…

材料科学 · 物理学 2022-03-04 Sukanya Das , Anil Kumar , K. S. Narayan

The conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) is one of the most researched materials. The 1980s bipolaron model remains the dominant interpretation of the electronic structure of PEDOT. Recent theoretical studies have…

材料科学 · 物理学 2024-05-01 Ben Craig , Peter Townsend , Carlos Ponce de Leon , Chris Kriton-Skylaris , Denis Kramer

"Secondary doping" in poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) is quite effective and a frequently used method for the conductivity enhancement. This simple approach, the addition of co-solvents to the PEDOT:PSS…

材料科学 · 物理学 2019-09-23 K. Itoh , Y. Kato , Y. Honma , H. Masunaga , A. Fujiwara , S. Iguchi , T. Sasaki

Polydimethylsiloxane (PDMS) is an insulator and it is commonly used in fabrication of micro-structures but there is a need of electrical conductive PDMS. Therefore, this research is mainly focused on producing PDMS nanocomposites with high…

应用物理 · 物理学 2021-05-19 Abuzer Alp Yetisgin , Hazal Sakar , Hakan Bermek , Levent Trabzon

The interaction of double wall carbon nanotubes (DWCNTs) and the conducting polymer poly(3,4-ethylenedioxythiphene/polystyrenesulfonate (PEDOT/PSS) was studied by in-situ Raman spectroelectrochemistry. The mixing of DWCNTs with PEDOT/PSS…

材料科学 · 物理学 2021-07-26 Martin Kalbáč , Ladislav Kavan , Lothar Dunsch

The strikingly different charge transport behaviors in nanocomposites of multiwall carbon nanotubes (MWNTs) and conducting polymer polyethylene dioxythiophene - polystyrene sulfonic acid (PEDOT-PSS) at low temperatures are explained by…

介观与纳米尺度物理 · 物理学 2015-05-28 Paramita Kar Choudhury , S. Ramaprabhu , K. P. Ramesh , Reghu Menon

Conducting polymers have wide technological applications in sensors, actuators, electric and optical devices, solar cells etc. To improve their operational performance, mechanical, thermal, electrical and optical properties, such polymers…

Thermoplastic elastomeric nanocomposites based on poly(trimethylene terephthalate-block-poly(tetramethylene oxide) copolymer (PTT-PTMO) and graphene oxide-Fe3O4 nanoparticle hybrid were prepared by in situ polymerization. Superparamagnetic…

In this work, we investigate the electrical conductivity of carbon nanotubes (CNTs), with a particular focus on the effects of doping. Using a first-principles approach, we study the electronic structure, phonon dispersion, and…

材料科学 · 物理学 2024-08-07 Mina Yoon , German D. Samolyuk , Kai Li , James A. Hayne , Tolga Aytug

In this work, electrically and thermally conductive poly (butylene terephthalate) nanocomposites were prepared by in-situ ring-opening polymerization of cyclic butylene terephthalate (CBT) in presence of a tin-based catalyst. One type of…

材料科学 · 物理学 2016-10-28 S. Colonna , O. Monticelli , J. Gomez , C. Novara , G. Saracco , A. Fina

In the present work, the morphology and the electrical and thermal conduction properties of co-continuous poly(vinylidene fluoride) (PVDF), maleated polypropylene (PPgMA) and multiwall carbon nanotubes (CNT) nanostructured blends are…

应用物理 · 物理学 2019-10-31 Samuele Colonna , Zhidong Han , Alberto Fina

Although strong modulation of interfacial electron concentrations by the relative acidity of surface additives has been suggested, direct observation of corresponding changes in surface conductivity, crucial for understanding the role of…

材料科学 · 物理学 2025-05-21 Gyu Rac Lee , Thomas Defferriere , Jinwook Kim , Han Gil Seo , Yeon Sik Jung , Harry L. Tuller

The fabrication of hybrid materials consisting of nanoporous hosts with conductive polymers is a challenging task, since the extreme spatial confinement often conflicts with the stringent physico-chemical requirements for polymerization of…

Cross-plane electrical and thermal transport in thin films of a conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) stabilized with trifluoromethanesulfonate (OTf) is investigated in this study. We explore their electrical…

材料科学 · 物理学 2022-06-16 K. Kondratenko , D. Guerin , X. Wallart , S. Lenfant , D. Vuillaume

Research on conjugated polymers for thermoelectric applications has made tremendous progress in recent years, which is accompanied by surging interest in molecular doping as a means to achieve the high electrical conductivities that are…

The addition of filler particles to polymer electrolytes is known to increment their ionic conductivity (IC). A detailed understanding of how the interactions between the constituent materials are responsible for the enhancement, remains to…

材料科学 · 物理学 2021-03-19 Andres Villa , Juan Carlos Verduzco , Joseph A. Libera , Ernesto E. Marinero

Vibrational properties of composites based on single-walled carbon nanotubes (SWNTs) and conducting polymers of the type polyaniline (PANI) and poly (3,4-ethylene dioxythiophene) (PEDOT) are reported. For PANI-functionalized SWNTs, the…

材料科学 · 物理学 2009-05-06 S. Lefrant , M. Baibarac , I. Baltog

The possibilities to increase the static conductivity of PVC compared to the initial antistatic level, for PVC plasticate obtained with effective plasticizer - a so called modifier of type A, and partial thermal dehydrochlorination for…

介观与纳米尺度物理 · 物理学 2012-08-22 V. I. Krystob , L. A. Apresyan , D. V. Vlasov , T. D. Vlasova

Conjugated polymers are increasingly used as organic mixed ionic-electronic conductors in electrochemical devices for neuromorphic computing, bioelectronics and energy harvesting. The design of efficient applications relies on high…

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