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We explore the sensitivity of several core-level spectroscopic methods to the underlying atomistic structure by using the water molecule as our test system. We first define a metric that measures the magnitude of spectral change as a…

化学物理 · 物理学 2022-06-22 Johannes Niskanen , Anton Vladyka , Joonas Niemi , Christoph J. Sahle

Directly imaging structural dynamics involving hydrogen atoms by ultrafast diffraction methods is complicated by their low scattering cross-sections. Here we demonstrate that megaelectronvolt ultrafast electron diffraction is sufficiently…

Acid solutions exhibit a variety of complex structural and dynamical features arising from the presence of multiple interacting reactive proton defects and counterions. However, disentangling the transient structural motifs of proton…

化学物理 · 物理学 2018-05-09 Joseph A. Napoli , Ondrej Marsalek , Thomas E. Markland

The total scattering structure factors of pure liquid n-pentanol, pentanal, and 5 of their mixtures, as determined by high energy synchrotron X-ray diffraction experiments, are presented. For the interpretation of measured data, molecular…

Amorphous solids exhibit structural short-range order despite lacking long-range crystalline order, with this structural descriptor found to be important for determining mechanical properties. Nanobeam electron diffraction offers a…

材料科学 · 物理学 2026-05-21 Junjie Wu , Timothy J. Rupert

Ethanol (CH3CH2OH) has been detected in interstellar ices within regions associated with the early stages of star and planet formation. Its solid-phase pathways can lead to diverse conditions that can significantly influence its…

The ExoMol database currently provides comprehensive line lists for modelling the spectroscopic properties of molecules in hot atmospheres. Extending the spectral range of the data provided to ultraviolet (UV) wavelengths brings into play…

地球与行星天体物理 · 物理学 2023-06-08 Jonathan Tennyson , Marco Pezzella , Jingxin Zhang , Sergei N. Yurchenko

Angle-resolved ultraviolet photoemission spectra are interpreted by combining the energetics and spatial properties of the contributing states. One-step calculations are in excellent agreement with new azimuthal experimental data for…

Heterostructures comprising uncoated ZnO and coated with thin layers of Ga$_2$O$_3$ were produced using spin-coating and subsequent hydrothermal processing. X-ray diffraction examination verifies the structural integrity of the synthesized…

材料科学 · 物理学 2025-06-25 Shashi Pandey , Swaroop Ganguly , Alok Shukla , Anurag Tripathi

Atmospheric haze is the leading candidate for the flattening of expolanetary spectra, as it's also an important source of opacity in the atmospheres of solar system planets, satellites, and comets. Exoplanetary transmission spectra, which…

地球与行星天体物理 · 物理学 2018-10-17 Z. Felfli , T. Karman , V. Kharchenko , D. Vrinceanu , J. F. Babb , H. R. Sadeghpour

In this article, visible-to-ultraviolet photon upconversion (UV-UC) by triplet-triplet annihilation in the emission range shorter than 340 nm, which is previously unexplored, is presented and the relevant physicochemical characteristics are…

Recent synthetic studies on the organic molecules tetracene and pentacene have found certain dimers and oligomers to exhibit an intense absorption in the visible region of the spectrum which is not present in the monomer or many…

Evaporation of multicomponent droplets is important in a wide range of applications, albeit complex, and requires a careful investigation. We experimentally and numerically investigate the evaporation characteristics of spherical,…

流体动力学 · 物理学 2024-02-27 Yuki Wakata , Xing Chao , Chao Sun , Christian Diddens

The adsorption structure of the molecular switch azobenzene on Ag(111) is investigated by a combination of normal incidence x-ray standing waves and dispersion-corrected density functional theory. The inclusion of non-local collective…

Transit spectroscopy is a key tool for exoplanet atmospheric characterization. However, transit spectrum observations can be limited by aerosol extinction when gas opacities are weak. The ultraviolet wavelength range contains a variety of…

地球与行星天体物理 · 物理学 2020-06-29 Patrick D. Tribbett , Tyler D. Robinson , Tommi T. Koskinen

We study the analytic structure of partial-wave amplitudes derived from u- and t-channel exchange processes. The latter plays a crucial role in dispersion-theory approaches to coupled-channel systems that model final state interactions in…

高能物理 - 唯象学 · 物理学 2015-07-22 M. F. M. Lutz , E. E. Kolomeitsev , C. L. Korpa

We develop a new method for analytical inversion of binned exoplanet transit spectra and for retrieval of planet parameters. The method has a geometrical interpretation and treats each observed spectrum as a single vector $\vec r$ in the…

地球与行星天体物理 · 物理学 2022-11-16 Konstantin T. Matchev , Katia Matcheva , Alexander Roman

Transient X-ray absorption techniques can measure ultrafast dynamics of the elemental edges in a material or multiple layer junction, giving them immense potential for deconvoluting concurrent processes. However, the interpretation of the…

材料科学 · 物理学 2021-06-10 Hanzhe Liu , Isabel M. Klein , Jonathan M. Michelsen , Scott K. Cushing

We present large-scale density-functional theory (DFT) calculations and temperature programmed desorption measurements to characterize the structural, energetic and vibrational properties of the functionalized molecular switch…

1T'-TaTe2 exhibits an intriguing first-order structural phase transition at around 170 K. Understanding the electronic structural properties is a crucial way to comprehend the origin of the structural phase transition. We performed a…

强关联电子 · 物理学 2022-02-23 T. C. Hu , Q. Wu , Z. X. Wang , L. Y. Shi , Q. M. Liu , L. Yue , S. J. Zhang , R. S. Li , X. Y. Zhou , S. X. Xu , D. Wu , T. Dong , N. L. Wang
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