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It is demonstrated that the substances with small difference in the free energies of the ferroelectric and antiferroelectric phases possess a set of properties characteristic for the so-called "dipole glasses". Possible phase diagrams of…

材料科学 · 物理学 2010-07-05 V. M. Ishchuk , V. L. Sobolev

Numerous measurements of the dielectric constant $\epsilon$ of the recently discovered ferroelectric nematic ($N_F$) liquid crystal (LC) phase report extraordinarily large values of $\epsilon^\prime$ (up to ~30,000). We show that what is in…

软凝聚态物质 · 物理学 2024-02-26 Noel A. Clark , Xi Chen , Joseph E. Maclennan , Matthew A. Glaser

Recently discovered ferroelectric nematic (NF) liquid crystals are fluids with a polar orientational order. The electric polarization vector can be aligned by an electric field and by surface anchoring. Here, we explore how the polarization…

软凝聚态物质 · 物理学 2026-02-27 Ashish Chandra Das , Sathyanarayana Paladugu , Oleg D. Lavrentovich

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

软凝聚态物质 · 物理学 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle

Herein we report the first examples of reactive mesogenic materials (RMs) which exhibit fluid ferroelectric order based on the recently discovered ferroelectric nematic (NF) phase. We term these materials NF RMs and they provide the first…

材料科学 · 物理学 2025-04-25 Stuart R Berrow , Jordan Hobbs , Calum J Gibb

Monte Carlo simulations are used to examine cooperative creation of polar state in fluids of two-state particles with nonzero dipole in the excited state. With lowering temperature such systems undergo a second order transition from…

软凝聚态物质 · 物理学 2009-11-11 Dmitry V. Matyushov , Andriy Okhrimovskyy

A transition in a spheroidal particle from the paraelectric to the ferroelectric phase as well as dynamic susceptibility are studied without approximation in the paraphase. It is assumed that the surface charge is compensated and the…

材料科学 · 物理学 2008-07-22 O. Hudak

The rare-earth chromates (RECrO$_3$) and manganites (REMnO$_3$) where, RE = Eu, Y, Dy, Ho, Gd are constantly under scrutiny in search of room temperature magnetoelectric multiferroics. However, the artefacts and undesirable signal in some…

The recent discoveries of ferroelectric metal and Weyl semimetal (WSM) have stimulated a natural question: whether these two exotic states of matter can coexist in a single material or not. These two discoveries ensure us that physically it…

Ferroelectric nematic fluids are promising materials for tunable nonlinear photonics, with applications ranging from second harmonic generation to sources of entangled photons. However, the few reported values of second-order…

During the last half-decade, a new class of ferroic-fluid, ferroelectric nematic liquid crystals (NFLCs), creates a noise owing to its exceptional properties such as a colossal polarization, high electro-optic activity plus high fluidity.…

Ferroelectricity is usually found in compound materials composed by different elements. Here, based on first-principles calculations, we reveal the first example of spontaneous electrical polarization and ferroelectricity in stable…

材料科学 · 物理学 2017-06-20 Chengcheng Xiao , Fang Wang , Shengyuan A. Yang , Yunhao Lu

A dielectric nonlinear response in model two-phase composites, prepared from a displacive ferroelectric material with a dominant dielectric response due to a single oscillator ferroelectric mode and a dielectric material, is characterized…

材料科学 · 物理学 2018-06-26 Matej Hudak , Jana Tothova , Ondrej Hudak

Ferroelectric nematic phases are a new class of polar fluids in which spontaneous polarization is directly coupled to the orientational order, providing unique opportunities for creating self-organized materils with spatially modulated…

Electronic electro-optic (EEO) phase modulation is a key emerging technology for the chip-scale inter-conversion of signals between the electronic and photonic domains. The recent discovery of the ferroelectric nematic ($N_F$) liquid…

Comprehensive review of investigations of substances with a small difference in the energies of the ferroelectric and antiferroelectric types of dipole ordering is presented. Detailed analysis of the stability of homogeneous phases and…

材料科学 · 物理学 2018-01-11 V. M. Ishchuk , V. L. Sobolev

Antiferroelectricity is a material property characterized by alternating electric dipoles spontaneously ordered in antiparallel directions. Antiferroelectrics are promising for energy storage, solid-state cooling, and memory technologies;…

We identify a first-order, isosymmetric transition between a ferrielectric (FiE) and ferroelectric (FE) state in $A$-site ordered LaScO$_{3}$/BiScO$_{3}$ and LaInO$_{3}$/BiInO$_{3}$ superlattices. Such a previously unreported ferroic…

材料科学 · 物理学 2013-09-11 Gaoyang Gou , James M. Rondinelli

Sr_(9-x)PbxCe2Ti12O36 system is derived from the perovskite SrTiO3 and its chemical formula can be written as (Sr_(1-y)Pby)0.75Ce0.167TiO3. We investigated dielectric response of Sr_(9-x)PbxCe2Ti12O36 ceramics (x = 0-9) between 100 Hz and…

Collinear dipole orders such as ferroelectricity and antiferroelectricity have developed rapidly in last decades. While, the noncollinear dipole orders are rarely touched in solids. Noncollinear dipole orders can provide a route to realize…

材料科学 · 物理学 2024-11-01 Xinyu Yang , Jun Chen , Shan-Shan Wang , Shuai Dong