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Adding porosity to battery electrodes is believed to be universally useful for adding space to accommodate volumetric expansion, electrolyte access to all active materials, helping to mitigate poor C-rate performance for thicker electrodes…

应用物理 · 物理学 2020-08-26 Sally O'Hanlon , David McNulty , Ruiyuan Tian , Jonathan Coleman , Colm O'Dwyer

We report a neutral salt water based battery which uses p-type and n-type solution processed polymer films as the cathode and the anode of the cell. The specific capacity of the electrodes (approximately 30 mAh cm-3) is achieved via…

The absence of piezoelectricity in silicon makes direct electro-mechanical applications of this mainstream semiconductor impossible. Integrated electrical control of the silicon mechanics, however, would open up new perspectives for on-chip…

Nanopositioning techniques currently applied to characterize physical properties of materials interesting for applications at the microscopic scale rely on high-voltage electronic control circuits that should have the lowest possible noise…

仪器与探测器 · 物理学 2014-09-12 Cristian H. Belussi , Mariano Gómez Berisso , Yanina Fasano

Silicon anodes promise high energy densities of next-generation lithium-ion batteries, but suffer from shorter cycle life. The accelerated capacity fade stems from the repeated fracture and healing of the solid-electrolyte interphase (SEI)…

化学物理 · 物理学 2022-12-01 Lars von Kolzenberg , Arnulf Latz , Birger Horstmann

Nanoporosity in silicon results in an interface-dominated mechanics, fluidics and photonics that are often superior to the ones of the bulk material. However, their active control, e.g. as a response to electronic stimuli, is challenging…

材料科学 · 物理学 2022-11-29 Manuel Brinker , Patrick Huber

The recent geopolitical crisis resulted in a gas price surge. Although lithium-ion batteries represent the best available rechargeable battery technology, a significant energy and power density gap exists between LIBs and petrol/gasoline.…

计算工程、金融与科学 · 计算机科学 2023-09-06 Dibakar Datta

Several active areas of research in novel energy storage technologies, including three-dimensional solid state batteries and passivation coatings for reactive battery electrode components, require conformal solid state electrolytes. We…

The practical use of nanoparticle superlattices (NPSLs) which are of great interest as materials with designed functionalities is often limited by their lack of structural stability under various utilization conditions. Here, we report a…

材料科学 · 物理学 2018-11-09 Shin-Hyun Kang , Min-Jae Lee , Jeeun Lee , Jun-Ki Lee , Min Gyu Kim , Sung-Min Choi

It is shown that porous spherical particles can be obtained via the freezing of silica nanoparticle aqueous suspensions emulsified in a continuous oil phase. After two freeze-thaw cycles, nanoparticles turn aggregated into flocculated…

软凝聚态物质 · 物理学 2020-05-26 Mathieu Nespoulous , Mickaël Antoni , Carine Chassigneux , Renaud Denoyel

Searching for efficient and high-performance cathode materials for rechargeable magnesium ion batteries (RMBs) is urgent for exploring sustainable energy technologies. However, the majority of cathode materials for RMBs usually suffer from…

材料科学 · 物理学 2021-01-12 Qin Zhang , Yaobo Hu , Jun Wang , Yuanxiao Dai , Fusheng Pan

Sodium ion batteries (SIBs) are considered as an efficient alternative for lithium-ion batteries (LIBs) owing to the natural abundance and low cost of sodium than lithium. In this context, the anode materials play a vital role in…

This study examines the distribution and evolution of lithium in both anode and cathode materials of commercial lithium-ion coin cells subjected to high C-rate cycling, providing insights into the mechanisms of lithium loss, trapping, and…

Polymer electrolytes present a promising solution to the challenges posed by aqueous electrolytes in energy storage systems, offering the flexibility needed for wearable electronics. Despite the increasing interest in polymer…

材料科学 · 物理学 2025-05-06 Roya Rajabi , Shichen Sun , Booker Wu , Jamil Khan , Kevin Huang

Enabling lithium (Li)-ion batteries with higher energy densities, longer cycle life, and lower costs will underpin the widespread electrification of the transportation and large-scale energy storage industries. Nickel (Ni)-rich layered…

A convenient method has been developed to thin electron beam fabricated Silicon nanopillars under controlled surface manipulation by transforming the surface of the pillars to an oxide shell layer followed by the growth of sacrificial…

介观与纳米尺度物理 · 物理学 2015-12-29 S Kalem , P Werner , B Nilsson , V G Talalaev , M Hagberg , O Arthursson , U Sodervall

We develop a generalized grand canonical potential for the ballistic nonequilibrium electron distribution in a metal nanowire with a finite applied bias voltage. Coulomb interactions are treated in the self-consistent Hartree approximation,…

介观与纳米尺度物理 · 物理学 2008-07-09 C. -H. Zhang , J. Bürki , C. A. Stafford

It is generally believed that silicon-based anodes for Li-ion batteries would benefit from stronger binders, as cyclic volume changes would not disrupt the cohesion of the composite electrode. Here, we put this belief to the proof by…

Nanostructured electrodes with voids or interconnected pores accommodate large volume changes, shorten ion diffusion pathways, and enhance the structural reversibility of alloying electrodes. While these nanoporous features improve the…

Density-functional-theory (DFT) calculations have been performed on the Li-Si and Li-Ge systems. Lithiated Si and Ge, including their metastable phases, play an important technological r\^ole as Li-ion battery (LIB) anodes. The calculations…

材料科学 · 物理学 2015-06-18 Andrew J. Morris , C. P. Grey , C. J Pickard