相关论文: Revealing Actual Viscoelastic Relaxation Times in …
Measurements of the capillary-driven thinning and breakup of fluid filaments are widely used to extract extensional rheological properties of complex materials. For viscoelastic (e.g., polymeric) fluids, the determination of the longest…
The viscoelastic relaxation time of a polymer solution is often measured using Capillary Breakup Extensional Rheometry (CaBER) where a droplet is placed between two plates which are pulled apart to form a thinning filament. For a slow plate…
Surface tension-driven flow techniques have recently emerged as an efficient means of shedding light into the rheology of thin polymer films. Motivated by experimental and theoretical approaches in films bearing a varying surface…
The deformation and break-up of Newtonian/viscoelastic droplets are studied in confined shear flow. Our numerical approach is based on a combination of Lattice-Boltzmann models (LBM) and finite difference schemes, the former used to model…
We propose a novel device capable of measuring the relaxation time of viscoelastic fluids as small as 1\,ms. In contrast to most rheometers, which by their very nature are concerned with producing viscometric or nearly-viscometric flows,…
The process of phase separation in elastic solids and viscous fluids is of fundamental importance to the stability and function of soft materials. We explore the dynamics of phase separation and domain growth in a viscoelastic material such…
In this experimental and numerical study, we revisit the question of the onset of the elastic regime in viscoelastic pinch-off. This is relevant for all modern filament thinning techniques which aim at measuring the extensional properties…
The stretching of viscoelastic polymer solutions close to break-up can create attached drops on a filament, whose properties and dynamics are little understood. The stretching of capillary bridges and the consecutive filament, until its…
The relaxation modulus of a viscoelastic fluid can be decomposed into multiple Maxwell models and characterized by the relaxation spectrum for the relaxation time. It is empirically known that the logarithmic relaxation time is useful to…
We numerically investigate viscoelastic phase separation in polymer solutions under shear using a time-dependent Ginzburg-Landau model. The gross variables in our model are the polymer volume fraction and a conformation tensor. The latter…
The viscoelastic behavior of liquid polymers changes depending on the microstructure of the polymer chains. To investigate the unsteady structural changes induced by polymer chain morphology under stress, we develop a simple rheo-optical…
The effects of elasticity on filament thinning and breakup are investigated in microchannel cross flow. When a viscous solution is stretched by an external immiscible fluid, a low 100 ppm polymer concentration strongly affects the breakup…
We study the capillary wave dynamics of a single viscoelastic supported film and of a double layer of immiscible viscoelastic supported films. Using both simple scaling arguments and a continuum hydrodynamic theory, we investigate the…
Experimental results from mechanical viscoelastic as well as dielectric relaxation times were compared to theoretical expectations utilizing polymer scaling theory. Viscoelastic relaxation of a hydrogel at 33% relative humidity fabricated…
We investigate a variety of different polymer solutions in shear and elongational flow. The shear flow is created in the cone-plate-geometry of a commercial rheometer. We use capillary thinning of a filament that is formed by a polymer…
We investigate the rheological characteristics of human blood plasma in shear and elongational flows. While we can confirm a Newtonian behavior in shear flow within experimental resolution, we find a viscoelastic behavior of blood plasma in…
We carry out overdamped simulations in a simple model of jamming - a collection of bi-disperse soft core frictionless disks in two dimensions - with the aim to explore the finite size dependence of different quantities, both the relaxation…
We studied experimentally the breakup of liquid bridges made of aqueous solutions of Poly(acrylic acid) between two separating solid surfaces with freely moving contact lines. For polymer concentrations higher than a certain threshold…
We study relaxation and rheology of dense athermal suspensions of frictionless particles close below the jamming density. Our key quantity, the relaxation time---determined from the exponential decay of the energy after the shearing has…
The progressive onset of slip at the wall, which corresponds to a slip length increasing with the solicitation time before reaching a plateau, has been investigated for model viscoelastic polymer solutions, allowing one to vary the longest…