相关论文: Monitorization of the H-O Bond Flexibility

The nature of the phonon triplet in the region of OH-stretching modes in hydrogen-bonded materials is often explained by the interplay of OH-stretching modes and combinations and overtones of OH-bending modes. In order to elucidate the both…

We consider how the infrared intensity of an O-H stretch in a hydrogen bonded complex varies as the strength of the H-bond varies from weak to strong. We obtain trends for the fundamental and overtone transitions as a function of…

Phonon dynamics, charge response and the phonon density of states are calculated for the high-temperature superconductors HgBa$_{2}$CuO$_{4}$ and Bi$_{2}$Sr$_{2}$CuO$_{6}$ within a microscopic model for the electronic density response. The…

The properties of the hydrogen bonds in ethylammonium nitrate are analyzed by using molecular dynamics simulations and infrared as well as nuclear magnetic resonance experiments. Ethylammonium nitrate features a flexible three-dimensional…

Hydrogen bonding plays a crucial role in biology and technology, yet it remains poorly understood and quantified despite its fundamental importance. Traditional models, which describe hydrogen bonds as electrostatic interactions between…

The effect of gravity and proper acceleration on the frequency spectrum of an optical resonator - both rigid or deformable - is considered in the framework of general relativity. The optical resonator is modeled either as a rod of matter…

We consider a polaron model where molecular \emph{rotations} are important. Here, the usual hopping between neighboring sites is affected directly by the electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This model…

Longitudinal optical phonons with oxygen character were measured in La_0.7Sr_0.3MnO_3 by inelastic neutron scattering in the (1 0 0) cubic direction and results were compared with shell model predictions. Measurements were performed in…

We predict a possible phonon softening instability in strongly correlated coupled semiconductor bilayer systems. By studying the plasmon-phonon coupling in coupled bilayer structures, we find that the renormalized acoustic phonon frequency…

The phonon spectral function of the one-dimensional Holstein model is obtained within weak and strong-coupling approximations based on analytical self-energy calculations. The characteristic excitations found in the limit of small…

Coupling between tuneable broadband modes of an array of plasmonic metamolecules and a vibrational mode of carbonyl bond of poly(methyl methacrylate) is shown experimentally to produce a Fano resonance, which can be tuned in situ by varying…

The simplicity of a question such as wondering if correlations characterize or not a certain system collides with the experimental difficulty of accessing such information. Here we present a low demanding experimental approach which refers…

Phonon drag may be harnessed for thermoelectric generators and devices. Here, we demonstrate the geometric control of the phonon-drag contribution to the thermopower. In nanometer-thin electrically conducting $\beta$-Ga$_2$O$_3$ films…

In the setting of nonstandard analysis we introduce the notion of flexible sequence. The terms of flexible sequences are external numbers. These are a sort of analogue for the classical \emph{O$ (\cdot ) $} and \emph{o$ (\cdot ) $} notation…

There are views prevalent in the noncovalent chemistry literature that i) the O atom in molecules cannot form a chalcogen bond, and ii) if formed, this bond is very weak. We have shown in this study that these views are not necessarily true…

Coherent and squeezed phonon oscillations can be excited in solids impulsively by a single femtosecond pulse whose duration is shorter that a phonon period. By applying the second ultrafast pump pulse these oscillations can be…

An understanding of spin excitations in cuprates is essential since the mechanism of high-T$_C$ superconductivity might be linked to spin fluctuations. Band calculations for long "1-dimensional" unit cells of La$_2$CuO$_4$ show that the…

A new method for examining the possible space-time variation of the fine structure constant ($\alpha$) is proposed. The technique uses a relatively simple measurement with an optical resonator to compare atom-stabilized optical frequency…

We extend a tight-binding total energy method to include f-electrons, and apply it to the study of the structural and elastic properties of a range of elements from Be to U. We find that the tight-binding parameters are as accurate and…

In hydrogenated amorphous silicon oxide (a-SiO:H) films, incorporation of oxygen enhances optical gap due to a large number of St-O-Si bond formation, which lies deep into valence band states. An induction effect of this Si-O on other bonds…