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Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…

物理教育 · 物理学 2015-06-26 Clinton D. Stoner

The photosystem II reaction center (PSII-RC) performs the primary energy conversion steps of oxygenic photosynthesis. While the PSII-RC has been studied extensively, the similar timescales of energy transfer and charge separation, and the…

Accurate characterization of entropy plays a pivotal role in capturing reversible and irreversible heating in supercapacitors during charging/discharging cycles. However, numerical methods that can faithfully capture entropy variation in…

数值分析 · 数学 2024-09-17 Jie Ding , Xiang Ji , Shenggao Zhou

Image enhancement methods often prioritize pixel level information, overlooking the semantic features. We propose a novel, unsupervised, fuzzy-inspired image enhancement framework guided by NSGA-II algorithm that optimizes image brightness,…

计算机视觉与模式识别 · 计算机科学 2025-05-19 Nirjhor Datta , Afroza Akther , M. Sohel Rahman

Understanding the water oxidation mechanism in Photosystem II (PSII) stimulates the design of biomimetic artificial systems that can convert solar energy into hydrogen fuel efficiently. The Sr2+ substituted PSII is active but slower than…

材料科学 · 物理学 2021-05-27 Muhamed Amin , Divya Kaur , M. R. Gunner , Gary Brudvig

The plant light-harvesting pigment-protein complex LHCII is the major antenna sub-unit of PSII and is generally (though not universally) accepted to play a role in photoprotective energy dissipation under high light conditions, a process…

分子网络 · 定量生物学 2023-07-27 Callum Gray , Lekshmi Kailas , Peter G. Adams , Christopher D. P. Duffy

A non-trivial interplay between quantum coherence and dissipative environment-driven dynamics is becoming increasingly recognised as key for efficient energy transport in photosynthetic pigment-protein complexes, and converting these…

量子物理 · 物理学 2013-03-19 M. del Rey , A. W. Chin , S. F. Huelga , M. B. Plenio

Entropy is a central concept in physics, but can be challenging to calculate even for systems that are easily simulated. This is exacerbated out of equilibrium, where generally little is known about the distribution characterizing simulated…

统计力学 · 物理学 2024-05-09 Samuel D. Gelman , Guy Cohen

The excess work required to drive a stochastic system out of thermodynamic equilibrium through a time-dependent external perturbation is directly related to the amount of entropy produced during the driving process, allowing excess work and…

统计力学 · 物理学 2021-03-15 Steven J Large , Jannik Ehrich , David A Sivak

We theoretically analyze the Photosystem II reaction center using a quantum master equation approach, where excitonic and charge-transfer rates are computed at the Redfield and F\"orster levels with realistic spectral densities. The focus…

化学物理 · 物理学 2025-07-08 Trishna Kalita , Manash Jyoti Sarmah , Javed Akhtar , Himangshu Prabal Goswami

We derive the expressions of photon energy and particle currents inside an open nanosystem interacting with light using non-equilibrium Green's functions. The model allows different temperatures for the electron reservoirs, which basically…

介观与纳米尺度物理 · 物理学 2017-04-05 Fabienne Michelini , Adeline Crépieux , Katawoura Beltako

We examine computational techniques and methodologies currently in use to explore electronic excitation energy transfer in the context of light-harvesting complexes in photosynthetic antenna systems, and comment on some new insights into…

化学物理 · 物理学 2012-07-05 Leonardo A. Pachon , Paul Brumer

Photosystem II is crucial for life on Earth as it provides oxygen as a result of photoinduced electron transfer and water splitting reactions. The excited state dynamics of the photosystem II-reaction center (PSII-RC) has been a matter of…

化学物理 · 物理学 2022-10-12 Yusuke Yoneda , Eric A. Arsenault , Kaydren Orcutt , Masakazu Iwai , Graham R. Fleming

Giant strides in ultrashort laser pulse technology have enabled real-time observation of dynamical processes in complex molecular systems. Specifically, the discovery of oscillatory transients in the two-dimensional electronic spectra of…

化学物理 · 物理学 2021-03-08 Akihito Ishizaki , Graham R. Fleming

On the one hand, the dissipated heat of a thermodynamic work extraction process upper bounds the non-predictive information, which the associated system encodes about its environment. Thus, emergent information processing capabilities can…

神经元与认知 · 定量生物学 2020-09-10 Kai Ueltzhöffer

Frequency up-conversion of few low-energy photons into a single high-energy photon, greatly contributes to imaging, light sources, detection and other fields of research. However, it offers negligible efficiency when up-converting many…

光学 · 物理学 2013-06-11 Assaf Manor , Nimrod Kruger , Carmel Rotschild

In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution $p$…

统计力学 · 物理学 2022-11-22 Artemy Kolchinsky , David H. Wolpert

Photosystem 0 concerns a primitive mechanism for free energy gain as ATP from fluctuating light during early evolution. The PS0 reaction centers had no reducing power: charge transport was only temporary. Light induced within the reaction…

生物物理 · 物理学 2007-05-23 Anthonie W. J. Muller

A p-n junction maintained at above ambient temperature can work as a heat engine, converting some of the supplied heat into electricity and rejecting entropy by interband emission. Such thermoradiative cells have potential to harvest…

材料科学 · 物理学 2016-11-16 Wei-Chun Hsu , Jonathan K. Tong , Bolin Liao , Yi Huang , Svetlana V. Boriskina , Gang Chen

This thesis focuses on three fundamental aspects of biological systems; namely, entropy production, Bayesian mechanics, and the free-energy principle. The contributions are threefold: 1) We compute the entropy production for a greater class…

数学物理 · 物理学 2024-10-16 Lancelot Da Costa