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Electrides are ionic crystals with electrons acting as anions occupying well-defined lattice sites. These exotic materials have attracted considerable attention in recent years for potential applications in catalysis, rechargeable…

材料科学 · 物理学 2025-06-06 Chang Liu , Mahfuza Mukta , Byungkyun Kang , Qiang Zhu

Electrides, with their excess electrons distributed in crystal cavities playing the role of anions, exhibit a variety of unique electronic and magnetic properties. In this work, we employ the first-principles crystal structure prediction to…

材料科学 · 物理学 2019-03-06 Sheng-cai Zhu , Lei Wang , Jing-yu Qu , Jun-jie Wang , Timofey Frolov , Xing-Qiu Chen , Qiang Zhu

We have investigated the electronic structure and the Fermi surface of SnO using density functional theory (DFT) calculations within recently proposed exchange-correlation potential (PBE+mBJ) at ambient conditions and high pressures up to…

材料科学 · 物理学 2015-05-28 J. A. McLeod , A. V. Lukoyanov , E. Z. Kurmaev , L. D. Finkelstein , A. Moewes

Recent discoveries of topological phases realized in electronic states in solids have revealed an important role of topology, which ubiquitously appears in various materials in nature. Many well-known materials have turned out to be…

材料科学 · 物理学 2018-09-14 Motoaki Hirayama , Satoru Matsuishi , Hideo Hosono , Shuichi Murakami

Two-dimensional (2D) electrides are a new concept material in which anionic electrons are confined in the interlayer space between positively charged layers. We have performed angle-resolved photoemission spectroscopy measurements on…

Electrides are unique compounds where most of the electrons reside at interstitial regions of the crystal behaving as anions, which strongly determines its physical properties. Interestingly, the magnitude and distribution of interstitial…

超导电性 · 物理学 2019-03-11 Ziyuan Zhao , Shoutao Zhang , Tong Yu , Haiyang Xu , Aitor Bergara , Guochun Yang

Electrides, with excess anionic electrons confined in their empty space, are promising for uses in catalysis, nonlinear optics and spin-electronics. However, the application of electrides is limited by their high chemical reactivity with…

材料科学 · 物理学 2023-01-03 Xuhui Yang , Kevin Parrish , Yan-Ling Li , Baisheng Sa , Hongbing Zhan , Qiang Zhu

Two-dimensional (2D) semiconductors are promising for low-power complementary metal oxide semiconductor (CMOS) electronics, which require ultrathin n- and p-type transistor channels. Among 2D semiconductors, WS2 is expected to have good…

Unusually large spontaneous and piezoelectric fields in the III-V nitrides have led to the making of an entirely new class of two-dimensional electron gas. Fluctuation from a perfectly periodic binary structure in highly polar semiconductor…

材料科学 · 物理学 2009-10-31 Debdeep Jena , Arthur. C. Gossard , Umesh. K. Mishra

Electrides are ionic crystals in which the electrons prefer to occupy free space, serving as anions. Because the electrons prefer to be in the pockets, channels, or layers to the atomic orbitals around the nuclei, it has been challenging to…

Boosting superconductivity by metallic reservoirs is the essence of Kivelson's bilayer proposal. One layer provides pairing to the electrons, while the weakly coupled metal provides additional phase coherence to those pairs by mediating…

Based on first-principles calculations and symmetry analysis, we report that the three-dimensional (3D) nodal line (NL) semimetal phases can be realized in the lead dioxide family (\emph{$\alpha$}-PbO$_2$ and \emph{$\beta$}-PbO$_2$) and its…

材料科学 · 物理学 2018-08-01 Run-Wu Zhang , Cheng-Cheng Liu , Da-Shuai Ma , Maoyuan Wang , Yugui Yao

Oxide electronics provide the key concepts and materials for enhancing silicon-based semiconductor technologies with novel functionalities. However, a basic but key property of semiconductor devices still needs to be unveiled in its oxidic…

The recent discovery of 2D superconductivity at the interface of BaPbO$_3$ (BPO) and BaBiO$_3$ (BBO) has motivated us to study in depth the electronic and structural properties and the relation between them in this particular…

超导电性 · 物理学 2021-05-26 S. Di Napoli , C. Helman , A. M. Llois , V. Vildosola

Oxide two-dimensional electron gases (2DEGs) promise high charge carrier concentrations and low-loss electronic transport in semiconductors such as BaSnO$_{3}$ (BSO). ACBN0 computations for BSO/SrNbO$_{3}$ (SNO) interfaces show…

材料科学 · 物理学 2022-06-27 Sharad Mahatara , Suresh Thapa , Hanjong Paik , Ryan Comes , Boris Kiefer

Experimentally, it is known that lithium undergoes a metal to semiconductor transition at about 80 GPA and a reentrant semiconductor to metal transition near 120 GPA. This unusual behaviour has been attributed to the formation of…

材料科学 · 物理学 2018-05-23 Mauricio A. Flores , Gonzalo Gutiérrez

In bilayer systems electron-hole (e-h) pairs with spatially separated components (i.e., with electrons in one layer and holes in the other) can be condensed to a superfluid state when the temperature is lowered. This article deals with the…

介观与纳米尺度物理 · 物理学 2015-05-28 A. I. Bezuglyj , S. I. Shevchenko

Interfaces between transition-metal oxides are able to host two-dimensional electron gases (2DEGs) and exhibit exotic quantum phenomena. Here we report the observation of superconductivity below 230 mK for the heterostructure composed of…

The electronic properties of polycrystalline lead oxide consisting of a network of single-crystalline $\alpha$-PbO platelets and the formation of the native point defects in $\alpha$-PbO crystal lattice are studied using first principles…

材料科学 · 物理学 2015-06-11 J. Berashevich , O. Semeniuk , O. Rubel , J. A. Rowlands , A. Reznik

We present research results on the electronic transport in heterostructures based on p-type nickel oxide (NiO) with the n-type oxide semiconductors zinc oxide (ZnO) and cadmium oxide (CdO). NiO is a desirable candidate for application in…

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