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Inspired by the high critical temperature in yttrium superhydride and the low stabilized pressure in superconducting cerium superhydride, we carry out four independent runs to synthesize yttrium-cerium alloy hydrides. The phases examined by…

We comment on a recent paper published by McWilliams et al claiming that high-pressure/high-temperature hydrogen is a semi-conductor or semi-metal, in conflict with all earlier measurements on this system which show that it is metallic. We…

材料科学 · 物理学 2016-08-17 Isaac F. Silvera , Rachel Husband , Ashkan Salamat , Mohamed Zaghoo

The discoveries of high-temperature superconductivity in H3S and LaH10 have excited the search for superconductivity in compressed hydrides. In contrast to rapidly expanding theoretical studies, high-pressure experiments on hydride…

超导电性 · 物理学 2021-09-15 Wuhao Chen , Dmitrii V. Semenok , Xiaoli Huang , Haiyun Shu , Xin Li , Defang Duan , Tian Cui , Artem R. Oganov

We present a new technique for measuring the critical temperature Tc in the high pressure, high Tc electron-phonon-driven superconducting hydrides. This technique does not require connecting leads to the sample. In the multiphonon region of…

超导电性 · 物理学 2018-08-01 J. P. Carbotte , E. J. Nicol , T. Timusk

Very recently, a report on possible room-temperature superconductivity in N-doped lutetium hydrides near 1 GPa pressure has drawn lots of attentions. To date, the superconductivity is not confirmed under relatively low pressure in…

超导电性 · 物理学 2023-06-27 Zhenfeng Ouyang , Miao Gao , Zhong-Yi Lu

Superconductivity commonly appears under pressure in charge density wave (CDW)-bearing transition metal dichalcogenides (TMDs), but has emerged so far only via either intercalation with electron donors or electrostatic doping in CDW-free…

In previous work,1 we showed that hydrogen metallizes in phase III at temperatures below ~200 K and at pressures near ~350 GPa. Here, we perform a detailed study of electrical conductivity R(T) in phase III over a pressure range of 200-400…

材料科学 · 物理学 2021-09-24 M. I. Eremets , P. P. Kong , A. P. Drozdov

Over the past decade, a combination of crystal structure prediction techniques and experimental synthetic work has thoroughly explored the phase diagrams of binary hydrides under pressure. The fruitfulness of this dual approach is…

超导电性 · 物理学 2022-02-21 Katerina P. Hilleke , Eva Zurek

The electronic and lattice dynamical properties of compressed solid SiH$_{4}$ have been calculated in the pressure range up to 300 GPa with density functional theory. We find that structures having a layered network with eight-fold…

超导电性 · 物理学 2008-03-20 X. J. Chen , J. L. Wang , V. V. Struzhkin , H. K. Mao , R. J. Hemley , H. Q. Lin

Recently, an extremely high superconducting temperature (Tc) of ~200 K has been reported in the sulfur hydride system above 100 GPa. This result is supported by theoretical predictions and verified experimentally. The crystal structure of…

It is generally assumed that solid hydrogen will transform into a metallic alkali-like crystal at sufficiently high pressure. However, some theoretical models have also suggested that compressed hydrogen may form an unusual two-component…

材料科学 · 物理学 2009-11-10 Stanimir A. Bonev , Eric Schwegler , Tadashi Ogitsu , Giulia Galli

Layered transition-metal tellurides have attracted considerable attention because of their rich physics; for example, tungsten ditelluride WTe2 exhibits extremely large magnetoresistance; the tritelluride ZrTe3 shows a charge density wave…

The properties of hydrogen at high pressure have wide implications in astrophysics and high-pressure physics. Its phase change in the liquid is variously described as a metallization, H2-dissociation, density discontinuity or plasma phase…

材料科学 · 物理学 2020-03-17 Hua Y. Geng , Q. Wu , Miriam Marqués , Graeme J. Ackland

PH3 is studied to understand the superconducting transition and responsible stoichiometry under high pressure by means of Raman, IR, and x-ray diffraction (XRD) measurements, and theoretical calculations. It is found PH3 is stable up to…

材料科学 · 物理学 2017-08-30 Ye Yuan , Yinwei Li , Guoyong Fang , Guangtao Liu , Cuiying Pei , Xin Li , Haiyan Zheng , Yuexiao Pan , Ke Yang , Lin Wang

Searching for superconducting hydrides has so far largely focused on finding materials exhibiting the highest possible critical temperatures ($T_c$). This has led to a bias towards materials stabilised at very high pressures, which…

超导电性 · 物理学 2020-04-29 Michael J. Hutcheon , Alice M. Shipley , Richard J. Needs

Migration of hydrogen and hydride formation under thermal gradient leads to hydrogen redistribution in certain metals. These metals include zirconium, titanium, hafnium and their alloys with tendency to form hydrides. A computational method…

材料科学 · 物理学 2026-01-01 K. A. Forsberg , A. R. Massih

Motivated by the recent discovery of near-room temperature superconductivity in high-pressure superhydrides, we investigate from first-principles the high-pressure superconducting phase diagram of the ternary Ca-B-H system, using ab-initio…

超导电性 · 物理学 2020-08-26 Simone Di Cataldo , Wolfgang von der Linden , Lilia Boeri

Compressed hydrogen-rich compounds have received extensive attention as appealing contenders for superconductors, and further challenges are maintaining the stability and superconductivity of hydrides at lower pressures. In this work, we…

超导电性 · 物理学 2023-02-22 Wendi Zhao , Defang Duan , Hao Song , Mingyang Du , Qiwen Jiang , Tiancheng Ma , Ming Xu , Tian Cui

In the last six years (2015-2021), many superconducting hydrides with critical temperatures $\textit{T}$$_C$ of up to 253 K, a record for today, have been discovered. Now, a special field of hydride superconductivity at ultrahigh pressures…

超导电性 · 物理学 2023-07-26 Dmitrii Semenok

Niobium polyhydride was synthesized at high pressure and high temperature conditions by using diamond anvil cell combined with in situ high pressure laser heating techniques. High pressure electric transport experiments demonstrate that…

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