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We identified interatomic Coulombic decay (ICD) channels in argon dimers after spectator-type resonant Auger decay $2p^{-1}~3d \to 3p^{-2}3d, 4d$ in one of the atoms, using momentum resolved electron-ion-ion coincidence. The results…

化学物理 · 物理学 2015-06-15 M. Kimura , H. Fukuzawa , K. Sakai , S. Mondal , E. Kukk , Y. Kono , S. Nagaoka , Y. Tamenori , N. Saito , K. Ueda

We report the first observation of intermolecular Coulombic decay (ICD) in liquid water following inner-valence ionization. By combining a monochromatized table-top high-harmonic source with a liquid micro-jet, we recorded electron-electron…

原子与分子团簇 · 物理学 2022-04-05 Pengju Zhang , Conaill Perry , Tran Trung Luu , Danylo Matselyukh , Hans Jakob Wörner

Aqueous solutions are crucial in chemistry, biology, environmental science, and technology. The chemistry of solutes is influenced by the surrounding solvation shell of water molecules, which have different chemical properties than bulk…

The predominant reason for the damaging power of high-energy radiation is multiple ionization of a molecule, either direct or via the decay of highly excited intermediates, as e.g., in the case of X-ray irradiation. Consequently, the…

Interatomic Coulombic decay (ICD) processes play a crucial role in weakly bound complexes exposed to intense or high-energy radiation. Using large helium nanodroplets, we demonstrate that ICD is efficient even when the droplets are…

The dynamics of the resonant Auger (RA) process of the core-excited C$^\ast$O(1s$^{-1}\pi^\ast,v_r=0$) molecule in an intense X-ray laser field is studied theoretically. The theoretical approach includes the analogue of the conical…

原子与分子团簇 · 物理学 2011-09-27 Philipp V. Demekhin , Ying-Chih Chiang , Lorenz S. Cederbaum

Electron removal in collisions of alpha particles with neon dimers is studied using an independent-atom-independent-electron model based on the semiclassical approximation of heavy-particle collision physics. The dimer is assumed to be…

原子物理 · 物理学 2022-07-06 Tom Kirchner

We report theory for time-resolved spectator resonant Interparticle Coulombic Decay (ICD) processes. Following excitation by a short extreme ultraviolet pulse, the spectrum of the resonant ICD electron develops. Strong-field ionization is…

量子物理 · 物理学 2020-04-29 Elke Fasshauer , Lars Bojer Madsen

Ionization of matter by energetic radiation generally causes complex secondary reactions which are hard to decipher. Using large helium nanodroplets irradiated by XUV photons, we show that the full chain of processes ensuing primary…

原子与分子团簇 · 物理学 2023-07-26 L. Ben Ltaief , K. Sishodia , S. Mandal , S. De , S. R. Krishnan , C. Medina , N. Pal , R. Richter , T. Fennel , M. Mudrich

Interatomic Coulombic decay (ICD) plays a crucial role in weakly bound complexes exposed to intense or high-energy radiation. So far, neutral or ionic atoms or molecules have been prepared in singly excited electron or hole states which can…

We provide the experimental evidence that the single electron capture process in slow collisions between O$^{3+}$ ions and neon dimer targets leads to an unexpected production of low-energy electrons. This production results from the…

Low-energy electrons (LEEs) are known to be effective in causing strand breaks in DNA. Recent experiments show that an important direct source of LEEs is the intermolecular Coulombic decay (ICD) process. Here we propose a new cascade…

原子与分子团簇 · 物理学 2014-02-14 Kirill Gokhberg , Premysl Kolorenc , Alexander I. Kuleff , Lorenz S. Cederbaum

The electron removal and excitation channels in argon dimer target and helium ion projectile collision systems that facilitate interatomic Coulombic decay (ICD) are investigated. We implement an independent-atom and independent-electron…

原子与分子团簇 · 物理学 2026-03-25 Darij Starko , Tom Kirchner

To exploit the high intensity of laser radiation, we propose to select frequencies at which single-photon absorption is of too low energy and two or more photons are needed to produce states of an atom that can undergo interatomic Coulombic…

原子与分子团簇 · 物理学 2012-01-04 Philipp V. Demekhin , Spas D. Stoychev , Alexander I. Kuleff , Lorenz S. Cederbaum

A real-space, real-time time-dependent density functional theory (RT-TDDFT) with Ehrenfest dynamics is used to simulate intermolecular Coulombic decay (ICD) processes following the ionization of an inner-valence electron. The approach has…

化学物理 · 物理学 2025-05-22 Kedong Wang , Cody L. Covington , Kalman Varga

The main purpose of this work is to provide reference data on X-ray ionization yields and energy spectra in liquid Ar to the studies in the field of Cryogenic Avalanche Detectors (CRADs) for rare-event and other experiments, based on liquid…

仪器与探测器 · 物理学 2016-02-19 A. Bondar , A. Buzulutskov , A. Dolgov , L. Shekhtman , A. Sokolov

Excited atoms and molecules can utilize their excess energy to ionize a neighboring system by a process named interatomic and intermolecular Coulombic decay (ICD). ICD is ultrafast, in the femtosecond regime, and has many modes of…

化学物理 · 物理学 2026-03-10 Alan G. Falkowski , Alexander I. Kuleff , Lorenz S. Cederbaum

We describe a new instrument, the Argonne Auger Radioisotope Microscope (ARM), capable of characterizing the Auger electron emission of radionuclides, including candidates relevant in nuclear medicine. Our approach relies on event-by-event…

Characterization of the inner-shell decay processes in molecules containing heavy elements is key to understanding x-ray damage of molecules and materials and for medical applications with Auger-electron-emitting radionuclides. The 1s hole…

The capability of generating two intense, femtosecond x-ray pulses with controlled time delay opens the possibility of performing time-resolved experiments for x-ray induced phenomena. We have applied this capability to study the…

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