相关论文: Core-hole Coherent Spectroscopy in Molecules

We investigate cooperative phenomena and superradiance for vibrational transitions in polar molecule spectroscopy when a high optical-depth (OD) sample is studied. Such cooperativity comes from the build-up of inter-particle coherence…

The use of ultra-short laser pulses to pump and probe materials activates a wealth of processes which involve the coherent and non coherent dynamics of interacting electrons out of equilibrium. Non equilibrium (NEQ) many body perturbation…

The development of X-ray free-electron lasers (XFELs) has enabled ultrafast X-ray diffraction (XRD) experiments, which are capable of resolving electronic/vibrational transitions and structural changes in molecules, or capturing molecular…

Highest resolution laser spectroscopy has generally been limited to single trapped ion systems due to rapid decoherence which plagues neutral atom ensembles. Here, precision spectroscopy of ultracold neutral atoms confined in a trapping…

We consider incoherent excitation of multilevel quantum systems, e.g. molecules with multiple vibronic states. We show that (1) the geometric constraints of the matter-field coupling operator guarantee that noise-induced coherences will be…

Core-excitations on different atoms are highly localized and therefore decoupled. By placing molecules in an X-ray cavity the core-transitions become coupled via the exchange of cavity photons and form delocalized hybrid light-matter…

Electronic decoherence processes in trans-polyacetylene oligomers are considered by explicitly computing the time dependent molecular polarization from the coupled dynamics of electronic and vibrational degrees of freedom in a mean-field…

Nuclear excitons known from M\"ossbauer spectroscopy describe coherent excitations of a large number of nuclei -- analogous to Dicke states (or Dicke super-radiance) in quantum optics. In this paper, we study the possibility of constructing…

The resonance strength of the two-step process of nuclear excitation by electron capture followed by $\gamma$ decay of the nucleus can be significantly increased in highly charged ions if the resonant capture proceeds via an excited…

We report a novel experimental technique to investigate ultrafast dynamics in photoexcited molecules by probing the third-order nonlinear optical susceptibility. A non-colinear 3-pulse scheme is developed to probe the ultrafast dynamics of…

Core hole resonance is used in X-ray spectroscopy to incisively probe the local electronic states of many-body systems. Here, resonant inelastic X-ray scattering (RIXS) is studied as a function of incident photon energy on Mott insulators…

One of the most pertinent problems in the debate on non-trivial quantum effects in biology concerns natural photosynthesis. Since sunlight is composed of thermal photons, it was argued to be unable to induce quantum coherence in matter, and…

We explore the mechanism for the long-lived quantum coherence by considering the discrete phonon modes: these vibrational modes effectively weaken the exciton-environment interaction, due to the new composite (polaron) formed by excitons…

Modern x-ray sources enable the production of coherent x-ray pulses with a pulse duration in the same order as the characteristic lifetimes of core-hole states of atoms and molecules. These pulses enable the manipulation of the core-hole…

We analyze the decoherence induced on a single qubit by the interaction with a two-level boson system with critical internal dynamics. We explore how the decoherence process is affected by the presence of quantum phase transitions in the…

Coherent dynamics of coupled molecules are effectively characterized by the two-dimensional (2D) electronic coherent spectroscopy. Depending on the coupling between electronic and vibrational states, oscillating signals of purely…

Electronic coherences are key to understanding and controlling photo-induced molecular transformations. We identify a crucial quantum-mechanical feature of electron-nuclear correlation, the projected nuclear quantum momenta, essential to…

We investigate the nonequilibrium dynamics and loss of coherence in a quantum impurity system using the spinless resonant level model subject to sudden quenches of the hybridization between the impurity and the metal. The survival…

X-ray photoemission (XPS) and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy play an important role in investigating the structure and electronic structure of materials and surfaces. Ab-initio simulations provide crucial…

The IceCube collaboration has recently identified events due to ultrahigh-energy neutrino interactions. Predictions of the neutrino-nucleon cross section at ultrahigh energies require a huge extrapolation of the cross sections…