相关论文: Life beyond Fritz: On the detachment of electrolyt…
We develop and implement numerically a phase field model for the growth and detachment of a gas bubble resting on an electrode and being filled with hydrogen produced by water electrolysis. The bubble is surrounded by a viscous liquid, has…
Three-dimensional direct numerical simulation of electrolysis is applied to investigate the growth and detachment of bubbles at electrodes. The moving gas-liquid interface is modeled employing the VOF-based method. To ensure the accuracy of…
The evolution of electrogenerated gas bubbles during water electrolysis can significantly hamper the overall process efficiency. Promoting the departure of electrochemically generated bubbles during (water) electrolysis is therefore…
Contact line friction (CLF) of bubbles is ubiquitous, from bubbles on a beer glass to H2 bubbles sliding over electrodes in electrolysis. However, a fundamental understanding of CLF of bubbles is still missing, mainly due to the challenge…
The formation, growth and detachment of gas bubbles on electrodes are omnipresent in electrolysis and other gas-producing chemical processes. To better understand their role in the mass transfer efficiency, we perform experiments involving…
Electrolytically generated gas bubbles can significantly hamper the overall electrolysis efficiency. Therefore it is crucial to understand their dynamics in order to optimise water electrolyzer systems. Here we demonstrate a distinct…
Bubble growth, departure and sliding in low-pressure flow boiling has received considerable attention in the past. However, most applications of boiling heat transfer rely on high-pressure flow boiling, for which very little is known, as…
Bubble coalescence can promote bubble departure at much smaller sizes compared to buoyancy. This can critically enhance the efficiency of gas-evolving electrochemical processes, such as water electrolysis. In this study, we integrate…
The dynamics of hydrogen bubbles produced by water electrolysis in an acidic electrolyte are studied using electrochemical and optical methods. A defined cyclic modulation of the electric potential is applied at a microelectrode to produce…
In gas evolving electrolysis, bubbles grow at electrodes due to a diffusive influx from oversaturation generated locally in the electrolyte by the electrode reaction. When considering electrodes of micrometer-size resembling catalytic…
The contact angle of a fluid droplet on an heterogeneous surface is analysed using the statistical dynamics of the spreading contact line. The statistical properties of the final droplet radius and contact angle are obtained through…
Contact angle hysteresis of a macroscopic droplet on a heterogeneous but flat substrate is studied using the interface displacement model. First, the apparent contact angle of a droplet on a heterogeneous surface under the condition of…
We develop and implement numerically a phase field model for the evolution and detachment of a gas bubble resting on a solid substrate and surrounded by a viscous liquid. The bubble has a static contact angle $\theta $ and will be subject…
The efficiency of water electrolysis is significantly impacted by the generation of micro- and nanobubbles on the electrodes. Here molecular dynamics simulations are used to investigate the dynamics of single electrolytic nanobubbles on…
We study the stability and breakup of liquid bridges with a free contact line on a surface with contact-angle hysteresis under zero-gravity conditions. Theoretical predictions of the stability limits are validated by experimental…
A novel 3-electrode cell type is introduced to run parametrical studies of H$_2$ evolution in an alkaline electrolyte on porous electrodes. Electrochemical methods combined with a high-speed optical measurement system are applied…
Enhancing the efficiency of water electrolysis, which can be severely impacted by the nucleation and growth of bubbles, is key in the energy transition. In this combined experimental and numerical study, in-situ bubble evolution and…
We investigate the transient bubbles that spontaneously appear in a simple liquid using molecular simulations. The objective is to deduce the free-energy of formation of the bubbles $W(s)$ from the bubble size distribution $p(s)$ through…
The removal of microbubbles from substrates is crucial for the efficiency of many catalytic and electrochemical gas evolution reactions in liquids. The current work investigates the coalescence and detachment of bubbles generated from…
Hypothesis: Understanding contact angle hysteresis on rough surfaces is important as most industrially relevant and naturally occurring surfaces possess some form of random or structured roughness. We hypothesise that hysteresis originates…