相关论文: Formation of extraterrestrial peptides and their d…
Organic molecules are widely present in the dense interstellar medium, and many have been synthesized in the laboratory on Earth under the conditions typical for an interstellar environment. Until now, however, only relatively small…
A recent suggestion that acetamide, \ce{CH3C(O)NH2}, could be readily formed on water-ice grains by the acid induced addition of water across the \ce{CN} bond is now shown to be valid. Computational modelling of the reaction between…
Water is abundantly present in the Universe. It is the main component of interstellar ice mantles and a key ingredient for life. Water in space is mainly formed through surface reactions. Three formation routes have been proposed in the…
Water is the main component of interstellar ice mantles, is abundant in the solar system and is a crucial ingredient for life. The formation of this molecule in the interstellar medium cannot be explained by gas-phase chemistry only and its…
The biological molecules delivered to Earth on the board of meteorites and comets were called one of the possible causes of the origin of life. Therefore, our understanding of the routes of formation of biomolecules in space should shed the…
We propose a simple and efficient pathway for the formation of precursors to core nucleobases in DNA and RNA using a suite of computational chemistry methods. Benzene, which is thermochemically stable in N2- or CO2-dominated atmospheres,…
Energetic processing of interstellar ice mantles and planetary atmospheres via photochemistry is a critical mechanism in the extraterrestrial synthesis of prebiotic molecules. Photochemistry is defined as chemical processes initiated by…
The synthesis of water is one necessary step in the origin and development of life. It is believed that pristine water is formed and grows on the surface of icy dust grains in dark interstellar clouds. Until now, there has been no…
The peptides in biosystems are homochiral polymers of L-amino acids, but razemisate slowly by an active isomerization kinetics. The chemical reactions in biosystems are, however, reversible and what racemisates the peptides at the water…
Photochemistry has the potential to substantially impact the atmospheric composition of exoplanets with consequences on the radiative transfer, thermal structure and dynamics of the atmospheres, particularly in UV-rich stellar environments.…
The formation of interstellar water has been commonly accepted to occur on the surfaces of icy dust grains in dark molecular clouds at low temperatures (10-20 K), involving hydrogenation reactions of oxygen allotropes. As a result of the…
The chemical fingerprint of a planet reveals information about its formation history regarding when and where it formed. The water content of a planet can help to constrain its formation pathway: If the planet formed in the outer regions of…
How life started on Earth is an unsolved mystery. There are various hypotheses for the location ranging from outer space to the seafloor, subseafloor or potentially deeper. Here, we applied extensive ab initio molecular dynamics (AIMD)…
Very little experimental work has been done to explore the properties of photochemical hazes formed in atmospheres with very different compositions or temperatures than that of the outer solar system or of early Earth. With extrasolar…
(Abridged) Exoplanet atmospheres are thought be built up from accretion of gas as well as pebbles and planetesimals in the midplanes of planet-forming disks. The chemical composition of this material is usually assumed to be unchanged…
It is long debated if pre-biotic molecules are indeed present in the interstellar medium. Despite substantial works pointing to their existence, pre-biotic molecules are yet to be discovered with a complete confidence. In this paper, our…
In warm (equilibrium temperature <1000 K) gas giant exoplanet atmospheres, the observation of trace species in abundances deviating from thermochemical equilibrium predictions could be used as an indicator of disequilibrium chemical…
Even though water is the main constituent in interstellar icy mantles, its chemical origin is not well understood. Three different formation routes have been proposed following hydrogenation of O, O2, or O3, but experimental evidence is…
Characterizing temperate exoplanet atmospheres remains challenging due to their small size and low temperatures. Recent JWST observations provide valuable data, but their interpretation has led to diverging conclusions. Complementary…
In order to examine how the terrestrial life emerged, a number of laboratory experiments have been conducted since the 1950s. Methane has been one of the key molecules in these studies. In earlier studies, strongly reducing gas mixtures…