相关论文: Attractive carbon black dispersions: structural an…
Due to rich rheological properties, dispersions of attractive colloidal particles are ubiquitous in industries. Specifically, upon experiencing a sudden reduction in shear rate, these dispersions may exhibit transient behaviors such as…
In recent years, significant effort has been devoted to developing smart materials whose mechanical properties can adapt under physical stimuli. Particulate colloidal gels, which behave as solids but can also flow under stress, have emerged…
Various dispersions of attractive particles are known to aggregate into patterns of vorticity-aligned stripes when sheared in confined geometries. We report a thorough experimental investigation of such shear-induced vorticity alignment…
The stress-induced yielding scenario of colloidal gels is investigated under rough boundary conditions by means of rheometry coupled to local velocity measurements. Under an applied shear stress, the fluidization of gels made of attractive…
Colloidal dispersions are commonly encountered in everyday life and represent an important class of complex fluid. Of particular significance for many commercial products and industrial processes is the ability to control and manipulate the…
Colloidal gels are out of equilibrium soft solids composed of attractive Brownian particles that form a space-spanning network at low volume fractions. The elastic properties of these systems result from the network microstructure, which is…
A recently proposed schematic model for the non--linear rheology of dense colloidal dispersions is compared to flow curves measured in suspensions that consist of thermosensitive particles. The volume fraction of this purely repulsive model…
Suspensions of attractive particles form space-spanning networks that endow the suspension with solid-like behavior at rest. The microstructure of these colloidal gels depends sensitively on the shear history and on the path followed across…
The aggregation of attractive colloids has been extensively studied from both theoretical and experimental perspectives as the fraction of solid particles is changed, and the range, type and strength of attractive or repulsive forces…
The flow of dense suspensions, glasses, and granular materials is heavily influenced by frictional interactions between constituent particles. However, neither hydrodynamics nor friction has successfully explained the full range of flow…
The increase of the viscosity, which is observed in attractive colloidal systems by varying the temperature or the volume fraction, can be related to the formation of structures due to particle aggregation. In particular we have studied the…
Sheared concentrated colloids with short range polymer coats are examined via simulations. Distributions of force are found to be sums of exponentials. The 'hydrodynamic clustering' underlying the shear thickening effect is shown, in this…
Attractive colloidal gels display a solid-to-fluid transition as shear stresses above the yield stress are applied. This shear-induced transition is involved in virtually any application of colloidal gels. It is also crucial for controlling…
We report a numerical study of the shear viscosity and the frequency dependent elastic moduli close to dynamical arrest for a model of short-range attractive colloids, both for the repulsive and the attractive glass transition. Calculating…
The nonlinear rheological properties of dense colloidal suspensions under steady shear are discussed within a first principles approach. It starts from the Smoluchowski equation of interacting Brownian particles in a given shear flow,…
Carbon Black is a filler frequently used in conductive suspensions or nanocomposites, in which it forms networks supporting electric conductivity. Although Carbon Black aggregates originate from a presumably isotropic aggregation process,…
Colloid-polymer hydrogels are encountered in various applications, from flow batteries to drug delivery. Here, we investigate hydrogels composed of hydrophobic colloidal soot particles -- carbon black (CB) -- and carboxymethylcellulose…
The growing interest in the non-equilibrium assembly of colloidal particles in active liquids is driven by the motivation to create novel structures endowed with tunable properties unattainable within the confines of equilibrium systems.…
Dense suspensions of soft colloidal particles display a broad range of physical and rheological properties which are still far from being fully understood. To elucidate the role of deformability on colloidal flow, we employ computer…
Typically, in quiescent conditions, attractive colloids at low volume fractions form fractal gels structured into two length scales: the colloidal and the fractal cluster scales. However when flow interfere with gelation colloidal fractal…