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Reverse osmosis (RO) is a method to desalinate water with membranes and an applied pressure. Very important in the theory of mass transport in RO is the concentration polarization (CP) layer, which develops on the upstream side of the…

化学物理 · 物理学 2023-10-03 P. M. Biesheuvel , S. Porada , I. Ryzhkov , M. Elimelech

Accounting for concentration-polarization (CP) is critical for modeling solute transport in membrane separation processes. In a mixed-electrolyte solution, ions CP is affected not only by diffusion and advection but also by…

软凝聚态物质 · 物理学 2021-08-05 Yaeli S. Oren , Viatcheslav Freger , Oded Nir

Polyamide membranes, such as nanofiltration (NF) and reverse osmosis (RO) membranes, are widely used for water desalination and purification. However, the mechanisms of solute transport and solute rejection due to charge interactions remain…

软凝聚态物质 · 物理学 2025-03-17 Suwei Liu , Zi Hao Foo , John H. Lienhard , Sinan Keten , Richard M. Lueptow

In this paper we study a mathematical model that represents the concentration polarization and osmosis effects in a reverse osmosis cross-flow channel with porous membranes at some of its boundaries. The fluid is modeled using the…

数值分析 · 数学 2022-12-19 Nicolás Carro , David Mora , Jesus Vellojin

In this article, we will derive the differential equations considering the concentration polarization (\textsc{cp}) in membrane separations and purifications, which involve convective-diffusive equations of the concentration polarization…

偏微分方程分析 · 数学 2020-01-03 Qiao-Le He , Pei Guo , Liming Zhao

The Angstrom-scale transport characteristics of water and six different solutes, methanol, ethanol, 2-propanol, urea, Na+, and Cl-, were studied for a polyamide reverse osmosis (RO) membrane, FT-30, using non-equilibrium molecular dynamics…

计算物理 · 物理学 2016-07-18 Meng Shen , Sinan Keten , Richard M. Lueptow

Nanoporous carbon composite membranes, comprising a layer of porous carbon fiber structures with an average channel width of 30-60 nm grown on a porous ceramic substrate, are found to exhibit robust desalination effect with high freshwater…

材料科学 · 物理学 2016-04-27 Wei Chen , Shuyu Chen , Qiang Zhang , Zhongli Fan , Kuo-Wei Huang , Xixiang Zhang , Zhiping Lai , Ping Sheng

A filtration procedure was developed to measure the reversibility of fouling during cross-flow filtration based on the square wave of applied pressure. The principle of this method, the apparatus required, and the associated mathematical…

软凝聚态物质 · 物理学 2008-01-18 Benjamin Espinasse , Patrice Bacchin , Pierre Aimar

Membrane ultrafiltration (UF) is a pressure driven process allowing for the separation and enrichment of protein solutions and dispersions of nanosized microgel particles. The permeate flux and the near-membrane concentration-polarization…

软凝聚态物质 · 物理学 2015-05-19 Rafael Roa , Emiliy K. Zholkovskiy , Gerhard Nägele

Modelling micro- and meso-scopic scale thermodynamic and transport properties of soft condensed matter hinges upon its representation. This is especially relevant for polar solvents such as water, since these require effective…

软凝聚态物质 · 物理学 2026-04-17 Michael A. Seaton , Benjamin T. Speake , Ilian T. Todorov

The reverse osmosis membrane module is an integral element of a desalination system as it determines the overall performance of the desalination plant. The fraction of clean water that can be recovered via this process is often limited by…

数值分析 · 数学 2023-01-31 Nicodemo Di Pasquale , Mayo Akele , Federico Municchi , John King , Matteo Icardi

Transport of liquid mixtures through porous membranes is central to processes such as desalination, chemical separations and energy harvesting, with ultrathin membranes made from novel 2D nanomaterials showing exceptional promise. Here we…

软凝聚态物质 · 物理学 2019-08-06 Daniel J. Rankin , Lydéric Bocquet , David M. Huang

We present theory for ion and water transport through reverse osmosis membranes based on a Maxwell-Stefan framework combined with hydrodynamic theory for the reduced motion of particles in thin pores. We include all driving forces and…

化学物理 · 物理学 2018-03-07 Y. S. Oren , P. M. Biesheuvel

We report a molecular dynamics (MD) simulation study of reverse osmosis desalination using nanoporous monolayer graphene passivated by SiH$_2$ and Si(OH)$_2$ functional groups. A highly accurate and detailed polarizable molecular mechanics…

化学物理 · 物理学 2018-04-10 Yudong Qiu , Benedict R. Schwegler , Lee-Ping Wang

Reverse Osmosis(RO) membranes are widespread nowadays for separating the solvent from a solution. RO membranes are made of polymer matrix. Experiments show changes in relative interaction of solvent and solute with RO membrane matrix lead…

软凝聚态物质 · 物理学 2023-05-16 Rahul Karmakar , Jaydeb Chakrabarti

We report a multiscale modeling study for charged cylindrical nanopores using three modeling levels that include (1) an all-atom explicit-water model studied with molecular dynamics (MD), and reduced models with implicit water containing…

The emergence of new nanoporous materials, based e.g. on 2D materials, offers new avenues for water filtration and energy. There is accordingly a need to investigate the molecular mechanisms at the root of the advanced performances of these…

介观与纳米尺度物理 · 物理学 2023-07-10 Geoffrey Monet , Marie-Laure Bocquet , Lydéric Bocquet

Reverse Osmosis Membrane (ROM) filtration systems are widely applied in wastewater recovery, seawater desalination, landfill water treatment, etc. During filtration, the system performance is dramatically affected by membrane fouling which…

流体动力学 · 物理学 2019-02-20 Bowen Ling , Ilenia Battiato

In a multiscale modeling approach, we present computer simulation results for a rectifying bipolar nanopore on two modeling levels. In an all-atom model, we use explicit water to simulate ion transport directly with the molecular dynamics…

介观与纳米尺度物理 · 物理学 2018-03-13 Zoltán Ható , Mónika Valiskó , Tamás Kristóf , Dirk Gillespie , Dezső Boda

Reverse osmosis (RO) and electrodialysis (ED) are the two most important membrane technologies for water desalination and treatment. Their modes of operation and transport mechanisms are very different, but on a closer look also have many…

化学物理 · 物理学 2025-07-08 P. M. Biesheuvel , S. Porada , L. Wang , R. Wang , M. Elimelech , J. E. Dykstra
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