相关论文: Hyperelastic swelling of stiff hydrogels
Hydrogels which are hydrophilic and porous materials have recently emerged as promising systems for filtration applications. In our study, we prepare hydrogel membranes by the photopolymerization of a mixture of poly (ethylene glycol)…
We apply monomer-resolved computer simulations of supercoiled ring polymers under shear, taking full account of the hydrodynamic interactions, accompanied, in parallel, by simulations in which these are switched off. The combination of…
When a rigid object approaches a soft material in a viscous fluid, hydrodynamic stresses arise in the lubricated contact region and deform the soft material. The elastic deformation modifies in turn the flow, hence generating a…
Cyclic loading is a common feature in poroelastic systems, the material response depending non-trivially on the exact form of boundary conditions, pore structure, and mechanical properties. The situation becomes more complex when…
Glasses behave as solids on experimental time scales due to their slow relaxation. Growing dynamic length scales due to cooperative motion of particles are believed to be central to this slow response. For quiescent glasses, however, the…
We investigate pattern transformations of periodic hydrogel systems that are triggered by swelling-induced structural instabilities. The types of microstructures considered in the present work include single-phase and two-phase voided…
Instability patterns of rolling up a sleeve appear more intricate than the ones of walking over a rug on floor, both characterized as uniaxially compressed soft-film/stiff-substrate systems. This can be explained by curvature effects. To…
The bending rigidity $k_c$ of bilayer vesicles self-assembled from amphiphilic diblock copolymers has been measured using single and dual-micropipet techniques. These copolymers are nearly a factor of 5 greater in hydrophobic membrane…
We show that the aging of the mechanical relaxation of a gelatin gel exhibits the same scaling phenomenology as polymer and colloidal glasses. Besides, gelatin is known to exhibit logarithmic structural aging (stiffening). We find that…
We use the impact of drops on a small solid target as a tool to investigate the behavior of viscoelastic fluids under extreme deformation rates. We study two classes of transient networks: semidilute solutions of supramolecular polymers and…
In this research study, a numerical tool, which is based on a version of Slender Body theory, has been used and also modified to simulate the mechanical behaviour of single- and double-cross-linked biopolymer networks (hydrogel) under…
As 2D materials such as graphene, transition metal dichalcogenides, and 2D polymers become more prevalent, solution processing and colloidal-state properties are being exploited to create advanced and functional materials. However, our…
We report experimental and computational observations of dynamic contact networks for colloidal suspensions undergoing shear thickening. The dense suspensions are comprised of sterically stabilized poly(methyl methacrylate) hard sphere…
Suspensions are of wide interest and form the basis for many smart fluids. For most suspensions, the viscosity decreases with increasing shear rate, i.e. they shear thin. Few are reported to do the opposite, i.e. shear thicken, despite the…
All-polymer syntactic foams are studied under large strain cyclic and monotonic tensile loading in order to reveal their tensile stress-strain behaviour, recoverability, tensile strength, and elongation at break. The syntactic foam under…
The viscoelastic effect on the hydrodynamic relaxation in semidilute polymer solutions is investigated. From the linearized two-fluid model equations, we predict that the dynamical asymmetry coupling between the velocity fluctuations and…
Fluid stretching in porous media governs the mixing of reactants, contaminants, and nutrients, yet how the solid microstructure controls the stretching statistics remains poorly understood. We investigate how porous-medium heterogeneity…
Thermo-responsive hydrogels are smart materials that rapidly switch between hydrophilic (swollen) and hydrophobic (shrunken) states when heated past a threshold temperature, resulting in order-of-magnitude changes in gel volume. Modelling…
The nonequilibrium dynamical behavior and structure formation of end-functionalized semiflexible polymer suspensions under flow are investigated by mesoscale hydrodynamic simulations. The hybrid simulation approach combines the…
We report temperature-responsive soft composites of semiflexible biopolymer networks (fibrin) containing dispersed microgel colloidal particles of poly(N-isopropylacrylamide) (pNIPAM) that undergo a thermodynamically driven de-swelling…