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Polymer chains decorated with a fraction of monomers capable of forming reversible bonds form transient polymer networks that are important in soft and biological systems. If chains are flexible and the attractive monomers are all of the…

软凝聚态物质 · 物理学 2023-10-18 Lorenzo Rovigatti , Francesco Sciortino

We introduce a novel coarse-grained bead-spring model for flexible polymers to systematically examine the effects of an adjusted bonded potential on the formation and stability of structural macrostates in a thermal environment. The density…

We perform numerical simulations of isolated, partially active polymers, driven out-of-equilibrium by a fraction of their monomers. We show that, if the active beads are all gathered in a contiguous block, the position of the section along…

软凝聚态物质 · 物理学 2023-09-04 Marin Vatin , Sumanta Kundu , Emanuele Locatelli

We study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the…

软凝聚态物质 · 物理学 2009-10-30 Tao Sun , Anna C. Balazs , David Jasnow

The associative interaction, such as hydrogen bonding, can bring about versatile functionalities to polymer systems, which has been investigated by tremendous researches, but the fundamental understanding on association process is still…

软凝聚态物质 · 物理学 2025-01-20 Xiangyu Zhang , Dong Meng

Cooperative binding affects many processes in biology, but it is commonly addressed only in equilibrium. In this work we explore dynamical cooperativity in driven systems, where the cooperation occurs because some of the bonds change the…

生物物理 · 物理学 2015-05-13 Jørgen Kjoshagen Trømborg , Alfredo Alexander-Katz

Phase-separated biomolecular condensates exhibit a wide range of dynamical properties, which depend on the sequences of the constituent proteins and RNAs. However, it is unclear to what extent condensate dynamics can be tuned without also…

生物大分子 · 定量生物学 2024-07-31 Yaxin An , Michael A. Webb , William M. Jacobs

Vitrimers are polymer networks that can undergo bond exchange reactions. They dynamically rearrange their structures while maintaining their overall integrity, thus resulting in unique properties such as self-healing, reprocessability,…

软凝聚态物质 · 物理学 2024-02-27 Rahul Karmakar , Himanshu , Srikanth Sastry , Sanat K Kumar , Tarak K Patra

The influence of structural constraints on the relaxation dynamics of three polyurea networks with varying degree of crosslinking, has been studied by means of a thorough analysis of broadband dielectric spectroscopy measurements. Two…

软凝聚态物质 · 物理学 2018-10-03 Nerea Sebastián , Christophe Contal , Antoni Sánchez-Ferrer , Marco Pieruccini

Hybrid molecular dynamics/Monte Carlo simulations used to study melts of unentangled, thermoreversibly associating supramolecular polymers. In this first of a series of papers, we describe and validate a model that is effective in…

软凝聚态物质 · 物理学 2015-05-13 Robert S. Hoy , Glenn H. Fredrickson

Heterogeneous distribution of passive and active domains in the chromosome plays a crucial role for its dynamic organization within the cell nucleus. Motivated by that here we investigate the steady-state conformation and dynamics of a…

软凝聚态物质 · 物理学 2024-09-27 Suman Majumder , Subhajit Paul

In this work, we investigate a model of an adaptive networked dynamical system, where the coupling strengths among phase oscillators coevolve with the phase states. It is shown that in this model the oscillators can spontaneously…

无序系统与神经网络 · 物理学 2010-11-02 Menghui Li , Shuguang Guan , C. -H. Lai

We present simulations on a binary blend of bead-spring polymer chains. The introduction of monomer size disparity yields very different relaxation times for each component of the blend. Competition between two different arrest mechanisms,…

软凝聚态物质 · 物理学 2007-05-23 Angel J. Moreno , Juan Colmenero

We investigate theoretically the effect of polymer tension on the collective behavior of reversibly binding cross-links. For this purpose, we employ a model of two weakly bending wormlike chains aligned in parallel by a tensile force, with…

生物物理 · 物理学 2015-02-10 Panayotis Benetatos , Alice von der Heydt , Annette Zippelius

Computer simulation studies on the miscibility behavior and single chain properties in binary polymer blends are reviewed. We consider blends of various architectures in order to identify important architectural parameters on a coarse…

统计力学 · 物理学 2007-05-23 Marcus Mueller

The coil-globule transition of hetero-polymer chains is studied here. By means of extensive Molecular Dynamics simulations, we show that the transition is directly linked to the complexity of the chain, which depends on the number of…

软凝聚态物质 · 物理学 2022-09-07 Fabrizio Tafuri , Andrea Maria Chiariello

Active polymers possess numerous unique properties that are quite different from those observed in the system of small active molecule due to the intricate interplay between their activity and topological constraints. This study focuses on…

软凝聚态物质 · 物理学 2024-07-09 Jing Li , Bokai Zhang , Zhi-Yong Wang

The structural properties of a linear polymer and its evolution in time have a strong bearing on its anisotropic stress response. The mean-square bond length and mean bond angle are the critical parameters that influence the time-varying…

软凝聚态物质 · 物理学 2010-12-30 Prashant Kumar Srivastava , Kartik Venkatraman

We have studied the thermodynamics of isolated homopolymer chains of varying stiffness using a lattice model. A complex phase behaviour is found; phases include chain-folded `crystalline' structures, the disordered globule and the coil. It…

软凝聚态物质 · 物理学 2008-02-03 Jonathan Doye , Richard Sear , Daan Frenkel

The non-equilibrium structural and dynamical properties of a flexible polymer tethered to a reflecting wall and subject to oscillatory linear flow are studied by numerical simulations. Polymer is confined in two dimensions and is modeled as…

软凝聚态物质 · 物理学 2024-07-30 A. Lamura
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