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Hydrous minerals contribute largely to the transport and distribution of water into the mantle of earth to regulate the process of deep-water cycle. Brucite is one of the simplest layered dense hydrous mineral belonging to MgO-SiO2-H2O…

材料科学 · 物理学 2023-09-12 Sudip Kumar Mondal , Pratik Kumar Das , Nibir Mandal

First principles calculations were carried out to study the phase stability and thermoelectric properties of the naturally occurring marcasite phase of FeS$_2$ at ambient condition as well as under pressure. Two distinct density functional…

Density-functional simulations are used to calculate structural properties and high-symmetry phonons of the hypothetical cubic phase, the stable orthorhombic phase and an intermediate tetragonal phase of magnesium silicate perovskite. We…

mtrl-th · 物理学 2016-09-07 M. C. Warren , G. J. Ackland

$\rm{RuO_2}$ stands as a quintessential rutile-type compound under ambient conditions, with its structural exploration under pressure bearing significant implications for both phase transition investigations and Earth science. Nonetheless,…

We investigate the elementary steps at the microscopic level for proton diffusion in brucite under high pressure, which results from a complex interplay between two processes: the O-H reorientations motion around the $\mathbf c$ axis and…

材料科学 · 物理学 2020-03-20 Sofiane Schaack , Philippe Depondt , Simon Huppert , Fabio Finocchi

By means of first-principles calculations, various properties of SrRuO3 are investigated, focusing on its lattice dynamical properties. Despite having a Goldschmidt tolerance factor very close to 1, the phonon dispersion curves of the…

材料科学 · 物理学 2015-03-09 Naihua Miao , Nicholas C Bristowe , Bin Xu , Matthieu Verstraete , Philippe Ghosez

We have performed extensive ab initio calculations to investigate phonon dynamics and their possible role in superconductivity in BaFe2As2 and related systems. The calculations are compared to inelastic neutron scattering data that offer…

超导电性 · 物理学 2009-11-13 M. Zbiri , H. Schober , M. R. Johnson , S. Rols , R. Mittal , Y. Su , M. Rotter , D. Johrendt

We have performed an experimental study of the crystal structure, lattice-dynamics, and optical properties of PbCrO4 (the mineral crocoite) at ambient and high pressures. In particular, the crystal structure, Raman-active phonons, and…

材料科学 · 物理学 2012-01-13 E. Bandiello , D. Errandonea , D. Martinez-Garcia , D. Santamaria-Perez , F. J. Manjon

The stability, structure and properties of carbonate minerals at lower mantle conditions has significant impact on our understanding of the global carbon cycle and the composition of the interior of the Earth. In recent years, there has…

The structure, lattice dynamics and mechanical properties of the magnesium hydroxide have been investigated with static density functional theory calculations as well as \it {ab initio} molecular dynamics. The hypothesis of a superstructure…

Marcasite-type compounds have been proposed as promising hosts of exotic magnetic quantum states, yet experimental realizations in stoichiometric, disorder-free systems remain limited. Here, we report the high-pressure stabilization and…

Binary carbides demonstrate attractive set of physical properties that are suitable for numerous and diverse applications. In the present study, we have explored the structural properties, electronic structures, elastic constants, acoustic…

材料科学 · 物理学 2022-02-01 M. I. Naher , S. H. Naqib

Bridgmanite, a high temperature and pressure form of $MgSiO_3$, is believed to be Earth's most abundant mineral and responsible for the observed seismic anisotropy in the mantle. Little is known about surfaces of bridgmanite but knowledge…

化学物理 · 物理学 2019-04-15 Ming Geng , Hannes Jónsson

The elastic, thermodynamic, and electronic properties of fluorite RuO_2 under high pressure are investigated by plane-wave pseudopotential density functional theory. The optimized lattice parameters, elastic constants, bulk modulus, and…

材料科学 · 物理学 2017-08-23 Z. J. Yang , A. M. Guo , Y. D. Guo , J. Li , Z. Wang , Q. Liu , R. F. Linghu , X. D. Yang

Using ab initio calculations, unexpected structural instability was recently found in the ground state of the U$_2$Mo compound. Instead of the unstable $I4/mmm$ structure, in this work the $P6/mmm$ ($\# 191$) space group, usually called…

材料科学 · 物理学 2016-08-03 E. L. Losada , J. E. Garcés

In this work we explore the phase diagram of the binary Nb-S system from ambient pressures up to 250 GPa using $ab$ $initio$ evolutionary crystal structure prediction. We find several new stable compositions and phases, especially in the…

材料科学 · 物理学 2021-01-13 Roman Lucrezi , Christoph Heil

The strongly correlated material FeSi exhibits several unusual thermal, magnetic, and structural properties under varying pressure-temperature (P-T) conditions. It is a potential thermoelectric alloy and a materials of several geological…

The temperature anomalies in the Earth's mantle associated with thermal convection1 can be inferred from seismic tomography, provided that the elastic properties of mantle minerals are known as a function of temperature at mantle pressures.…

材料科学 · 物理学 2017-10-25 A. R. Oganov , J. P. Brodholt , G. D. Price

It is well known that conventional harmonic lattice dynamics cannot be applied to energetically unstable crystals at 0 K, such as high temperature body centered cubic (BCC) phase of crystalline Zr. Predicting phonon spectra at finite…

材料科学 · 物理学 2019-01-02 Xin Qian , Ronggui Yang

The properties of crystals consisting of several components can be widely tuned. Often solid solutions are produced, where substitutional or interstitional disorder determines the crystal thermodynamic and mechanical properties. The…

软凝聚态物质 · 物理学 2019-10-30 Tadeus Ras , Michael Szafarczyk , Matthias Fuchs
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