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We propose a method for the estimation of the initial polarization of spinful nuclei of the 13 C isotope in diamond via a measurement of the evolution of the coherence of an NV center spin qubit. Existing polarization measurement methods…

量子物理 · 物理学 2025-04-01 Mateusz Kuniej , Katarzyna Roszak

NV centers in diamond recommend themselves as good sensors of environmental fields as well as detectors of diamond impurities. In particular, C-centers, often also called ${{p}_{1}}$-centers, can be detected via double electron-electron…

Nitrogen vacancy (NV) centers in diamond have been used as ultrasensitive magnetometers to perform nuclear magnetic resonance (NMR) spectroscopy of statistically polarized samples at 1 - 100 nm length scales. However, the spectral linewidth…

Dynamic nuclear polarization (DNP) is a method of enhancing NMR signals via the transfer of polarization from electron spins to nuclear spins using on-resonance microwave (MW) irradiation. In most cases, monochromatic continuous-wave (MCW)…

化学物理 · 物理学 2022-11-17 Daphna Shimon , Kelly A. Cantwell , Linta Joseph , Chandrasekhar Ramanathan

Efficient polarization of organic molecules is of extraordinary relevance when performing nuclear magnetic resonance (NMR) and imaging. Commercially available routes to dynamical nuclear polarization (DNP) work at extremely…

The sensitivity of Magnetic Resonance Imaging (MRI) depends strongly on nuclear spin polarisation and, motivated by this observation, dynamical nuclear spin polarisation has recently been applied to enhance MRI protocols (Kurhanewicz, J.,…

Single-molecule nuclear magnetic resonance (NMR) is a crown-jewel challenge in the field of magnetic resonance spectroscopy and has important applications in chemical analysis and in quantum computing. Recently, it becomes possible to…

介观与纳米尺度物理 · 物理学 2015-06-17 Fazhan Shi , Xi Kong , Pengfei Wang , Fei Kong , Nan Zhao , Ren-Bao Liu , Jiangfeng Du

A promising approach for multi-qubit quantum registers is to use optically addressable spins to control multiple dark electron-spin defects in the environment. While recent experiments have observed signatures of coherent interactions with…

Electron paramagnetic resonance spectroscopy (EPR) is among the most important analytical tools in physics, chemistry, and biology. The emergence of nitrogen-vacancy (NV) centers in diamond, serving as an atomic-sized magnetometer, has…

Coupled electron-nuclear spins represent a promising quantum system, where the optically induced electron spin polarization can be dynamically transferred to nuclear spins via the hyperfine interaction. Most experiments on dynamic nuclear…

材料科学 · 物理学 2026-01-13 A. N. Anisimov , A. V. Poshakinskiy , G. V. Astakhov

The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…

Dynamic nuclear polarization experiments use microwave irradiation to transfer the larger electron polarization to nuclear spins of interest, and thus enhance the NMR transitions above thermal equilibrium. How the polarization transfer from…

化学物理 · 物理学 2026-01-12 Gian-Marco Camenisch , Nino Wili , Gunnar Jeschke , Matthias Ernst

A key limitation of electron paramagnetic resonance (EPR), an established and powerful tool for studying atomic-scale biomolecular structure and dynamics is its poor sensitivity, samples containing in excess of 10^12 labeled biomolecules…

Nuclear electric resonance (NER) is based on nuclear magnetic resonance mediated by spatial oscillations of electron spin domains excited by a radio frequency (RF) electric field, and it allows us to investigate the spatial distribution of…

介观与纳米尺度物理 · 物理学 2012-10-25 S. Watanabe , G. Igarashi , N. Kumada , Y. Hirayama

Initializing a set of qubits to a given quantum state is a basic prerequisite for the physical implementation of quantum-information protocols. Here, we discuss the polarization of the electronic and nuclear spin in a single nitrogen…

量子物理 · 物理学 2017-07-26 Tanmoy Chakraborty , Jingfu Zhang , Dieter Suter

We introduce a method for the measurement of the lower bound on the initial polarization of spinful nuclei in a diamond by following the coherence evolution of an NV center spin qubit after a simple scheme is operated on the qubit to…

量子物理 · 物理学 2026-02-24 Mateusz Kuniej , Katarzyna Roszak

Spectral analysis of electron spin resonance (ESR) is a powerful technique for various investigations including characterization of spin systems, measurements of spin concentration, and probing spin dynamics. The nitrogen-vacancy (NV)…

介观与纳米尺度物理 · 物理学 2019-07-19 Benjamin Fortman , Susumu Takahashi

The use of nitrogen-vacancy centers in diamond as a non-invasive platform for hyperpolarizing nuclear spins in molecular samples is a promising area of research with the potential to enhance the sensitivity of nuclear magnetic resonance…

量子物理 · 物理学 2024-08-08 H. Espinós , C. Munuera-Javaloy , I. Panadero , P. Acedo , R. Puebla , J. Casanova , E. Torrontegui

The hyperpolarization of nuclear spins can enable powerful imaging and sensing techniques provided the hyperpolarization is sufficiently long-lived. Recent experiments on nanodiamond $^{13}$C nuclear spins demonstrate that relaxation times…

介观与纳米尺度物理 · 物理学 2024-02-20 Gargee Sharma , Torsten Gaebel , Ewa Rej , David J. Reilly , Sophia E. Economou , Edwin Barnes

Harnessing dipolar spin environments as controllable quantum resources is a central challenge in solid-state quantum technologies. Here, we report the observation of a coherent mesoscopic spin state in a disordered ensemble of…

量子物理 · 物理学 2026-02-20 Taewoong Yoon , Sangwon Oh , Junghyun Lee , Hyunyong Choi