相关论文: P1 center electron spin clusters are prevalent in …
NV-diamonds have attracted keen interest for nanoscale sensing and spin manipulation. In particular, the non-equilibrium electron spin polarization after optical excitation of single NV centers has successfully been transferred to nuclear…
Dynamical nuclear polarisation (DNP) is an important technique that uses polarisation transfer from electron to nuclear spins to achieve nuclear hyperpolarisation. As the electron spin of the nitrogen vacancy (NV) centres in diamond can be…
Coherence times of spin qubits in solid-state platforms are often limited by the presence of a spin bath. While some properties of these typically dark bath spins can be indirectly characterized via the central qubit, it is important to…
Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…
Optically-pumped color centers in semiconductor powders can potentially induce high levels of nuclear spin polarization in surrounding solids or fluids at or near ambient conditions, but complications stemming from the random orientation of…
Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most…
Hyperpolarisation at room temperature is one of the most important research fields in order to improve liquid, gas or nanoparticle tracer for Magnetic Resonance Imaging (MRI) in medical applications. In this paper we utilize nuclear…
We use microwave-induced dynamic nuclear polarization (DNP) of the substitutional nitrogen defects (P1 centers) in diamond to hyperpolarize bulk $^{13}$C nuclei in both single crystal and powder samples at room temperature at 3.34 T. The…
Dynamic nuclear polarization (DNP) can increase nuclear magnetic resonance (NMR) signals by orders of magnitude. DNP in diamond proceeds through different DNP mechanisms with a possible temperature-dependence. We report on 13C dynamic…
We report polarization of a dense nuclear-spin ensemble in diamond and its dependence on magnetic field and temperature. The polarization method is based on the transfer of electron spin polarization of negatively charged nitrogen vacancy…
We perform sensitive nuclear magnetic resonance (NMR) with spin ensembles which are polarized by nitrogen vacancy centers (NV centers) in diamond at room-temperature. With a near shot-noise-limited photoluminescence detection and a highly…
The inhomogeneous distribution of P1 centers in type 1b HPHT diamond samples allows multiple DNP mechanisms to occur within the same crystal, resulting in complex DNP spectra. At some crystal orientations, different DNP mechanisms can…
Substitutional nitrogen atoms in a diamond crystal (P1 centers) are, on one hand, a resource for creation of nitrogen-vacancy (NV) centers, that have been widely employed as nanoscale quantum sensors. On the other hand, P1's electron spin…
Polarizing nuclear spins is of fundamental importance in biology, chemistry and physics. Methods for hyperpolarizing 13C nuclei from free electrons in bulk, usually demand operation at cryogenic temperatures. Room-temperature approaches…
Color-center-hosting semiconductors are emerging as promising source materials for low-field dynamic nuclear polarization (DNP) at or near room temperature, but hyperfine broadening, susceptibility to magnetic field heterogeneity, and…
After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…
We report a versatile method to efficiently polarize single nuclear spins in diamond, which is based on optical pumping of a single NV color center and mediated by a level-anti crossing in its excited state. A nuclear spin polarization…
One of the most remarkable properties of the nitrogen-vacancy (NV) center in diamond is that optical illumination initializes its electronic spin almost completely, a feature that can be exploited to polarize other spin species in their…
The sharp optical resonances of NV- centers in diamond at cryogenic temperatures offer powerful new capabilities for material characterization, but extracting the most detailed information typically requires careful calibration of…
Dynamic Nuclear Polarization (DNP) presently stands as the preferred strategy to enhance the sensitivity of nuclear magnetic resonance measurements, but its application relies on the use of high-frequency microwave to manipulate electron…