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Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical…

星系天体物理 · 物理学 2022-07-04 Juris Kalvāns , Kedron Silsbee

Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such as dark and translucent clouds. Yet the picture of organic…

Our current understanding of interstellar carbon fractionation hinges on the interpretation of astrochemical kinetic models. Yet, the various reactions included carry large uncertainties in their (estimated) rate coefficients, notably those…

星系天体物理 · 物理学 2021-03-24 C. M. R. Rocha , H. Linnartz

A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…

星系天体物理 · 物理学 2022-02-23 Robin T. Garrod , Mihwa Jin , Kayla A. Matis , Dylan Jones , Eric R. Willis , Eric Herbst

Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar…

星系天体物理 · 物理学 2023-07-19 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

Complex organic molecules (COMs) are thought to form on icy dust grains in the earliest phase of star formation. The evolution of these COMs from the youngest Class 0/I protostellar phases toward the more evolved Class II phase is still not…

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…

星系天体物理 · 物理学 2017-05-23 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

The mobility of lighter species on the surface of interstellar dust grains plays a crucial role in forming simple through complex molecules. Carbon monoxide is one of the most abundant molecules, its surface diffusion on the grain surface…

星系天体物理 · 物理学 2022-03-30 Kinsuk Acharyya

Complex organic molecules (COMs) have been detected in a variety of interstellar sources. The abundances of these COMs in warming sources can be explained by syntheses linked to increasing temperatures and densities, allowing quasi-thermal…

星系天体物理 · 物理学 2020-11-18 Alec Paulive , Christopher N. Shingledecker , Eric Herbst

Cosmic rays are able to heat interstellar dust grains. This may enhance molecule mobility in icy mantles that have accumulated on the grains in dark cloud cores. A three-phase astrochemical model was used to investigate the molecule…

星系天体物理 · 物理学 2018-03-14 Juris Kalvans

Thanks to the advent of sensitive and broad bandwidth instrumentation, complex organic molecules (COMs) have been found in a wide variety of interstellar environments, not only in our Galaxy but also in external galaxies up to a redshift of…

星系天体物理 · 物理学 2025-03-24 Izaskun Jimenez-Serra , Claudio Codella , Arnaud Belloche

Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds, suggesting that these interstellar species originate from the early stage(s) of starformation. The reaction pathways…

太阳与恒星天体物理 · 物理学 2020-04-08 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , C. Jäger , Th. Henning , M. E. Palumbo , E. F. van Dishoeck , H. Linnartz

Hydrogenated amorphous carbon (a-C:H) has been proposed as one of the carbonaceous solids detected in the interstellar medium. Energetic processing of the a-C:H particles leads to the dissociation of the C-H bonds and the formation of…

地球与行星天体物理 · 物理学 2016-06-22 Rafael Martín-Doménech , Emmanuel Dartois , Guillermo M. Muñoz Caro

The chemical inventory of protoplanetary midplanes is the basis for forming planetesimals. Among them, solid-state reactions based on CO/CO$_2$ toward molecular complexity on interstellar dust grains have been studied in theoretical and…

太阳与恒星天体物理 · 物理学 2023-10-31 K. -J. Chuang , C. Jaeger , N. -E. Sie , C. -H. Huang , C. -Y. Lee , Y. -Y. Hsu , Th. Henning , Y. -J. Chen

The biological molecules delivered to Earth on the board of meteorites and comets were called one of the possible causes of the origin of life. Therefore, our understanding of the routes of formation of biomolecules in space should shed the…

地球与行星天体物理 · 物理学 2021-03-29 Serge A. Krasnokutski

Reactions occurring on the ice-covered surfaces of interstellar dust grains are considered to be among the most important sources of complex species in the interstellar medium. Despite this, molecules such as cyanamide, NH2CN, are largely…

星系天体物理 · 物理学 2026-04-20 Kevin M. Hickson , Jean-Christophe Loison , Audrey Coutens

The interactions of atomic and molecular hydrogen with bare interstellar dust grain surfaces are important for understanding H2 formation at relatively high temperatures (>20 K). We investigate the diffusion of physisorbed H atoms and the…

星系天体物理 · 物理学 2019-11-14 Masashi Tsuge , Tetsuya Hama , Yuki Kimura , Akira Kouchi , Naoki Watanabe

The interstellar medium contains dust and gas, in which at high densities and cold conditions molecules can proliferate. Interstellar Complex Organic Molecules (iCOMs) are C-bearing species that contain at least six atoms. As they are…

The mobility of O atoms at very low temperatures is not generally taken into account, despite O diffusion would add to a series of processes leading to the observed rich molecular diversity in space. We present a study of the mobility and…

星系天体物理 · 物理学 2014-02-11 M. Minissale , E. Congiu , F. Dulieu

The detection of complex organic molecules (COMs) toward dense, collapsing prestellar cores has sparked interest in the fields of astrochemistry and astrobiology, yet the mechanisms for COM formation are still debated. It was originally…

星系天体物理 · 物理学 2023-04-05 Samantha Scibelli , Yancy Shirley