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The transport of polyelectrolytes confined by oppositely charged surfaces and driven by a constant electric field is of interest in studies of DNA separation according to size. Using molecular dynamics simulations that include surface…

软凝聚态物质 · 物理学 2020-09-15 Debarshee Bagchi , Monica Olvera de la Cruz

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

软凝聚态物质 · 物理学 2021-03-03 Michiel Sprik

We present a novel microfield approach for studying the dependence of the orientational polarization of the water in aqueous electrolyte solutions upon the salt concentration and temperature. The model takes into account the orientation of…

化学物理 · 物理学 2016-07-15 Nir Gavish , Keith Promislow

The electric and magnetic fields are investigated on the basis of quantum vacuum. The analysis of the electromagnetic energy and force indicates that an electric field is a polarized distribution of the vacuum virtual dipoles, and that a…

综合物理 · 物理学 2009-08-22 Xing-Hao Ye

We characterize the dynamics of an electrolyte embedded in a varying-section channel under the action of a constant external electrostatic field. By means of molecular dynamics simulations we determine the stationary density, charge and…

软凝聚态物质 · 物理学 2018-10-31 Mauro Chinappi , Paolo Malgaretti

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

统计力学 · 物理学 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

The control of the dielectric and conductive properties of device-level systems is important for increasing the efficiency of energy- and information-related technologies. In some cases, such as neuromorphic computing, it is desirable to…

介观与纳米尺度物理 · 物理学 2020-07-28 Dimitrios Fraggedakis , Mohammad Mirzadeh , Tingtao Zhou , Martin Z. Bazant

The effects of the discharge voltage on the formation and nature of electric field transients in a symmetric, collisionless, very high frequency, capacitively coupled plasma are studied using a self-consistent particle-in-cell (PIC)…

等离子体物理 · 物理学 2019-07-24 Sarveshwar Sharma , N. Sirse , A. Sen , J. S. Wu , M. M. Turner

The electric dipole moment of an electron (eEDM) is one of the sensitive probes of physics beyond the standard model. The possible existence of the eEDM gives rise to an experimentally observed energy shift, which is proportional to the…

计算物理 · 物理学 2017-01-18 A. Sunaga , M. Abe , M. Hada , B. P. Das

Nonlinear field dependence of electrophoresis in high fields has been investigated theoretically, yet experimental studies have failed to reach consensus on the effect. In this work, we present a systematic study on the nonlinear…

软凝聚态物质 · 物理学 2019-07-10 Soichiro Tottori , Karolis Misiunas , Ulrich F. Keyser , Douwe Jan Bonthuis

The mechanisms of electrostatic interactions between two charged dielectric spheres inside a polarizable medium have been investigated, in terms of hypothetical effective dipoles that depict how the positive and negative charge in each…

软凝聚态物质 · 物理学 2025-02-06 Yanyu Duan , Zecheng Gan , Ho-Kei Chan

An external electric field changes the physical properties of polar-liquids due to the reorientation of their permanent dipoles. For example it should affect significantly the physical properties of water confined in a nanochannel. The…

介观与纳米尺度物理 · 物理学 2016-08-03 Sobrino Fernández Mario , M. Neek-Amal , F. M. Peeters

A simple and robust electrode insulation technique that can withstand a voltage as high as $\mathrm{1000~V}$, which is equivalent to an electric field strength of $\sim 1MV/m$ across a $\mathrm{10~\mu m}$ channel filled with an electrolyte…

Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…

软凝聚态物质 · 物理学 2025-02-04 Ali Behjatian , Ralf Blossey , Madhavi Krishnan

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

流体动力学 · 物理学 2022-06-08 Jean-Philippe Péraud , Andy Nonaka , John B. Bell , Aleksandar Donev , Alejandro L. Garcia

Electrophoresis is a motion of charged dispersed particles relative to a fluid in a uniform electric field. The effect is widely used to separate macromolecules, to assemble colloidal structures, to transport particles in nano- and…

软凝聚态物质 · 物理学 2011-01-21 Oleg D. Lavrentovich , Israel Lazo , Oleg P. Pishnyak

We propose a fully ab initio theory to compute the electron density response under the perturbation in the local field. This method is based on our recently developed local dielectric response theory [Phys. Rev. B 92, 241107(R), 2015],…

材料科学 · 物理学 2020-02-18 Xiaochuan Ge , Deyu Lu

Electrode polarization error is the biggest problem when measuring the low frequency dielectric properties of electrolytes or suspensions of particles, including cells, in electrolytes. We present a simple and robust method to remove the…

软凝聚态物质 · 物理学 2008-05-13 Camelia Prodan , Corina Bot

We study the electrode polarization behaviour of different Na-Ca-phosphosilicate glasses by measuring the differential capacitance between blocking Pt electrodes. At low applied dc bias voltages, we detect a linear capacitance regime with…

无序系统与神经网络 · 物理学 2009-11-11 C. R. Mariappan , T. P. Heins , B. Roling

Supercapacitors have been attracting significant attention as promising energy storage devices. However, the voltage window limitation associated with electrolyte solutions has hindered the improvement of their capacitance. To address this…

化学物理 · 物理学 2023-06-27 Weihang Gao , Teng Zhao , Shian Dong , Xingyi Huang , Zhenli Xu
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