相关论文: Discovery of the elusive carbonic acid (HOCOOH) in…

We studied theoretically the cis-trans isomerization reactions of two astrophysically relevant acids, formic acid (HCOOH) and thioformic acid (HC(O)SH), where the latter has recently been discovered in space. We also searched for these…

In the interstellar medium, formic acid (HCOOH) plays a significant role in the synthesis of the simplest amino acid, glycine (NH$_{2}$CH$_{2}$COOH). The presence of HCOOH suggests that oxygen-bearing molecules may be directly involved in…

We present the first detection in space of O-protonated carbonyl sulfide (\ch{HOCS+}), in the midst of an ultradeep molecular line survey toward the G+0.693-0.027 molecular cloud. From the observation of all $K$$_a$ = 0 transitions ranging…

Acetic acid (CH$_3$COOH) has been detected mainly in hot molecular cores where the distribution between oxygen (O) and nitrogen (N) containing molecular species is co-spatial within the telescope beam. Previous work has presumed that…

The molecular species hydrogen peroxide, HOOH, is likely to be a key ingredient in the oxygen and water chemistry in the interstellar medium. Our aim with this investigation is to determine how abundant HOOH is in the cloud core {\rho} Oph…

Aims. Our aim is to confirm the interstellar detection of cyanic acid, HOCN, in the Galactic center clouds. It has previously been tentatively detected only in Sgr B2(OH). Methods. We used a complete line survey of the hot cores Sgr B2(N)…

The abundance ratios between isomers of a COM observed in the ISM provides valuable information about the chemistry and physics of the gas and eventually, the history of molecular clouds. In this context, the origin of an abundance of…

Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated…

The tentative detection of 3-hydroxypropanal (HO(CH$_2$)$_2$C(O)H) toward the Galactic center molecular cloud G+0.693-0.027 prompts a systematic survey in this source aimed at detecting all C$_3$H$_6$O$_2$ isomers with available…

We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and…

As many organic molecules, formic acid (HCOOH) has two conformers (trans and cis). The energy barrier to internal conversion from trans to cis is much higher than the thermal energy available in molecular clouds. Thus, only the most stable…

The formation of asteroids, comets and planets occurs in the interior of protoplanetary disks during the early phase of star formation. Consequently, the chemical composition of the disk might shape the properties of the emerging planetary…

The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling…

With the recent radioastronomical detection of cis-trans-carbonic acid (H$_2$CO$_3$) in a molecular cloud toward the galactic center, the more stable but currently unobserved cis-cis conformer is shown here to have strong IR features. While…

Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…

Atomic carbon ([CI]) is a key species in the carbon chemistry of the interstellar medium (ISM). Using the Submillimeter Wave Astronomy Satellite (SWAS), we conducted a [CI]($^3$P$_1$--$^3$P$_0$) 492 GHz survey covering approximately 4…

Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…

Isocyanic acid (HNCO), the most stable of the simplest molecules containing the four main elements essential for organic chemistry, has been observed in several astrophysical environments such as molecular clouds, star-forming regions,…

We report the detection of the carbon-chain radical HC$_5$O for the first time in the interstellar medium toward the dark cloud TMC-1 using the 100 m Green Bank Telescope. We observe four hyperfine components of this radical in the $J =…

The rotational transitions of carbon monoxide (CO) are the primary means of investigating the density and velocity structure of the molecular interstellar medium. Here we study the lowest four rotational transitions of CO towards…