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Atomic disorder, a widespread problem in compound crystalline materials, is a imperative affecting the performance of multi-chalcogenide Cu2ZnSn(S, Se)4 (CZTSSe) photovoltaic device known for its low cost and environmental friendliness.…

Cu2ZnSn(S, Se)4 (CZTSSe) is one of most competitive photovoltaic materials for its earth-abundant reserves, environmental friendliness, and high stability.The quality of CZTSSe absorber determines the power-conversion efficiency (PCE) of…

Kesterite is a leading candidate among inorganic thin-film photovoltaic technologies, offering sustainable and environmentally friendly solutions without reliance on critical raw materials. This study investigates the performance of…

Aqueous precursors provide an alluring approach for low-cost and environmentally friendly production of earth-abundant Cu2ZnSn(S,Se)4 (CZTSSe) solar cells. The key is to find an appropriate molecular agent to prepare a stable solution and…

Cu2ZnSnS(e)4 (CZTS(e)) solar cells have attracted much attention due to the elemental abundance and the non-toxicity. However, the record efficiency of 12.6% for Cu2ZnSn(S,Se)4 (CZTSSe) solar cells is much lower than that of Cu(In,Ga)Se2…

应用物理 · 物理学 2018-03-14 Shoushuai Gao , Zhenwu Jiang , Li Wu , Jianping Ao , Yu Zeng , Yun Sun , Yi Zhang

Flexible Cu2ZnSn(S, Se)4 (CZTSSe) solar cells take the advantages of environmental friendliness, low cost, and multi-scenario applications, and have drawn extensive attention in recent years. Compared with rigid devices, the lack of alkali…

The monolithic tandem integration of third-generation solar energy materials on silicon holds great promise for photoelectrochemistry and photovoltaics. However, this can be challenging when it involves high-temperature reactive processes,…

Dual-absorber solar cells represent a promising approach to surpass the efficiency limit of single-junction devices by extending spectral absorption and minimizing thermalization losses. Among earth-abundant thin-film materials, kesterites…

材料科学 · 物理学 2025-11-14 Hasib Md Abid Bin Farid , Md Tashfiq Bin Kashem

Thin-film solar cells based on kesterite (Cu2ZnSnSe4) material are a promising alternative for photovoltaic devices due to their composition consisting of earth abundant elements, ease of production at a relatively low temperatures and…

In kesterite CZTSSe solar cell research, an asymmetric crystallization profile is often obtained after annealing, resulting in a bilayered or double-layered absorber. So far, only segregated pieces of research exist to characterize this…

Solar cells based on kesterite-type $Cu_2ZnSnS_4$ (CZTS) thin films were fabricated using a chemical route to prepare the $CZTS$ films, consisting in sequential deposition of $Cu_2SnS_3$ (CTS) and $ZnS$ thin films followed by annealing at…

应用物理 · 物理学 2019-08-06 John M. Correa , Raúul A. Becerra , Asdrubal A. Ramírez , Gerardo Gordillo

Ternary chalcostibite copper antimony selenide (CuSbSe2) is a promising absorber material for next generation thin film solar cells due to the non-toxic nature, earth-abundance, low-cost fabrication technique, optimum bandgap and high…

Phase evolution during the selenization is crucial for high-quality kesterite Cu2ZnSn(S, Se)4 (CZTSSe) absorbers and efficient solar cells. Herein, we regulate kinetic process of phase evolution from Cu+-Sn4+-MOE (MOE: 2-methoxyethanol)…

A coupled optoelectronic model was implemented along with the differential evolution algorithm to assess the efficacy of grading the bandgap of the CZTSSe layer for enhancing the power conversion efficiency of thin-film CZTSSe solar cells.…

应用物理 · 物理学 2020-04-07 Faiz Ahmad , Akhlesh Lakhtakia , Tom H. Anderson , Peter B. Monk

Thin-film solar cells based on the semiconductor Cu$_2$ZnSnS$_4$ (CZTS) are a promising candidate for Terawatt-scale renewable energy generation. While CZTS is composed of earth abundant and non-toxic elements, arranged in the kesterite…

材料科学 · 物理学 2014-04-02 Adam J. Jackson , Aron Walsh

The limiting factor preventing kesterite (CZTSSe) thin film solar cell performance further improvement is the large open-circuit voltage deficit (Voc,def) issue, which is 0.345V for the current world record device with an efficiency of…

CdTe is one of the leading materials for low cost, high efficiency thin-film solar cells, because it has a high absorption coefficient and a nearly ideal band gap of 1.48 eV for solar cell according to the Shockley-Queisser limit. However,…

材料科学 · 物理学 2019-08-14 Jingxiu Yang , Su-Huai Wei

Cu2ZnSnS4 (CZTS) is a promising candidate as an absorber material for thin film solar cells. The reported wet chemical synthesis approaches often have a high environmental impact due to the usage of abrasive solvents such as hydrazines,…

材料科学 · 物理学 2015-10-20 Atul Kumar , Anup V. Sanchela , C. V. Tomy , Ajay D. Thakur

CdTe-based thin film solar cell has been modeled and enumerated with a thin CuInTe2 (CIT) current booster layer. CdTe-based n-CdS/p-CdTe/p+-CIT/p++-WSe2 heterojunction device has been evaluated for the highest performance. It is revealed…

We considered modification of the defect density of states in CdTe as influenced by a buffer layer in ZnO(ZnS, SnSe)/CdS/CdTe solar cells. Compared to the solar cells employing ZnO buffer layers, implementation of ZnSe and ZnS resulted in…

材料科学 · 物理学 2016-01-15 Y. G. Fedorenko , J. D. Major , A. Pressman , L. Phillips , K. Durose
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