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Recently, atomically thin PdSe$_2$ semiconductors with rare pentagonal Se-Pd-Se monolayers were synthesized and were also found to possess superior properties such as ultrahigh air stability, and high carrier mobility, thus offering a new…

材料科学 · 物理学 2021-09-21 Vijay Kumar Gudelli , Guang-Yu Guo

The bulk photovoltaic effect (BPVE) is a second-order optical process in noncentrosymmetric materials that converts the light into DC currents. BPVE is classified into shift current and injection current according to the generation…

材料科学 · 物理学 2023-02-21 Hanqi Pi , Shuai Zhang , Hongming Weng

In future solar cell technologies, the thermodynamic Shockley-Queisser limit for solar-to-current conversion in traditional p-n junctions could potentially be overcome with a bulk photovoltaic effect by creating an inversion broken symmetry…

Converting light into steady currents and spin-currents in two-dimensional (2D) platform is essential for future energy harvesting and spintronics. We show that the giant and modulable bulk photovoltaic effects (BPVEs) can be achieved in…

材料科学 · 物理学 2023-01-10 Liang Liu , Weikang Liu , Bin Cheng , Bin Cui , Jifan Hu

Two-dimensional ferroelectrics have recently emerged as a promising avenue for next-generation optoelectronic and photovoltaic devices. Due to the intrinsic absence of inversion symmetry, 2D ferroelectrics exhibit bulk photovoltaic effect…

材料科学 · 物理学 2025-12-08 Francesco Delodovici , Brahim Dkhil , Charles Paillard

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

材料科学 · 物理学 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

介观与纳米尺度物理 · 物理学 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

The bulk photovoltaic effect (BPVE) refers to the direct current generation in a noncentrosymmetric material under illumination and can be applied to solar energy technology. BPVE includes injection and shift currents, led by the change of…

介观与纳米尺度物理 · 物理学 2025-11-04 Bo-Xin Lin , Hsiu-Chuan Hsu

The bulk photovoltaic effect (BPVE) offers a promising avenue to surpass the efficiency limitations of current solar cell technology. However, disentangling intrinsic and extrinsic contributions to photocurrent remains a significant…

The bulk photovoltaic effect (BPVE) generates a direct current photocurrent under uniform irradiation and is a nonlinear optical effect traditionally studied in non-centrosymmetric materials. The two main origins of BPVE are the shift and…

介观与纳米尺度物理 · 物理学 2025-03-03 Ying-Ming Xie , Naoto Nagaosa

A bulk material without inversion symmetry can generate a direct current under illumination. This interface-free current generation mechanism, referred to as the bulk photovoltaic effect (BPVE), does not rely on $p$-$n$ junctions. Here, we…

材料科学 · 物理学 2023-05-01 Zhuang Qian , Jian Zhou , Hua Wang , Shi Liu

The bulk photovoltaic (BPV) effect that converts light into electric current is highly sensitive to the system symmetry and its electronic Bloch wavefunction. To create a sizable net electric current, it is necessary to break the…

材料科学 · 物理学 2024-07-08 Chunmei Zhang , Jian Zhou

The bulk photovoltaic effect (BPVE) occurs in solids with broken inversion symmetry and refers to DC current generation due to uniform illumination, without the need of heterostructures or interfaces, a feature that is distinct from the…

材料科学 · 物理学 2022-06-02 Zhenbang Dai , Andrew M. Rappe

The bulk photovoltaic effect that is intimately associated with crystalline symmetry has been extensively studied in various nonmagnetic materials, especially ferroelectrics with a switchable electric polarization. In order to further…

材料科学 · 物理学 2022-12-28 Chunmei Zhang , Ping Guo , Jian Zhou

Spontaneous polarization and bulk photovoltaic effect (BPVE) are two concomitant physical properties in ferroelectric materials. The flipping of ferroelectric order usually accompanies with the switching of BPVE as both of them are reversed…

材料科学 · 物理学 2022-07-04 Rui-Chun Xiao , Yang Gao , Hua Jiang , Wei Gan , Changjin Zhang , Hui Li

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

材料科学 · 物理学 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

Weyl semimetals are gapless topological states of matter with broken inversion and/or time reversal symmetry, which can support unconventional responses to externally applied electrical, optical and magnetic fields. Here we report a new…

We elucidate light-induced orbital and spin current through nonlinear response theory, which generalizes the well-known bulk photovoltaic effect in centrosymmetric broken materials from charge to the spin and orbital degrees of freedom. We…

材料科学 · 物理学 2021-08-30 Xingchi Mu , Jian Zhou

Broadband, efficient and fast conversion of light to electricity is crucial for sensing and clean energy. Here we reveal the largest observed bulk photo-voltaic effect (BPVE), an intrinsic mechanism predicted to be ultrafast and exceed the…

The bulk photovoltaic effect (BPVE) -- generation of electric currents by light in noncentrosymmetric materials in the absence of electric fields and gradients -- has been intensively investigated in the end of the last century. The…

介观与纳米尺度物理 · 物理学 2019-11-28 Boris Sturman
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