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CuInP2S6 (CIPS) is an emerging layered material that exhibits ferrielectric ordering well above room temperature (Curie temperature TC ~ 315 K). When synthesized with Cu deficiencies, CIPS spontaneously segregates into CuInP2S6 and…

材料科学 · 物理学 2021-11-02 Rahul Rao , Ryan Selhorst , Benjamin S. Conner , Michael A. Susner

Layered multi-ferroic materials exhibit a variety of functional properties that can be tuned by varying the temperature and pressure. As-synthesized CuInP$_2$S$_6$ is a layered material that displays ferrielectric behavior at room…

材料科学 · 物理学 2022-01-05 Rahul Rao , Benjamin S. Conner , Ryan Selhorst , Michael A. Susner

The layered van der Waals (vdW) ferroelectric CuInP2S6 (CIPS) exhibits unique cation hopping-driven phenomena that bring about unconventional properties with intriguing mechanisms and hold promises for advanced applications in…

Two dimensional ferroic materials exhibit a variety of functional properties that can be tuned by temperature and pressure. CuInP2S6 is a layered material that is ferrielectric at room temperature and whose properties are a result of the…

材料科学 · 物理学 2023-06-14 R. Rao , B. S. Conner , J. Jiang , R. Pachter , M. A. Susner

Using Landau-Ginsburg-Devonshire approach and available experimental results we reconstruct the thermodynamic potential of the layered ferroelectric CuInP$_2$S$_6$ (CIPS), which is expected to be applicable a wide range of temperatures and…

Strain-induced transitions of polarization reversal in thin films of a ferrielectric CuInP$_2$S$_6$ (CIPS) with ideally-conductive electrodes is explored using the Landau-Ginzburg-Devonshire (LGD) approach with an eighth-order free energy…

In this work, we performed temperature-dependent Raman spectroscopy studies on three layered metal thiophosphates: CuInP2S6, CuCrP2S6, and CuInP2S6-In4/3P2S6 heterostructures. These materials are emerging multiferroics, with CuInP2S6 and…

材料科学 · 物理学 2022-12-29 Rahul Rao , Michael A. Susner

The two-dimensional ferroelectric (FE) material CuInP$_2$S$_6$ (CIPS) has garnered considerable interest due to its out-of-plane ferroelectricity at room temperature. However, a notable discrepancy exists between experiments and density…

材料科学 · 物理学 2026-03-27 Shengxian Li , Jiaren Yuan , Tao Ouyang , Anlian Pan , Mingxing Chen

The chalcopyrite Cu(In,Ga)S${_2}$ has gained renewed interest in recent years due to the potential application in tandem solar cells. In this contribution, a combined theoretical and experimental approach is applied to investigate stable…

Nanoscale ferroelectric 2D materials offer unique opportunity to investigate curvature and strain effects on materials functionalities. Among these, CuInP2S6 (CIPS) has attracted tremendous research interest in recent years due to…

Using the Landau-Ginzburg-Devonshire phenomenological approach we explore the strain-polarization coupling in the low-dimensional van der Waals ferrielectrics. We evolve the analytical model of the piezoelectric susceptibility of the…

Van der Waals (vdW) layered materials have rather weaker interlayer bonding than the intra-layer bonding, therefore the exfoliation along the stacking direction enables the achievement of monolayer or few layers vdW materials with emerging…

2D layered ferroelectric materials such as CuInP$_2$S6 (CIPS) are promising candidates for novel and high-performance photocatalysts, owning to their ultrathin layer thickness, strong interlayer coupling, and intrinsic spontaneous…

材料科学 · 物理学 2023-01-26 Fanyi Kong , Lei Zhang , Tianze Cong , Zhiwei Wu , Kun Liu , Changsen Sun , Lujun Pan , Dawei Li

Intelligent reflecting surface (IRS) has been recognized as a powerful technology for boosting communication performance. To reduce manufacturing and control costs, it is preferable to consider discrete phase shifts (DPSs) for IRS, which…

信息论 · 计算机科学 2023-11-07 Guojie Hu , Qingqing Wu , Dognhui Xu , Kui Xu , Jiangbo Si , Yunlong Cai , Naofal Al-Dhahir

In order to explore the properties of a two-sublattice ferroelectric, we measured the infrared and Raman scattering response of CuInP2S6 across the ferroelectric and glassy transitions and compared our findings to a symmetry analysis,…

Using Landau-Ginzburg-Devonshire (LGD) phenomenological approach we analyze the bending-induced re-distribution of electric polarization and field, elastic stresses and strains inside ultrathin layers of van der Waals ferrielectrics. We…

CuCrP$_2$S$_6$ (CCPS), a type-II multiferroic material, exhibits unique phase transitions involving ferroelectric, antiferroelectric, and antiferromagnetic ordering. In this study, we conduct a comprehensive investigation on the intricate…

The interest in ferroelectric van der Waals crystals arises from the potential to realize ultrathin ferroic systems owing to the reduced surface energy of these materials and the layered structure that allows for exfoliation. Here, we…

We present measurements of the optical spectra on single crystals of spinel-type compound \cis. This material undergoes a sharp metal-insulator transition at 230 K. Upon entering the insulating state, the optical conductivity shows an…

强关联电子 · 物理学 2009-11-10 N. L. Wang , G. H. Cao , P. Zheng , G. Li , Z. Fang , T. Xiang , H. Kitazawa , T. Matsumoto

Tunable optical materials are indispensable elements in modern optoelectronics, especially in integrated photonics circuits where precise control over the effective refractive index is essential for diverse applications. Two-dimensional…

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