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We investigate the heterogeneous dynamics in a model, where chemical gelation and glass transition interplay, focusing on the dynamical susceptibility. Two independent mechanisms give raise to the correlations, which are manifested in the…

软凝聚态物质 · 物理学 2017-05-09 Antonio de Candia , Annalisa Fierro , Raffaele Pastore , Massimo Pica Ciamarra , Antonio Coniglio

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

统计力学 · 物理学 2015-06-23 Mikhail Vasin

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

材料科学 · 物理学 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

We use coherent X-rays to probe the aging dynamics of a metallic glass directly on the atomic level. Contrary to the common assumption of a steady slowing down of the dynamics usually observed in macroscopic studies, we show that the…

When a liquid freezes, a change in the local atomic structure marks the transition to the crystal. When a liquid is cooled to form a glass, however, no noticeable structural change marks the glass transition. Indeed, characteristic features…

软凝聚态物质 · 物理学 2015-11-24 Samuel S. Schoenholz , Ekin D. Cubuk , Daniel M. Sussman , Efthimios Kaxiras , Andrea J Liu

The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…

软凝聚态物质 · 物理学 2017-03-08 Samuel S. Schoenholz , Ekin D. Cubuk , Efthimios Kaxiras , Andrea J. Liu

The most puzzling aspect of the glass transition observed in laboratory is an apparent decoupling of dynamics from structure. In this paper we recount the implication of various theories of glass transition for the static correlation length…

无序系统与神经网络 · 物理学 2017-02-08 S. Davatolhagh

As liquids approach the glass transition temperature, dynamical heterogeneity emerges as a crucial universal feature of their behavior. Dynamic facilitation, where local motion triggers further motion nearby, plays a major role in this…

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

无序系统与神经网络 · 物理学 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

Gaining fundamental understanding of crystal nucleation processes in metal alloys is crucial for the development and design of high-performance materials with targeted properties. Yet, crystallization is a complex non-equilibrium process…

材料科学 · 物理学 2022-12-09 Grisell Díaz Leines , Angelos Michaelides , Jutta Rogal

The relationship between the microscopic arrangement of molecules in a supercooled liquid and its slow dynamics at low temperature near glass transition is studied by Molecular Dynamics (MD) simulations. A Lennard-Jones liquid with…

软凝聚态物质 · 物理学 2009-11-13 Sneha Elizabeth Abraham , Biman Bagchi

The presence of dynamical heterogeneities, i.e. nanometer-scale regions containing molecules rearranging cooperatively at very different rates compared to the bulk, is increasingly being recognized as crucial in our understanding of the…

无序系统与神经网络 · 物理学 2015-06-25 Horacio E. Castillo , Azita Parsaeian

Metallic glasses possess outstanding mechanical and physical properties, making them promising candidates for advanced structural and functional applications; however, the lack of understanding and control over their glass transition and…

软凝聚态物质 · 物理学 2025-06-04 Wei Chu , Zheng Wang , Christopher Ness , Konrad Samwer , Alessio Zaccone , Lina Hu

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

材料科学 · 物理学 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

We investigate the influence of hydrogen on the electronic structure of a binary transition metallic glass of V$_{80}$Zr$_{20}$. We examine the hybridization between the hydrogen and metal atoms with the aid of hard x-ray photoelectron…

材料科学 · 物理学 2024-03-21 Johan Bylin , Rebecka Lindblad , Lennart Spode , Ralph H. Scheicher , Gunnar K. Pálsson

The atomic structure, electronic structure and physical properties of $(TiZrNbCu)_{(1-x)}Ni_x$ (x $\leq$ 0.5) metallic glasses (MG) were studied in both the high-entropy (0<x<0.35) and the higher Ni concentration range (x $\geq$ 0.35).…

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

统计力学 · 物理学 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

The glass transition remains unclarified in condensed matter physics. Investigating the mechanical properties of glass is challenging because any global deformation that may result in shear rejuvenation requires an astronomical relaxation…

软凝聚态物质 · 物理学 2020-07-21 Ji Woong Yu , S. H. E. Rahbari , Takeshi Kawasaki , Hyunggyu Park , Won Bo Lee

To experimentally clarify the changes in structural and dynamic heterogeneities in a metallic glass (MG), Gd65Co35, by rejuvenation with a temperature cycling (cryogenic rejuvenation), high-energy x-ray diffraction (HEXRD), anomalous x-ray…

We examine the structural relaxation of glassy materials at finite temperatures, considering the effect of activated rearrangements and long-range elastic interactions. Our three-dimensional mesoscopic relaxation model shows how the…

软凝聚态物质 · 物理学 2023-12-20 Gieberth Rodriguez-Lopez , Kirsten Martens , Ezequiel E. Ferrero