相关论文: Chemical equilibrium under vibrational strong coup…

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Experimental studies indicate that optical cavities can affect chemical reactions, through either vibrational or electronic strong coupling and the quantized cavity modes. However, the current understanding of the interplay between…

We discuss Floquet engineering of dissipative molecular systems through periodic driving of an infrared-active vibrational transition, either directly or via a cavity mode. Following a polaron quantum Langevin equations approach, we derive…

Modulational instabilities play a key role in a wide range of nonlinear optical phenomena, leading e.g. to the formation of spatial and temporal solitons, rogue waves and chaotic dynamics. Here we experimentally demonstrate the existence of…

We study the equilibrium properties of a system of dipole-active excitons coupled to a single photon mode at fixed total excitation. Treating the presence or absence of a trapped exciton as a two-level system produces a model that is…

We develop a comprehensive theoretical model for the interaction strength between a pair of exciton-polaritons in microcavity devices. Ab initio numerical calculations for dipolar polaritons in one dimension are used as a starting point to…

The interaction of quantum light with matter like that inside a cavity is known to give rise to mixed light-matter states called polaritons. We discuss the impact of rotation of the cavity on the polaritons. It is shown that the number of…

Interfacing materials with electromagnetic cavities offers a route to modify equilibrium properties through structured vacuum fluctuations. The coupling of light with correlated electrons lacks a characteristic energy scale, making vacuum…

Resonant coupling of a vibration to a cavity mode has been reported to dramatically modify spontaneous Raman scattering, but subsequent studies have produced conflicting results. In this Letter, we develop a microscopic quantum framework…

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Recent advances in polaritonic chemistry suggest that chemical reactions can be controlled via collective vibrational strong coupling (VSC) in a cavity. In this fully analytical work, we demonstrate that the collective vibrations of a…

We present a precise calculation of spatially-indirect exciton states in semiconductor coupled quantum wells and polaritons formed from their coupling to the optical mode of a microcavity. We include the presence of electric and magnetic…

Recently, we predicted theoretically that in cavities that support several longitudinal modes, strong coupling can occur in very different manners, depending on the system parameters. Distinct longitudinal cavity modes are either entangled…

We present a theory for rigorous quantum scattering calculations of probabilities for chemical reactions of atoms with diatomic molecules in the presence of an external electric field. The approach is based on the fully uncoupled basis set…

We introduce a prototypical model for cavity polaritonic control of ultracold photochemistry by considering the resonant vibrational strong coupling of a rubidium dimer to a terahertz cavity. We demonstrate that at avoided crossings between…

We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due…

We study a system of interacting matter quasiparticles strongly coupled to photons inside an optomechanical cavity. The resulting normal modes of the system are represented by hybrid polaritonic quasiparticles, which acquire effective…

Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since…

A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…

We investigate theoretically the polariton coupling between the light confined in a planar cavity and the intersubband transitions of a two-dimensional electron gas confined in semiconductor quantum wells in the presence of a vertical…