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We report on the crystal structure and ferroelectric properties of epitaxial ZrO$_2$ films ranging from 7 to 42 nm thickness grown on La$_{0.67}$Sr$_{0.33}$MnO$_3$-buffered (110)-oriented SrTiO$_3$ substrate. By employing X-ray diffraction,…

Interfacing two-dimensional bismuth with a magnetic layer provides a promising route towards realizing higher-order topological phases. In particular, bismuthene on a ferromagnetic insulator substrate has been theoretically proposed by…

介观与纳米尺度物理 · 物理学 2026-04-24 Subham Naskar , Sujit Manna

We demonstrate that SrRuO3 and CaRuO3 thin films undergo a room temperature structural phase transition driven by the substrate imposed epitaxial biaxial strain. As tensile strain increases, ARuO3 (A=Ca, Sr) films transform from the…

材料科学 · 物理学 2009-11-13 Arturas Vailionis , Wolter Siemons , Gertjan Koster

The interplay between spin-orbit coupling (SOC) and electron correlation ($U$) is considered for many exotic phenomena in iridium oxides. We have investigated the evolution of structural, magnetic and electronic properties in pyrochlore…

强关联电子 · 物理学 2017-03-08 Harish Kumar , R. S. Dhaka , A. K. Pramanik

Our single crystal study of the magneto-thermal and transport properties of the pyrochlore iridate Eu2Ir2O7 reveals a continuous phase transition from a paramagnetic metal to an antiferromagnetic insulator for a sample with stoichiometry…

强关联电子 · 物理学 2015-06-04 Jun J. Ishikawa , Eoin C. T. O'Farrell , Satoru Nakatsuji

The binary ruthenate, RuO$_2$, has been the subject of intense interest due to its itinerant antiferromagnetism and strain-induced superconductivity. The strain mechanism and its effect on the microscopic electronic states leading to the…

Various physical properties of the pyrochlore oxide Y2-xBixIr2O7 have been studied. The magnetizations M measured under the conditions of the zero-field-cooling(ZFC) and the field-cooling(FC) have different values below the temperature…

强关联电子 · 物理学 2009-11-10 Natsuki Aito , Minoru Soda , Yoshiaki Kobayashi , Masatoshi Sato

The possible existence of topological insulators in cubic pyrochlore iridates A$_{2}$Ir$_{2}$O$_{7}$ (A = Y or rare-earth elements) is investigated by taking into account the strong spin-orbit coupling and trigonal crystal field effect. It…

强关联电子 · 物理学 2015-03-14 Bohm-Jung Yang , Yong Baek Kim

Composition dependent Rayleigh and structural analysis was carried out on the lead-free piezoceramics (1-x)(BaTi0.88Sn0.12)-x(Ba0.7Ca0.3)TiO3 at room temperature. The system exhibits tetragonal (P4mm) structure for x > 0.21, rhombohedral…

材料科学 · 物理学 2017-09-20 Mulualem Abebe , Kumar Brajesh , Rajeev Ranjan

A study of impedance spectroscopy was done for the electrical characterization of pyrochlore materials. The experiment consisted of measurements of the dependence of the impedance of such systems with the temperature during heating (25 to…

Interdiffusion between the yttria stabilized zirconia (YSZ) electrolyte and the gadolinia doped ceria (CGO) barrier layer is one of the major causes to the degradation of solid oxide fuel cells (SOFCs). We present in this work experimental…

材料科学 · 物理学 2019-11-22 Huixia Xu , Kaiming Cheng , Ming Chen , Lijun Zhang , Karen Brodersen , Yong Du

Thin layers of orthorhombic uranium ({\alpha}-U) have been grown onto buffered sapphire substrates by d.c. magnetron sputtering, resulting in the discovery of new epitaxial matches to Ti(00.1) and Zr(00.1) surfaces. These systems have been…

材料科学 · 物理学 2023-08-09 R. Nicholls , D. A. Chaney , G. H. Lander , R. Springell , C. Bell

Piezoelectrics interconvert mechanical energy and electric charge and are widely used in actuators and sensors. The best performing materials are ferroelectrics at a morphotropic phase boundary (MPB), where several phases can intimately…

We report the single-crystal X-ray analysis of the structure of the pyrochlore oxide superconductor KOs$_2$O$_6$. The structure was identified as the $\beta$-pyrochlore structure with space group $Fd\bar{3}m$ and lattice constant $a$ =…

超导电性 · 物理学 2009-11-11 Jun-Ichi Yamaura , Shigeki Yonezawa , Yuji Muraoka , Zenji Hiroi

Effect of structural disorder is investigated for an $XY$ pyrochlore antiferromagnet with continuous degeneracy of classical ground states. Two types of disorder, vacancies and weakly fluctuating exchange bonds, lift degeneracy selecting…

强关联电子 · 物理学 2014-09-26 V. S. Maryasin , M. E. Zhitomirsky

Density functional calculations are performed to investigate the experimentally-reported field-induced phase transition in thin-film ZrO2 (J. Muller et al., Nano. Lett. 12, 4318). We find a small energy difference of ~ 1 meV/f.u. between…

材料科学 · 物理学 2014-10-22 Sebastian E. Reyes-Lillo , Kevin F. Garrity , Karin M. Rabe

We present a structural analysis of the substituted system (Ba$_{1-x}$Sr$_{x}$)CuSi$_{2}$O$_{6}$, which reveals a stable tetragonal crystal structure down to 1.5 K. We explore the structural details with lowtemperature neutron and…

Fully relativistic first-principles electronic structure calculations based on a noncollinear local spin density approximation (LSDA) are performed for pyrochlore iridates Y$_2$Ir$_2$O$_7$ and Pr$_2$Ir$_2$O$_7$. The all-in, all-out…

强关联电子 · 物理学 2015-06-22 Fumiyuki Ishii , Yo Pierre Mizuta , Takehiro Kato , Taisuke Ozaki , Hongming Weng , Shigeki Onoda

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

材料科学 · 物理学 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

The pyroelectric effect in ferroelectric thin films is typically composed of different contributions, which are difficult to disentangle. In addition, clamping to the substrate interface plays an important role. We studied epitaxial…

材料科学 · 物理学 2025-08-26 D. Schmidt , J. Wawra , D. Hensel , M. Brede , R. Hühne , P. Gaal