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Pyrochlore erbium titanate samples in the form of powders (with nominal compositions of Er2Ti2+xO7) and bulk single crystals were prepared to elucidate the effect of synthesis and growth conditions on their composition, structure, and…

材料科学 · 物理学 2018-12-14 Q. Wang , A. Ghasemi , A. Scheie , S. M. Koohpayeh

Epitaxial heterostructures of two-dimensional van der Waals magnets and topological insulators offer a powerful platform for probing interfacial spin interactions that govern magnetic textures in low-dimensional quantum systems, while…

For most applications, zirconia (ZrO2) is doped with yttria. Doping leads to the stabilization of the tetragonal or cubic phase, and increased oxygen ion conductivity. Most previous surface studies of yttria-doped zirconia were plagued by…

材料科学 · 物理学 2020-02-26 Peter Lackner , Amy J. Brandt , Ulrike Diebold , Michael Schmid

We explore the field-temperature phase diagram of the XY pyrochlore antiferromagnet Er$_2$Ti$_2$O$_7$, by means of magnetization and neutron diffraction experiments. Depending on the field strength and direction relative to the high…

We have investigated the effect of synthesis and growth conditions on the magnetic, structural, and compositional properties of pyrochlore oxide holmium titanate and demonstrate a method for growing high quality stoichiometric single…

材料科学 · 物理学 2018-09-26 Alireza Ghasemi , Allen Scheie , Jonas Kindervater , Seyed M. Koohpayeh

The binary fluorite oxide Hf0.5Zr0.5O2 tends to grab a significant amount of notice due to the distinct and superior ferroelectricity found in its metastable phase. Stabilizing the metastable ferroelectric phase and delineating the…

材料科学 · 物理学 2023-07-12 Yufan Shen , Mitsutaka Haruta , I-Ching Lin , Lingling Xie , Daisuke Kan , Yuichi Shimakawa

We present a magnetic phase diagram of rare-earth pyrochlore $\rm{Yb_2Ti_2O_7}$ in a $\langle 111 \rangle$ magnetic field. Using heat capacity, magnetization, and neutron scattering data, we show an unusual field-dependence of a first-order…

We investigate energetically favorable structures of ABO$_2$N oxynitrides as functions of pressure and strain via swarm-intelligence-based structure prediction methods, DFT lattice dynamics and first-principles molecular dynamics. We…

材料科学 · 物理学 2021-06-11 Li Zhu , Hiroyuki Takenaka , R. E. Cohen

We report the epitaxial thin film synthesis of SrCu$_3$O$_4$ with infinitely stacked Cu$_3$O$_4$ layers composed of edge-sharing CuO$_4$ square-planes, using molecular beam epitaxy. Experimental and theoretical characterizations showed that…

The critical impact of epitaxial stress on the stabilization of the ferroelectric orthorhombic phase of hafnia is proved. Epitaxial bilayers of Hf0.5Zr0.5O2 and La0.67Sr0.33MnO3 electrodes were grown on a set of single crystalline oxide…

Nickel oxide (NiO) is a binary compound with a lot of applications in the present technology. NiO thin films were deposited by reactive sputtering magnetron under several voltage biases applied in the glass substrates (0, 50, 100, 200, 300,…

Single crystals of a novel ruthenate, Ca2Ru2O7, were obtained. An X-ray diffraction study on a single crystal revealed that this material crystallizes in a pyrochlore structure with a lattice parameter, a = 10.197 Angstroms. The magnetic…

材料科学 · 物理学 2009-11-11 Taiya Munenaka , Hirohiko Sato

It is shown that both structural phase transitions in Cd2Re2O7, which occur at T_{s1}=200 K and T_{s2}=120 K, are due to an instability of the Re tetrahedral network with respect to the same doubly degenerate long-wavelength phonon mode.…

超导电性 · 物理学 2009-11-10 I. A. Sergienko , S. H. Curnoe

Iron(II) monoxide (FeO) is thermodynamically stable in the halite (w\"ustite) structure only at elevated temperatures in a typically non-stoichiometric, Fe-deficient, Fe$_{1-z}$O form that tends to phase separate and/or transform into…

We have investigated low-temperature crystal structure of BiCh2-based compounds LaO1-xFxBiSSe (x = 0, 0.01, 0.02, 0.03, and 0.5), in which anomalous two-fold-symmetric in-plane anisotropy of superconducting states has been observed for x =…

A2Ir2O7 iridates were proven to crystallise in the geometrically frustrated pyrochlore structure, which remains stable upon rare-earth cation substitution, temperature variation, and external pressure application. However, the change of…

强关联电子 · 物理学 2024-08-05 Daniel Staško , Petr Proschek , Jiří Prchal , Milan Klicpera

Eu2Ir2O7, a candidate Weyl semimetal, shows an insulator-to-metal transition as a function of Bi substitution at the Eu site. In this work, we investigate the (Eu_1-xBi_x)2Ir2O7 series via Hard X-ray Photoemission Spectroscopy (HAXPES),…

强关联电子 · 物理学 2021-01-29 Prachi Telang , Kshiti Mishra , Rabindranath Bag , A. Gloskovskii , Yu. Matveyev , Surjeet Singh

Epitaxial growth of (La$_{1.48}$Nd$_{0.40}$Sr$_{0.12}$)CuO$_4$ thin films was studied by pulsed-laser deposition technique on three different substrates, SrTiO$_3$ (100), LaSrAlO$_4$ (001), and YAlO$_3$ (001). The (Nd,Sr,Ce)$_2$CuO$_4$-type…

超导电性 · 物理学 2016-08-31 I. Tsukada

We have succeeded in growing epitaxial and highly stoichiometric films of EuO on yttria-stabilized cubic zirconia (YSZ) (001). The use of the Eu-distillation process during the molecular beam epitaxy assisted growth enables the consistent…

Frustrated rare-earth pyrochlore titanates, Yb$_2$Ti$_2$O$_7$, and Tb$_2$Ti$_2$O$_7$ have been proposed as promising candidates to realize quantum spin ice (QSI). Multiple exotic quantum phases, including Coulombic ferromagnet, quantum…

强关联电子 · 物理学 2021-01-12 Fangdi Wen , Tsung-Chi Wu , Xiaoran Liu , Michael Terilli , Mikhail Kareev , Jak Chakhalian