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We achieve, at room temperature, conductance enhancements over two orders of magnitude in single molecule circuits formed with polycyclic benzoquinoidal (BQn) diradicals upon increasing molecular length by ~0.5 nm. We find that this extreme…

介观与纳米尺度物理 · 物理学 2024-03-11 Brent Lawson , Efrain Vidal , Michael M. Haley , Maria Kamenetska

We present a detailed study of the conduction properties of a molecular wire where hopping processes between electronic sites are coupled to a vibrational mode of the molecule. The latter is sandwiched between two electronic leads at finite…

介观与纳米尺度物理 · 物理学 2017-05-24 Simon Pigeon , Lorenzo Fusco , Gabriele De Chiara , Mauro Paternostro

Semi-crystalline polymers have been shown to have greatly increased thermal conductivity compared to amorphous bulk polymers due to effective heat conduction along the covalent bonds of the backbone. However, the mechanisms governing the…

介观与纳米尺度物理 · 物理学 2015-12-09 Andrew B. Robbins , Austin J. Minnich

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

A qualitative model describing the "anomalous" features of the conductivity of polymer nanocomposites, in particular, switching to the conducting state in relatively thick (tens of microns or more) of flexible PVC films is considered. In…

软凝聚态物质 · 物理学 2013-02-26 D. V. Vlasov , L. A. Apresyan

We present and analyze a method where parametric (two-photon) driving of a cavity is used to exponentially enhance the light-matter coupling in a generic cavity QED setup, with time-dependent control. Our method allows one to enhance…

量子物理 · 物理学 2018-03-07 C. Leroux , L. C. G. Govia , A. A. Clerk

Amorphous polymers are known as thermal insulators, increasing their thermal conductivities have not been guided by fully understood physics. In this work, we use molecular dynamics simulations to study the thermal transport mechanism of…

软凝聚态物质 · 物理学 2019-04-03 Xingfei Wei , Tengfei Luo

We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we…

介观与纳米尺度物理 · 物理学 2015-05-27 A. Ueda , O. Entin-Wohlman , A. Aharony

Conventional and unconventional superconductivity, respectively, arise from attractive (electron-phonon) and repulsive (many-body Coulomb) interactions with fixed-sign and sign-reversal pairing symmetries. Although heavy-fermions, cuprates,…

超导电性 · 物理学 2019-12-11 Priyo Adhikary , Tanmoy Das

We experimentally demonstrate magnon-polaritons with ultrastrong coupling and directional nonreciprocity in a metamolecule lacking time-reversal and space-inversion symmetries at room temperature. These experimental results are reproduced…

When interacting electrons are confined to low-dimensions, the electron-electron correlation effect is enhanced dramatically, which often drives the system into exhibiting behaviors that are otherwise highly improbable. Superconductivity…

Thermal conductivity of aligned polymer molecules can be exceptionally high along the alignment direction due to energy transport through strong covalent bonds. At the same time, it is highly sensitive to molecular conformation, varying by…

化学物理 · 物理学 2026-04-29 Igor V. Parshin , Igor V. Rubtsov , Alexander L. Burin

Unconventional superconductivity arising from electron-electron interaction can manifest exotic symmetry and topological properties. We investigate the superconducting pairing symmetry problem based on the 3D cubic $O_h$ symmetry with both…

超导电性 · 物理学 2025-06-19 Zhiming Pan , Chen Lu , Fan Yang , Congjun Wu

Laser control of solids was so far mainly discussed in the context of strong classical nonlinear light-matter coupling in a pump-probe framework. Here we propose a quantum-electrodynamical setting to address the coupling of a…

超导电性 · 物理学 2018-07-02 Michael A. Sentef , Michael Ruggenthaler , Angel Rubio

Recently a variety of $\pi$-conjugated polymers have been developed and essayed for a number of applications such as organic light-emitting diodes, organic field-effect transistors, organic photovoltaics, and sensors. Is central for these…

介观与纳米尺度物理 · 物理学 2020-04-27 Miguel Lagos

Strong coupling between a single quantum emitter and an electromagnetic mode is one of the key effects in quantum optics. In the cavity QED approach to plasmonics, strongly coupled systems are usually understood as single-transition…

We consider Kohn-Luttinger mechanism for superconductivity in a two-dimensional electron gas confined to a narrow well between two metallic planes with two occupied subbands with Fermi momenta $k_{FL} > k_{FS}$. On the basis of a…

超导电性 · 物理学 2017-11-22 Andrey V Chubukov , Steven A. Kivelson

Collective strong coupling between a disordered ensemble of $N$ localized molecular vibrations and a resonant optical cavity mode gives rise to 2 polariton and $N-1\gg2$ dark modes. Thus, experimental changes in thermally-activated reaction…

量子物理 · 物理学 2022-03-14 Matthew Du , Joel Yuen-Zhou

Hybrid ionic-electronic conductors have the potential to generate memory effects and neuronal behavior. The functionality of these mixed materials depends on ion motion through thin polarizable channels. Here, we explore different…

Nonlinear optical excitation of infrared active lattice vibrations has been shown to melt magnetic or orbital orders and to transform insulators into metals. In cuprates, this technique has been used to remove charge stripes and promote…

超导电性 · 物理学 2014-09-03 W. Hu , S. Kaiser , D. Nicoletti , C. R. Hunt , I. Gierz , M. C. Hoffmann , M. Le Tacon , T. Loew , B. Keimer , A. Cavalleri