相关论文: Circular Dichroism of Crystals from First Principl…
Circular dichroism (CD) is in widespread use as a means of determining enantiomeric excess. We show how slow-light phenomena in dispersive structured media allow for a reduction in the required optical path length of an order of magnitude.…
We analyze circular dichroism (CD) in resonant inelastic x-ray scattering (RIXS) in magnetic materials. We define RIXS-CD as the difference between scattering amplitudes for the right- and left-circularly polarized incoming photons and…
Chirality is a structural property of molecules lacking mirror symmetry that has strong implications in diverse fields, ranging from life to materials sciences. Established spectroscopic methods that are sensitive to chirality, such as…
Chirality, a fundamental concept describing an object cannot superpose with its mirror image, is crucial in optics and photonics and leads to various exotic phenomena, such as circular dichroism, and optical activity. Recent findings reveal…
In this Letter, we predict a structural phase transition unique to chiral crystals with screw symmetry. In chiral crystals, the phonon frequency renormalized by the electron-phonon coupling depends on the handedness of circular…
Molecular chirality plays a crucial role in innumerable biological processes. The chirality of a molecule can typically be identified by its characteristic optical response, the circular dichroism (CD). CD signals have thus long been used…
Molecular Circular dichroism (CD) spectroscopy faces significant limitations due to the inherent weakness of chiroptical light-matter interactions. In this view, resonant optical antennas constitute a promising solution to this problem…
The Chirality-Induced Spin Selectivity (CISS) effect describes the ability of chiral molecules and crystals to transmit spin-polarized currents, a phenomenon first identified in 1999. Although this effect holds great promise for a broad…
Broken symmetry plays a pivotal role in determining the macroscopic electrical, optical, magnetic, and topological properties of materials. Circular dichroism (CD) has been widely employed to probe broken symmetry in various systems, from…
We study the spin-dependent electronic structure of UTe and UT_{2}Si_{2} (T=Cu and Mn) compounds with a combination of x-ray magnetic circular dichroism measurements and first principle calculations. By exploiting the presence of sizable…
Circular dichroism (CD) spectroscopy is a useful technique for characterizing chiral molecules. It is more sensitive than total absorption to molecule conformation, and it is routinely used to identify enantiomers. We present here a first…
The chirality-induced spin selectivity (CISS) effect has garnered significant interest in the field of molecular spintronics due to its potential for creating spin-polarized electrons without the need for a magnet. Recent studies devoted to…
Resonant X-ray diffraction (RXD) provides a unique capability to investigate electronically ordered states in matter. Importantly, circular dichroism in RXD can determine the absolute chirality formed by anisotropic multipole arrangement.…
Chiral phonons offer a route to transfer angular momentum without relying on magnetic order, but their electronic response in metals remains poorly understood from perspectives beyond spin-based scenarios. Using first-principles…
Circular dichroism (CD), arising from spin-selective light-matter interactions controlled by chirality, is critical for advanced applications such as chiral imaging and ultrasensitive biosensing. However, CD of chiral natural materials is…
Chirality-induced spin selectivity is a spin-splitting phenomenon from a helical structure with a considerably effective spin-orbit coupling. This unexpectedly large spin-splitting phenomenon has been experimentally observed in chiral…
Spintronic devices typically employ heterostructures with ferromagnets which break time-reversal symmetry and have non-vanishing magnetization. With the growing class of materials that support spin-polarized carriers, current, and…
We demonstrate theoretically that non-chiral perovskite layers can exhibit circular dichroism (CD) in the absence of a magnetic field and without chiral activation by chiral molecules. The effect is shown to be due to splitting of helical…
We derive here a new highly selective photoelectron-based chirality-sensing technique that utilizes 'locally-chiral' laser pulses. We show that this approach results in strong chiral discrimination, where the standard forwards/backwards…
Optical activity is a fundamental phenomenon originating from the chiral nature of crystals and molecules. While intrinsic chiroptical responses of ordinary chiral materials to circularly polarized light are relatively weak, they can be…