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We study the thickness dependence of the electronic, magnetic, and optical properties of a NiPS$_3$ thin film, an antiferromagnetic charge-transfer insulator. Utilizing state-of-the-art advanced density functionals, we find the…

强关联电子 · 物理学 2020-08-26 Christopher Lane , Jian-Xin Zhu

Two-dimensional antiferromagnetism has long attracted significant interest in many areas of condensed matter physics, but only recently has experimental exploration become feasible due to the isolation of van der Waals antiferromagnetic…

介观与纳米尺度物理 · 物理学 2025-11-21 Cheol-Yeon Cheon , Volodymyr Multian , Kenji Watanabe , Takashi Taniguchi , Alberto F. Morpurgo , Dmitry Lebedev

Compounds with two-dimensional (2D) layers of magnetic ions weakly connected by van der Waals bonding offer routes to enhance quantum behavior, stimulating both fundamental and applied interest. CrPS4 is one such magnetic van der Waals…

强关联电子 · 物理学 2020-07-07 S. Calder , A. V. Haglund , Y. Liu , D. M. Pajerowski , H. B. Cao , T. J. Williams , V. O. Garlea , D. Mandrus

Single layers of transition-metal thiophosphates (2D-TMPS$_{3}$) van der Waals magnets are an ideal platform for studying antiferromagnetic interactions in two dimensions. However, the magnetic coupling mechanism between two or more…

材料科学 · 物理学 2024-10-18 Andrea León , Beatriz Costa , Thomas Heine , Thomas Brumme

The electronic structure of high-quality van der Waals NiPS$_3$ crystals was studied using near-edge x-ray absorption spectroscopy (NEXAFS) and resonant photoelectron spectroscopy (ResPES) in combination with density functional theory (DFT)…

In the rich phases of van der Waals (vdW) materials featuring intertwined electronic order and collective phenomena, characterizing elementary dynamics that entail the low-energy Hamiltonian and electronic degrees of freedom is of paramount…

Strong charge-spin coupling is found in a layered transition-metal trichalcogenide NiPS3, a van derWaals antiferromagnet, from our study of the electronic structure using several experimental and theoretical tools: spectroscopic…

Two-dimensional antiferromagnets are promising materials for spintronics. The van der Waals antiferromagnet NiPS$_3$ has attracted extensive interest due to its ultra-narrow exciton feature which is closely linked with the magnetic…

强关联电子 · 物理学 2025-04-09 Jacob A. Warshauer , Huyongqing Chen , Qishuo Tan , Jing Tang , Xi Ling , Wanzheng Hu

Neutron spectroscopy measurements have been performed on single crystals of the antiferromagnetic van der Waals compound NiPS$_3$. Linear spin wave theory using a Heisenberg Hamiltonian with single-ion anisotropies has been applied to…

强关联电子 · 物理学 2022-12-19 A. R. Wildes , J. R. Stewart , M. D. Le , R. A. Ewings , K. C. Rule , G. Deng , K. Anand

The recently discovered two-dimensional (2D) van der Waals magnet NiPS$_3$ provides a new route to examine many-body quasiparticles under 2D confinement. Excitons are of particular interest due to their strong coupling to the magnetic…

强关联电子 · 物理学 2022-10-07 Christopher Lane , Jian-Xin Zhu

Exfoliated magnetic 2D materials enable versatile tuning of magnetization, e.g., by gating or providing proximity-induced exchange interaction. However, their electronic band structure after exfoliation has not been probed, most likely due…

This study presents a comprehensive analysis of the band structure in NiPS$_3$, a van der Waals layered antiferromagnet, utilizing high-resolution synchrotron-based angle-resolved photoemission spectroscopy (ARPES) and corroborative density…

Magnetic interactions are thought to play a key role in the properties of many unconventional superconductors, including cuprates, iron pnictides, and square-planar nickelates. Superconductivity was also recently observed in the bilayer and…

Magnetic van der Waals (vdW) materials have opened new frontiers for realizing novel many-body phenomena. Recently NiPS3 has received intense interest since it hosts an excitonic quasiparticle whose properties appear to be intimately linked…

Magnetic 2D materials enable novel tuning options of magnetism. As an example, the van der Waals material FePS3, a zigzag-type intralayer antiferromagnet, exhibits very strong magnetoelastic coupling due to the different bond lengths along…

We have performed electrochemical treatment of the van der Waals antiferromagnetic materials FePS$_3$ and NiPS$_3$ with the ionic liquid EMIM-BF$_4$, achieving significant molecular intercalation. Mass analysis of the intercalated…

Two-dimensional van der Waals compounds with magnetic ions on a honeycomb lattice are hosts to a variety of exotic behavior. The magnetic interactions in one such compound, MnPSe$_3$, are investigated with elastic and inelastic neutron…

强关联电子 · 物理学 2021-01-20 S. Calder , A. V. Haglund , A. I. Kolesnikov , D. Mandrus

NiPS3 is an exfoliable van-der-Waals intralayer antiferromagnet with zigzag-type spin arrangement. It is distinct from other TMPS3 (TM: transition metal) materials by optical excitations into a strongly correlated state that is tied to the…

How a certain ground state of complex physical systems emerges, especially in two-dimensional materials, is a fundamental question in condensed-matter physics. A particularly interesting case is systems belonging to the class of XY…

介观与纳米尺度物理 · 物理学 2019-01-31 Kangwon Kim , Soo Yeon Lim , Jae-Ung Lee , Sungmin Lee , Tae Yun Kim , Kisoo Park , Gun Sang Jeon , Cheol-Hwan Park , Je-Geun Park , Hyeonsik Cheong

We present $\mu$-ARPES spectra of the Mott-insulating van der Waals antiferromagnet NiPS$_3$. Signatures of strong correlations -- such as the onset of atomic or atomic-ligand multiplets and spin-orbit-entangled exciton have been observed…

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