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The temperature dependence of the elastic properties of antiferroelectric PbHfO3 was investigated by Brillouin scattering. The two structural phase transitions of antiferroelectric-antiferroelectric-paraelectric phases were clearly…

材料科学 · 物理学 2015-06-18 Jae-Hyeon Ko , Krystian Roleder , Andrzej Majchrowski , Annette Bussmann-Holder

Relaxor ferroelectrics are difficult to study and understand. The experiment shows that at low energy scattering there is an acoustic mode, an optic mode, dynamic quasi-elastic scattering and strictly elastic scattering as well as Bragg…

材料科学 · 物理学 2008-08-29 R. A. Cowley , S. N. Gvasaliya , B. Roessli

We report on a thermal-expansion study of the ferroelectric phase transition in insulating Sr$_{1-x}$Ca$_x$TiO$_3$ ($x=0.009$) and its evolution upon increasing charge-carrier concentration up to $n\simeq 60 \times 10^{19}$cm$^{-3}$.…

The effect of Sr doping in BaTiO3 (BTO) with nominal compositions Ba0.80Sr0.20TiO3 (BSTO) have been explored in its structural, lattice vibration, dielectric, ferroelectric and electrocaloric properties. The temperature dependent dielectric…

材料科学 · 物理学 2020-03-02 Satish Yadav , Mohit Chandra , R. Rawat , Vasant Sathe , A. K. Sinha , Kiran Singh

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

Historically, the soft mode theory of ferroelectric phase transitions has been developed for the high-temperature (paraelectric) phase, where the phonon mode softens upon decreasing the temperature. In the low-temperature ferroelectric…

材料科学 · 物理学 2021-03-19 Luigi Casella , Alessio Zaccone

We have observed a softening of phonons and a structural phase transition in a superconducting Ba0.59K0.41BiO3 (Tc = 31 K) single crystal using elastic and inelastic neutron scattering measurements. The soft phonon occurs for the [111]…

超导电性 · 物理学 2011-07-27 H. J. Kang , Y. S. Lee , J. W. Lynn , S. V. Shiryaev , S. N. Barilo

The electrocaloric effect (ECE) of BaZr$_{x}$Ti$_{1-x}$O$_3$ (BZT) is closely related to the relaxor state transition of the materials. This work presents a systematic study on the ECE and the state transition of the BZT, using a combined…

We report thermal-expansion, lattice-constant, and specific-heat data of the series La_1-xA_xCoO_3 for 0<= x <= 0.30 with A = Ca, Sr, and Ba. For the undoped compound LaCoO_3 the thermal-expansion coefficient alpha(T) exhibits a pronounced…

强关联电子 · 物理学 2015-05-13 M. Kriener , M. Braden , H. Kierspel , D. Senff , O. Zabara , C. Zobel , T. Lorenz

The effects of Co-substitution on Ba(Ni$_{1-x}$Co$_x$)$_2$As$_2$ ($0\leq x\leq 0.251$) single crystals grown out of Pb flux are investigated via transport, magnetic, and thermodynamic measurements. BaNi$_2$As$_2$ exhibits a first order…

Materials undergoing antiferroelectric/ferroelectric (AFE/FE) transitions are studied for possible applications that exploit the large volume, charge and entropy differences between the two states, such as electrocaloric cooling, energy…

The normal ferroelectric to paraelectric phase transition in model ferroelectric materials such as BaTiO3 is typically characterized by a sharp, well-defined dielectric constant peak at a specific transition temperature. However, under…

材料科学 · 物理学 2025-10-17 Prithwiraj Ganguly , Prashant Joshi , Maneesha Puthiyoth , Dilip Sasmal , Somaditya Sen

Clear anomalies in the lattice thermal expansion (deviation from linear variation) and elastic properties (softening of the sound velocity) at the antiferromagnetic-to-paramagnetic transition are observed in the prototypical multiferroic…

Dielectric spectroscopy of $SrTiO_3$ single crystal over a broad range of microwave frequency using quasi $TE_{m,1,1}$ and quasi $TM_{m,1,1}$ modes reveals crystal asymmetry from typical measurement of $Q$-factor, transmission or frequency…

材料科学 · 物理学 2025-05-22 M. A. Hosain , J-M. Le Floch , J. F. Bourhill , J. Krupka , M. E. Tobar

Analysis of kinetic literature suggests several electronic rearrangements above 600K involving O- (subperoxides) in YBa2Cu3Oy. Slow cooling to 260K produces a Tc=50K level with conventional plane and cell volume contracted varieties (P-V-),…

材料科学 · 物理学 2015-12-09 H Oesterreicher

We present measurements of the thermal expansion coefficient alpha of polycrystalline LaFeAsO1-xFx (x <= 0.1). The magnetic and structural transitions of the samples with x <= 0.04 give rise to large anomalies in alpha(T), while the onset…

超导电性 · 物理学 2015-05-13 L. Wang , U. Kohler , N. Leps , A. Kondrat , M. Nale , A. Gasparini , A. de Visser , G. Behr , C. Hess , R. Klingeler , B. Buchner

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

统计力学 · 物理学 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

We review the theory of second--order (ferro--)elastic phase transitions, where the order parameter consists of a certain linear combination of strain tensor components, and the accompanying soft mode is an acoustic phonon. In…

凝聚态物理 · 物理学 2009-10-28 F. Schwabl , U. C. Täuber

We measure the transport properties of mechanically strained single crystals of BaFe$_{2}$(As$_{1-x}$P$_{x}$)$_{2}$ over a wide range of $x$. The N\'eel transition is extremely sensitive to stress and this sensitivity increases as optimal…

超导电性 · 物理学 2015-06-05 H-. H. Kuo , James G. Analytis , J. -H. Chu , R. M. Fernandes , J. Schmalian , I. R. Fisher

In contrast to ordinary ferroelectrics where the temperature, Tm, of the permittivity maximum monotonically increases with bias field, E, in (1-x)PbMg1/3Nb2/3O3-(x)PbTiO3 (0<x<0.35) single crystals, Tm was found to remain constant or…

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