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The motion of a gas-liquid interface along a solid wall is influenced by the capillary forces resulting from the interface's shape and its interaction with the solid, where it forms a dynamic contact angle. Capillary models play a…

The structure of liquid water at ambient conditions is studied in ab initio molecular dynamics simulations using van der Waals (vdW) density-functional theory, i.e. using the new exchange-correlation functionals optPBE-vdW and vdW-DF2.…

An outstanding challenge of theoretical electronic structure is the description of van der Waals (vdW) interactions in molecules and solids. Renewed interest in resolving this is in part motivated by the technological promise of layered…

材料科学 · 物理学 2016-01-20 Luke Shulenburger , Andrew D. Baczewski , Zhen Zhu , Jie Guan , David Tomanek

Graphene monolayers supported on oxide substrates have been demonstrated with superior charge mobility and thermal transport for potential device applications. Morphological corrugation can strongly influence the transport properties of the…

介观与纳米尺度物理 · 物理学 2015-05-18 Zachary H. Aitken , Rui Huang

We show that the usual sum of $R^{-6}$ contributions from elements separated by distance $R$ can give \emph{qualitatively} wrong results for the electromagnetically non-retarded van der Waals interaction between non-overlapping bodies. This…

软凝聚态物质 · 物理学 2009-11-11 John F. Dobson , Angela White , Angel Rubio

Water's ability to autoionize into hydroxide and hydronium ions profoundly influences surface properties, rendering interfaces either basic or acidic. While it is well-established that protons show an affinity to the air-water interface, a…

化学物理 · 物理学 2025-02-05 Xavier R. Advincula , Kara D. Fong , Angelos Michaelides , Christoph Schran

Graphene hydrophobic coatings paved the way towards a new generation of optoelectronic and fluidic devices. Nevertheless, such hydrophobic thin films rely only on graphene non-polar surface, rather than taking advantage of its surface…

In this work the interface system of the van der Waals fluid is investigated by using the density gradient theory incorporated with the mean-field theory. Based on the mean-field dividing interface generated by the Maxwell construction, we…

软凝聚态物质 · 物理学 2023-03-22 Hongqin Liu

X-ray photoelectron spectroscopy of graphene is important both for its characterization and as a model for other carbon materials. Despite great recent interest, the intrinsic photoemission of its single layer has not been unambiguously…

The magnetite/water interface is commonly found in nature and plays a crucial role in various technological applications. However, our understanding of its structural and dynamical properties at the molecular scale remains still limited. In…

Phospholipid monolayers at the air-water interface serve as model systems for various biological interfaces, e.g. lung surfactant layers and outer leaflets of cell membranes. Although the dynamical (viscoelastic) properties of these…

流体动力学 · 物理学 2009-11-19 Siyoung Q. Choi , Todd M. Squires

Van der Waals heterostructures display a rich variety of unique electronic properties. To identify novel transport mechanisms, nonlocal measurements have been widely used, wherein a voltage is measured at contacts placed far away from the…

Atoms deposited on two-dimensional (2D) electronic materials, such as graphene, can exhibit unconventional many-body correlations, not accessible in other settings. All of these are driven by van der Waals forces: between the atoms…

介观与纳米尺度物理 · 物理学 2022-01-13 Adrian Del Maestro , Carlos Wexler , Juan M. Vanegas , Taras Lakoba , Valeri N. Kotov

Computer experiments concerning interactions between a graphite surface and the rigid pyramidal nanoasperity of a friction force microscope tip when it is brought close to and retracted from the graphitic sample are presented. Covalent…

统计力学 · 物理学 2010-10-19 A. V. Khomenko , N. V. Prodanov

We calculate the interaction energy and force between atoms and molecules and single-walled carbon nanotubes described by the Dirac model of graphene. For this purpose the Lifshitz-type formulas adapted for the case of cylindrical geometry…

材料科学 · 物理学 2015-05-30 Yu. V. Churkin , G. L. Klimchitskaya , A. B. Fedortsov , V. A. Yurova

We study an interface-capturing two-phase fluid model in which the interfacial tension is modelled as a volumetric stress. Since these stresses are obtainable from a Van der Waals-Cahn-Hilliard free energy, the model is, to a certain…

comp-gas · 物理学 2008-02-03 B. T. Nadiga , S. Zaleski

Both single layer Ga2O3 (SLGO) and graphene are attractive due to their respective electronic and mechanical properties such as wide bandgap and high electrical conductivity. Bringing them together by using van der Waals force to form a…

材料科学 · 物理学 2022-01-21 Lijie Li

Graphene nanochannels are relevant for their possible applications, as in water purification, and for the challenge of understanding how they change the properties of confined liquids. Here, we use all-atom molecular dynamics simulations to…

软凝聚态物质 · 物理学 2021-03-25 Carles Calero , Giancarlo Franzese

The impact of van der Waals interaction on the electronic structure between a pentacene monolayer and a graphite surface was investigated. Upon cooling the monolayer, newly formed dispersive bands, showing the constant final state nature…

With molecular simulation for water and a tunable hydrophobic substrate, we apply the instantaneous interface construction [A. P. Willard and D. Chandler, J. Phys. Chem. B, 114, 1954 (2010)] to examine the similarity between a water-vapor…

软凝聚态物质 · 物理学 2015-01-21 Adam P. Willard , David Chandler
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