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Spin current generators are critical components for spintronics-based information processing. In this work, we theoretically and computationally investigate the bulk spin photovoltaic (BSPV) effect for creating DC spin current under light…

材料科学 · 物理学 2021-07-20 Haowei Xu , Hua Wang , Jian Zhou , Ju Li

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

介观与纳米尺度物理 · 物理学 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

We compute the shift current bulk photovoltaic effect (BPVE) in bulk BaTiO$_3$ and two-dimensional monochalcogenide SnSe considering quasi-particle corrections and exciton effects. We explore changes in shift current peak position and…

材料科学 · 物理学 2020-01-15 Ruixiang Fei , Liang Z. Tan , Andrew M. Rappe

Recently, atomically thin PdSe$_2$ semiconductors with rare pentagonal Se-Pd-Se monolayers were synthesized and were also found to possess superior properties such as ultrahigh air stability, and high carrier mobility, thus offering a new…

材料科学 · 物理学 2021-09-21 Vijay Kumar Gudelli , Guang-Yu Guo

Converting light into steady currents and spin-currents in two-dimensional (2D) platform is essential for future energy harvesting and spintronics. We show that the giant and modulable bulk photovoltaic effects (BPVEs) can be achieved in…

材料科学 · 物理学 2023-01-10 Liang Liu , Weikang Liu , Bin Cheng , Bin Cui , Jifan Hu

Noncentrosymmetric bulk crystals generate photocurrent without any bias voltage. One of the dominant mechanisms, shift current, comes from a quantum interference of electron wave functions being distinct from classical current caused by…

材料科学 · 物理学 2018-12-17 M. Nakamura , H. Hatada , Y. Kaneko , N. Ogawa , Y. Tokura , M. Kawasaki

The bulk photovoltaic effect that is intimately associated with crystalline symmetry has been extensively studied in various nonmagnetic materials, especially ferroelectrics with a switchable electric polarization. In order to further…

材料科学 · 物理学 2022-12-28 Chunmei Zhang , Ping Guo , Jian Zhou

The bulk photovoltaic (BPV) effect that converts light into electric current is highly sensitive to the system symmetry and its electronic Bloch wavefunction. To create a sizable net electric current, it is necessary to break the…

材料科学 · 物理学 2024-07-08 Chunmei Zhang , Jian Zhou

We employ first-principles calculations to investigate the ferroelectric properties and the bulk photovoltaic effect (BPVE) of antimony sulfur iodide (SbSI). The BPVE enables direct sunlight-to-electricity conversion in homogeneous…

材料科学 · 物理学 2025-06-13 Giuseppe Cuono , Subhadeep Bandyopadhyay , Andrea Droghetti , Silvia Picozzi

Photogalvanic effect (PGE) occurs in materials with non-centrosymmetric structures when irradiated by linearly or circularly polarized light. Here, using non-equilibrium Green's function combined with density functional theory (NEGF-DFT),…

材料科学 · 物理学 2023-05-26 Li-Wen Zhang , Ya-Qing Yang , Jun Chen , Lei Zhang

Broadband, efficient and fast conversion of light to electricity is crucial for sensing and clean energy. Here we reveal the largest observed bulk photo-voltaic effect (BPVE), an intrinsic mechanism predicted to be ultrafast and exceed the…

DC photoelectrical currents can be generated purely as a non-linear effect in uniform media lacking inversion symmetry without the need for a material junction or bias voltages to drive it, in what is termed photogalvanic effect. These…

介观与纳米尺度物理 · 物理学 2016-08-17 F. Hipolito , Thomas G. Pedersen , Vitor M. Pereira

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

材料科学 · 物理学 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

The bulk photovoltaic effect (BPE) leads to the generation of a photocurrent from an asymmetric material. Despite drawing much attention due to its ability to generate photovoltages above the band gap ($E_g$), it is considered a weak effect…

The bulk photovoltaic effect generates intrinsic photocurrents in materials without inversion symmetry. Shift current is one of the bulk photovoltaic phenomena related to the Berry phase of the constituting electronic bands: photo-excited…

材料科学 · 物理学 2020-07-17 Banasree Sadhukhan , Yang Zhang , Rajyavardhan Ray , Jeroen van den Brink

Hybrid halide perovskites exhibit nearly 20% power conversion efficiency, but the origin of their high efficiency is still unknown. Here, we compute the shift current, a dominant mechanism of bulk photovoltaic (PV) effect for ferroelectric…

材料科学 · 物理学 2014-10-14 Fan Zheng , Hiroyuki Takenaka , Fenggong Wang , Nathan Z. Koocher , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) leads to directed photo-currents and photo-voltages in bulk materials. Unlike photo-voltages in p-n junction solar cells that are limited by carrier recombination to values below the bandgap energy of the…

应用物理 · 物理学 2023-03-17 Andreas Pusch , Udo Römer , Dimitrie Culcer , Nicholas J. Ekins-Daukes

The bulk photovoltaic effect provides a fundamental pathway for direct light-to-current conversion in quantum materials. However, these nonlinear currents are often strictly constrained or forbidden by crystal symmetries, hindering their…

介观与纳米尺度物理 · 物理学 2026-05-25 Zhuocheng Lu , Zhuang Qian , Zhichao Guo , Likun Shi , Shi Liu , Hua Wang , Kai Chang

The bulk photovoltaic effect (BPVE) has attracted an increasing interest due to its potential to overcome the efficiency limit of traditional photovoltaics, and much effort has been devoted to understanding its underlying physics. However,…

材料科学 · 物理学 2022-01-05 Zhenbang Dai , Andrew M. Rappe

Bulk photovoltaic (BPV) effect, a second order nonlinear process that generates static current under light irradiation, requires centrosymmetric broken systems as its application platform. In order to realize measurable BPV photocurrent in…

材料科学 · 物理学 2023-01-05 Xingchi Mu , Qianqian Xue , Yan Sun , Jian Zhou