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Strong light-matter coupling in chiral cavities has been proposed as an effective way to selectively interact with an enantiomer that shares the same handedness as the cavity's chiral mode. We show that surface plasmons supported by a…

Separation of the two mirror images of a chiral molecule, the enantiomers, is a historically complicated problem of major relevance for biological systems. Since chiral molecules are optically active, it has been speculated that strong…

化学物理 · 物理学 2024-10-23 Rosario R. Riso , Matteo Castagnola , Enrico Ronca , Henrik Koch

Chirality, the absence of mirror symmetry, is a fundamental molecular property with far-reaching consequences from chemistry to biology. Yet enantiosensitive optical responses are very weak. Here, we introduce a theoretical framework in…

光学 · 物理学 2026-01-12 Yang-Cheng Ye , Panpan Zhang , Ajay Jha , Fulu Zheng , Hong-Guang Duan

Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…

化学物理 · 物理学 2025-03-07 Andrés Ordóñez , Patricia Vindel-Zandbergen , David Ayuso

Spin-dependent, directional light-matter interactions form the basis of chiral quantum networks. In the solid state, quantum emitters commonly possess circularly polarised optical transitions with spin-dependent handedness. We demonstrate…

光学 · 物理学 2022-01-31 D. Hallett , A. P. Foster , D. M. Whittaker , M. S. Skolnick , L. R. Wilson

The development of efficient techniques to distinguish mirror images of chiral molecules (enantiomers) is very important in both chemistry and physics. Enantiomers share most molecular properties except, for instance, the absorption of…

化学物理 · 物理学 2023-07-11 Rosario R. Riso , Laura Grazioli , Enrico Ronca , Tommaso Giovannini , Henrik Koch

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

介观与纳米尺度物理 · 物理学 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

We propose a gain-assisted enantioselective scheme in dye-doped chiral particles, demonstrating optical pulling and pushing forces that can be tuned using externally controllable parameters. By controlling the concentration of dye molecules…

光学 · 物理学 2023-04-20 R. Ali , F. A. Pinheiro , R. S. Dutra , T. P. Mayer Alegre , G. S. Wiederhecker

We demonstrate coherent control over the photoelectron circular dichroism in randomly oriented chiral molecules, based on quantum interference between multiple photoionization pathways. To significantly enhance the chiral signature, we use…

量子物理 · 物理学 2019-01-16 R. Esteban Goetz , Christiane P. Koch , Loren Greenman

Directional radiation and scattering play an essential role in light manipulation for various applications in integrated nanophotonics, antenna and metasurface designs, quantum optics, etc. The most elemental system with this property is…

经典物理 · 物理学 2023-06-21 Yuqiong Cheng , Kayode Adedotun Oyesina , Bo Xue , Dangyuan Lei , Alex M. H. Wong , Shubo Wang

Strong light-matter interactions are gaining importance in controlling the photoswitching behavior of molecules exhibiting bistability. Here, we used the strategy of electronic strong coupling of both the E and Z-isomers of azopyrrole…

The light-matter interaction can be utilized to qualitatively alter physical properties of materials. Recent theoretical and experimental studies have explored this possibility of controlling matter by light based on driving many-body…

介观与纳米尺度物理 · 物理学 2020-11-11 Yuto Ashida , Atac Imamoglu , Jerome Faist , Dieter Jaksch , Andrea Cavalleri , Eugene Demler

Strong dissipation of plasmonic resonances is detrimental to quantum manipulation. To enhance the quantum coherence, we propose to tailor the local density of states (LDOS) of plasmonic resonances by integrating with a photonic cavity…

量子物理 · 物理学 2024-05-24 Yuwei Lu , Haoxiang Jiang , Renming Liu

Exploring the photoinduced dynamics of chiral states offers promising avenues for advanced control of condensed matter systems. Photoinduced or photoenhanced chirality in 1T-TiSe$_{2}$ has been suggested as a fascinating platform for…

We investigate enantiodetection for both a single cyclic three-level chiral molecule and finite ensembles of such molecules by monitoring the steady-state intracavity photon number in a cavity-QED platform. Our scheme exploits the intrinsic…

量子物理 · 物理学 2025-11-14 Xiang Guo , Xiaojun Zhang , Yong Li , Zhihai Wang

We consider a system comprising two groups of quantum dimers placed in a common electromagnetic cavity, and controlled by selectively applying a static external potential to one of the groups. We show that in the regime of deep strong…

介观与纳米尺度物理 · 物理学 2023-08-21 Andrey Kudlis , Denis Novokreschenov , Ivan Iorsh , Ilya Tokatly

Chiral excited electronic states of molecules have an intrinsic sense of handedness, or twist, and are the active component in energy efficient display technologies and in new photosynthetic routes to produce pharmaceuticals. Creating…

The differential response of chiral molecules to incident left- and right- handed circularly polarized light is used for sensing the handedness of molecules. Currently, significant effort is directed towards enhancing weak differential…

Distinguishing between the left- and right-handed versions of a chiral molecule (enantiomers) is vital, but also inherently difficult. Traditional optical methods using elliptically or circularly polarized light rely on weak linear effects…

光学 · 物理学 2022-06-08 Laura Rego , David Ayuso

Chirality describes the asymmetry between an object and its mirror image and manifests itself in diverse functionalities across all scales of matter - from molecules and aggregates to thin films and bulk chiral materials. A particularly…

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