相关论文: Optomechanical Effects in Nanocavity-enhanced Reso…
Vibrational Raman scattering -- a process where light exchanges energy with a molecular vibration through inelastic scattering -- is most fundamentally described in a quantum framework where both light and vibration are quantized. When the…
The interaction between molecules is commonly ignored in surface-enhanced Raman scattering (SERS). Under this assumption, the total SERS signal is described as the sum of the individual contributions of each molecule treated independently.…
Surface-Enhanced Raman Scattering (SERS) allows for detection and identification of molecular vibrational fingerprints in minute sample quantities. The SERS process can be also exploited for optical manipulation of molecular vibrations. We…
Molecular vibrations couple to visible light only weakly, have small mutual interactions, and hence are often ignored for non-linear optics. Here we show the extreme confinement provided by plasmonic nano- and pico-cavities can sufficiently…
We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…
The conventional explanation of plasmon-enhanced Raman scattering attributes the enhancement to the antenna effect focusing the electromagnetic field into sub-wavelength volumes. Here we introduce a new model that additionally accounts for…
Plasmon resonances at the surface of plasmonic antennas allow for extremely strong enhancement of Raman scattering. Intrinsic to plasmonics, however, is that extreme field confinement lacks precise spectral control, which would hold great…
We present a general model study of surface-enhanced resonant Raman scattering and fluorescence, focusing on the interplay between electromagnetic (EM) effects and the molecular dynamics as treated by a density matrix calculation. The model…
In this work we identify coherent electron-vibron interactions between near-resonant and non-resonant electronic levels that contribute beyond standard optomechanical models for off-resonant or resonance SERS. By developing an open-system…
Herein we report experimental evidence of directional SERS from molecules situated inside a single nanowire-nanoparticle junction cavity. The emission was confined to a narrow range of wavevectors perpendicular to the axis of the cavity. In…
We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…
We investigate how proximity to a metal nanostructure, particularly to a flat mirror or a cavity confined between two mirrors, affects the vibronic structure of Raman scattering signals. We find that such proximity, particularly for the…
We report on the experimental observation of beaming elastic and surface enhanced Raman scattering (SERS) emission from a bent-nanowire on a mirror (B-NWoM) cavity. The system was probed with polarization resolved Fourier plane and…
We theoretically investigate the enhancement of surface enhanced Raman spectroscopy (SERS) using hyperbolic stratified nanostructures and compare to metal nanoresonators. The photon Green function of each nanostructure within its…
A mechanism for additional enhancement of SERS in the nanoparticle-on-mirror scheme is proposed. This new mechanism is based on the use of a substrate made of material with a near-minus-one permittivity. The setup involves a plasmonic…
We consider the Molecular Opto-mechanical systems in back-action amplification of single molecule Raman imaging. Surface Enhanced Raman Scattering (SERS) is mapped into the dissipative cavity opto-mechanics system of coupled resonators. We…
Quantum electrodynamics theory of the resonance Raman scattering is developed for an atom in a close proximity to a carbon nanotube. The theory predicts a dramatic enhancement of the Raman intensity in the strong atomic coupling regime to…
Cavity optomechanics aims to establish optical control over vibrations of mechanical systems, to heat, cool or to drive them toward coherent, or nonclassical states. This field was recently extended to include molecular optomechanics, which…
Surface-enhanced Raman spectroscopy (SERS) allows single-molecule detection due to the strong field localization occurring at sharp bends or kinks of the metal-vacuum interface. An important question concerns the limits of the signal…
We present a self-consistent quantum optics approach to calculating the surface enhanced Raman spectrum of molecules coupled to arbitrarily shaped plasmonic systems. Our treatment is intuitive to use and provides fresh analytical insight…