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In this study, we succeeded in synthesizing new antiperovskite phosphides $M$Pd$_3$P ($M$ = Ca, Sr, Ba) and discovered the appearance of a superconducting phase (0.17 $\leq$ $x$ $\leq$ 0.55) in a solid solution (Ca$_{1-x}$Sr$_x$)Pd$_3$P.…

In the recently discovered antiperovskite phosphide (Ca,Sr)Pd$_3$P, centrosymmetric (CS) and non-centrosymmetric (NCS) superconducting phases appear depending on the Sr concentration, and their transition temperatures ($T_\mathrm{c}$)…

Antiperovskites are a promising candidate structure for the exploration of new materials. We discovered an antiperovskite phosphide, LaPd$_{3}$P, following our recent synthesis of $A$Pd$_{3}$P ($A$ = Ca, Sr, Ba). While $A$Pd$_{3}$P and…

Oxides with perovskite-based structures have been known as essential materials for fascinating phenomena such as high-temperature and unconventional superconductivity. Discoveries of these oxide superconductors have driven the science…

Guided by first-principles calculations, we demonstrate superconductivity in the ternary perovskite hydride SrPdH$_{3-x}$, synthesized at low pressure. Structural characterization via neutron diffraction reveals the near-stoichiometric…

Pressure as a clean and efficient tool can bring about unexpected extraordinary physical and chemical properties of matters. The recent discoveries of superconductivity at nearly room temperature in hydrides highlight the power of pressure…

超导电性 · 物理学 2022-08-22 Di Peng , Ren-Shu Wang , Li-Na Zong , Xiao-Jia Chen

Silver-based chalcohalide anti-perovskites (CAP), Ag$_{3}$BC (B = S, Se; C = Cl, Br, I), represent an emerging family of energy materials with intriguing optoelectronic, vibrational and ionic transport properties. However, the structural…

Pressure not only provides a powerful way to tune the crystal structure of transition metal dichalcogenides (TMDCs) but also promotes the discovery of exotic electronic states and intriguing phenomena. Structural transitions from the…

超导电性 · 物理学 2026-01-13 Feng Xiao , Wen Lei , Wei Wang , Carmine Autieri , Xiaojun Zheng , Xing Ming , Jianlin Luo

Since the discovery of high-temperature superconductivity (SC) in quasi-two-dimensional copper oxides, a few layered compounds, which bear similarities to the cuprates, have also been found to host unconventional SC. Our recent observation…

The oxide perovskites are a large family of materials with many important physical properties. Of particular interest has been the fact that this structure type provides an excellent structural framework for the existence of…

Antiperovskites share the same structure as perovskites, but allow completely different chemistries and nominal charge states of anions to be stabilized. This gives rise to many interesting phenomena, including septet superconductivity and…

材料科学 · 物理学 2026-02-09 He Zhu , Turan Birol

We report the discovery of structural phase transitions and superconductivity in the full Heusler compounds $X$Pd$_2$Sn ($X$ = Ti, Zr, Hf), by means of electrical transport, magnetic susceptibility, specific heat and x-ray diffraction…

超导电性 · 物理学 2023-03-07 Hang Su , Feng Du , Rui Li , Shuaishuai Luo , Yuxuan Chen , Jiyong Liu , Ye Chen , Chao Cao , Michael Smidman , Huiqiu Yuan

We report the discovery of a family of ternary platinum phosphides APt3P (A = Ca, Sr and La), which crystallize in an antiperovskite-based structure closely related to that of the heavy fermion superconductor CePt3Si. All three phosphides…

超导电性 · 物理学 2012-05-09 T. Takayama , K. Kuwano , D. Hirai , Y. Katsura , A. Yamamoto , H. Takagi

SrPt3P has recently been reported to exhibit superconductivity with Tc = 8.4 K. To explore its superconducting mechanism, we have performed electron and phonon band calculations based on the density functional theory, and found that the…

超导电性 · 物理学 2013-04-10 Chang-Jong Kang , Kyo-Hoon Ahn , Kwan-Woo Lee , B. I. Min

Bulk single crystals of SrPt3P have been grown for the first time by a self-flux method at 2 GPa and 1500 {\deg}C using the cubic-anvil, high-pressure and high-temperature technique. The grown black crystals were found to have either a…

超导电性 · 物理学 2016-10-11 Nikolai D. Zhigadlo

Discovery of exotic phases of matter from the topologically non-trivial systems not only makes the research on topological materials more interesting but also enriches our understanding of the fascinating physics of such materials.…

Antiperovskite materials are well known for their high thermoelectric performance and gained huge research interest. Here, we report the structural stability and transport properties of Sr$_3$AsN from a precise first-principles study. The…

材料科学 · 物理学 2022-05-10 Enamul Haque , M. Anwar Hossain

SrPt2As2 is a novel arsenide superconductor, which crystallizes in the CaBe2Ge2-type structure as a different polymorphic form of the ThCr2Si2-type structure. SrPt2As2 exhibits a charge-density-wave (CDW) ordering at about 470 K and enters…

超导电性 · 物理学 2010-12-14 Kazutaka Kudo , Yoshihiro Nishikubo , Minoru Nohara

We report the results of our investigation of SrPt3P, a recently discovered strong-coupling superconductor with Tc = 8.4 K, by application of high physical pressure and by chemical doping. We study hole-doped SrPt3P, which was theoretically…

超导电性 · 物理学 2015-05-15 BenMaan I. Jawdat , Bing Lv , Xiyu Zhu , Yuyi Xue , Ching-wu Chu

The recent discovery of superconductivity in hydrogen-rich compounds has garnered significant experimental and theoretical interest because of the record-setting critical temperatures. As the direct observation of the superconducting (SC)…

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