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Measurements of liquid-liquid phase transition temperatures (cloud points) of mixtures of a protein (lysozyme) and a polymer, poly(ethylene glycol) (PEG) show that the addition of low molecular weight PEG stabilizes the mixture whereas high…

软凝聚态物质 · 物理学 2009-11-11 J. Bloustine , T. Virmani , G. M. Thurston , S. Fraden

Using synchrotron radiation with a photon energy of 15 keV, the molecular structure of an adsorbed n-triacontanol layer at the n-hexadecane - water interface in different its phase states has been studied by the method of diffuse X-ray…

软凝聚态物质 · 物理学 2018-01-16 Aleksey M. Tikhonov

Using molecular dynamics simulations, we investigate the relation between the dynamic transitions of biomolecules (lysozyme and DNA) and the dynamic and thermodynamic properties of hydration water. We find that the dynamic transition of the…

软凝聚态物质 · 物理学 2009-11-11 P. Kumar , Z. Yan , L. Xu , M. G. Mazza , S. V. Buldyrev , S. -H. Chen , S. Sastry , H. E. Stanley

We introduce a new dynamic light scattering method, termed photon correlation imaging, which enables us to resolve the dynamics of soft matter in space and time. We demonstrate photon correlation imaging by investigating the slow dynamics…

软凝聚态物质 · 物理学 2009-03-02 Agnes Duri , David A. Sessoms , Veronique Trappe , Luca Cipelletti

We have developed a new technique to measure viscoelasticity in soft materials such as polymer solutions, by monitoring thermal fluctuations of embedded probe particles using laser interferometry in a microscope. Interferometry allows us to…

软凝聚态物质 · 物理学 2009-10-30 B. Schnurr , F. Gittes , F. C. MacKintosh , C. F. Schmidt

Machine learning (ML) methods provide advanced means for understanding inherent patterns within large and complex datasets. Here, we employ the principal component analysis (PCA) and the diffusion map (DM) techniques to evaluate the glass…

软凝聚态物质 · 物理学 2024-07-01 Artem Glova , Mikko Karttunen

Significant progress has been made in recent years in understanding the dynamics of pure hydrogen-bonded systems by analyzing the spectral shape of various susceptibilities. Monohydroxy- and polyalcohols are currently considered to form…

软凝聚态物质 · 物理学 2025-11-11 Jan Philipp Gabriel

Enthalpic interactions at the interface between nanoparticles and matrix polymers is known to influence various properties of the resultant polymer nanocomposites (PNC). For athermal PNCs, consisting of grafted nanoparticles embedded in…

Immediately before adsorption to a horizontal substrate, sinking polymer-coated colloids can undergo a complex sequence of landing, jumping, crawling and rolling events. Using video tracking we studied the soft adhesion to a horizontal flat…

软凝聚态物质 · 物理学 2018-01-24 Giuseppe Boniello , Christophe Tribet , Emmanuelle Marie , Vincent Croquette , Dražen Zanchi

Observations are reported in isothermal torsional oscillation tests on melts of isotactic polypropylene (iPP) and low-density polyethylene (LDPE) in the intervals of temperature between 190 and 250C (iPP) and between 120 and 190C (LDPE).…

材料科学 · 物理学 2007-05-23 A. D. Drozdov , S. Agarwal , R. K. Gupta

To test basic assumptions inherent to most theories of molecular liquids and glasses, Infrared spectroscopy is carried out on short polyalcohols at temperatures ranging from far above to far below their glass transition. By analyzing…

材料科学 · 物理学 2021-01-14 Jan Philipp Gabriel , Martin Tress , Wilhelm Kossack , Ludwig Popp , Friedrich Kremer

Poly(vinyl alcohol)/Poly(vinylidene fluoride) blends at mass ratio 3:1 with Nano - Graphene Platelet fillers constitute mechanically and thermally stable systems, which are used for developing piezoelectric devices. Blends host a fraction…

化学物理 · 物理学 2025-05-07 Eirini Kolonelou , Anthony N. Papathanassiou

Colloidal particles with appropriate wetting properties can become very strongly trapped at an interface between two immiscible fluids. We have harnessed this phenomenon to create a new class of soft materials with intriguing and…

软凝聚态物质 · 物理学 2009-11-13 K. A. White , A. B. Schofield , B. P. Binks , P. S. Clegg

Molecular dynamics simulations of SPC/E water confined in a Silica pore are presented. The simulations have been performed at different hydration levels and temperatures to study the single-particle dynamics. Due to the confinement and to…

软凝聚态物质 · 物理学 2017-08-23 Paola Gallo

Using non-contact scanning probe microscopy (SPM) techniques, dielectric properties were studied on 50 nanometer length scales in poly-vinyl-acetate (PVAc) films in the vicinity of the glass transition. Low frequency (1/f) noise observed in…

无序系统与神经网络 · 物理学 2009-10-31 E. Vidal Russell , N. E. Israeloff , L. E. Walther , H. Alvarez Gomariz

We describe the design of micropatterned surfaces for single cell studies, based on thermoresponsive polymer brushes. We show that brushes made of poly(N-isopropylacrylamide) grafted at high surface density display excellent protein and…

软凝聚态物质 · 物理学 2012-06-04 Kalpana Mandal , Martial Balland , Lionel Bureau

The average scattered intensity is determined by the optical characteristics of particles in dispersion. The normalized time auto-correlation function of the scattered light intensity $g^{(2)}(\tau) $ includes both the optical and…

化学物理 · 物理学 2007-05-23 Yong Sun

Living and engineered systems rely on the stable coexistence of two interspersed liquid phases. Yet surface tension drives their complete separation. Here we show that stable droplets of uniform and tuneable size can be produced through…

Electronic polarization and charge transfer effects play a crucial role in thermodynamic, structural and transport properties of room-temperature ionic liquids (RTILs). These non-additive interactions constitute a useful tool for tuning…

材料科学 · 物理学 2014-09-09 Vitaly V. Chaban , Oleg V. Prezhdo

We study swelling and structural properties of ionic microgel suspensions within a comprehensive coarse-grained model that combines the polymeric and colloidal natures of microgels as permeable, compressible, charged spheres governed by…

软凝聚态物质 · 物理学 2018-06-07 Tyler J. Weyer , Alan R. Denton