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Perovskite solar cells (PSCs) offer an efficient, inexpensive alternative to current photovoltaic technologies, with the potential for manufacture via high-throughput coating methods. However, challenges for commercial-scale…

The establishment of a rigorous theory on thermodynamics of light management in photovoltaics that accommodates various loss mechanisms as well as wave-optical effects in the absorption and reemission of light is at stake in this…

The low efficiency of metal halide perovskite light-emitting diodes (PeLEDs) with blue emission block their potential applications in large-area full-color displays and solid-state lighting. A delicate control over the entire…

应用物理 · 物理学 2020-12-08 Hai-Yan Wu , Yang Shen , Yan-Qing Li , Kong-Chao Shen , Jian-Xin Tang

Organic-inorganic halide perovskites recently have emerged as a promising material for highly effective light-emitting diodes (LEDs) and solar cells (SCs). Despite efficiencies of both perovskite SCs and LEDs are already among the best, the…

Operational stability of perovskite solar cells is remarkably influenced by the device temperature, therefore, decreasing the interior temperature of the device is one of the most effective approaches to prolong the service life. Herein, we…

Perovskite solar cells employing self assembled monolayers such as Me-4PACz as hole transport layer has been reported to demonstrate high device efficiency. However, the poor perovskite wetting on the Me-4PACz caused by poor perovskite ink…

The ideality factor determined by measuring the open circuit voltage (VOC) as function of light intensity is often used as a means to identify the dominant recombination mechanism in solar cells. However, applying this Suns-VOC technique to…

Transition metal perovskite chalcogenides (TMPC) are a new class of semiconductor materials with broad tunability of physical properties due to their chemical and structural flexibility. Theoretical calculations show that band gaps of TMPCs…

Two-dimensional (2D) halide perovskites (HPs) are promising materials for various optoelectronic applications, yet a comprehensive understanding of their dynamics is still elusive. Here, we offer insight into the dynamics of prototypical 2D…

材料科学 · 物理学 2024-08-15 Erik Fransson , Julia Wiktor , Paul Erhart

We present a novel analytical model for analysing the spectral photoluminescence quantum yield of non-planar semiconductor thin films. This model considers the escape probability of luminescence and is applied to triple-cation perovskite…

The stability of perovskite solar cells is closely related to the defects in perovskite crystals, and there are a large number of crystal defects in the perovskite thin films prepared by the solution method, which is not conducive to the…

材料科学 · 物理学 2024-05-03 Xianhu Wu , Jieyu Bi , Guanglei Cui , Nian Liu , Gaojie Xia , Ping Li , Chunyi Zhao , Zewen Zuo , Min Gu

One effective way to prevent toxicity and improve the stability of materials for photovoltaic applications is to exclude lead and organic molecules from perovskite materials. Specifically, the CsSn1-xGexI3 appears to be a promising…

Perovskite-silicon tandem solar cells are currently one of the most investigated concepts to overcome the theoretical limit for the power conversion efficiency of silicon solar cells. For monolithic tandem solar cells the available light…

The extraction of photogenerated charge carriers and the generation of a photovoltage belong to the fundamental functionalities of any solar cell. These processes happen not instantaneously but rather come with finite time constants, e.g.,…

材料科学 · 物理学 2023-02-08 Lisa Krückemeier , Zhifa Liu , Thomas Kirchartz , Uwe Rau

Lead (Pb) halide perovskites have achieved great success in recent years due to their excellent optoelectronic properties, which is largely attributed to the lone-pair s orbital-derived antibonding states at the valence band edge. Guided by…

材料科学 · 物理学 2021-05-07 Gang Tang , Philippe Ghosez , Jiawang Hong

Organic-inorganic halide perovskite solar cells have recently attracted much attention due to their low-cost fabrication, flexibility, and high-power conversion efficiency. The reduction from three- to two-dimension (2D) promises an…

材料科学 · 物理学 2018-07-24 Rahul Singh , Prashant Singh , Ganesh Balasubramanian

Understanding and controlling charge carrier recombination dynamics is essential for enhancing the performance of metal halide perovskite optoelectronic devices. In this study, we present a machine learning-assisted intensity-modulated…

化学物理 · 物理学 2025-04-30 Qi Shi , Tönu Pullerits

Design and modification of the interfaces, always a critical issue for semiconductor devices, has become the primary tool to harness the full potential of halide perovskite (HaP)-based ones. In particular the outstanding improvements in HaP…

应用物理 · 物理学 2018-12-13 Philip Schulz , David Cahen , Antoine Kahn

The use of mixed cation absorber composition was considered as an efficient strategy to mitigate the degradation effects in halide perovskite solar cells. Despite the reports about partial stabilization at elevated temperatures, unfavorable…

We demonstrate four and two-terminal perovskite-perovskite tandem solar cells with ideally matched bandgaps. We develop an infrared absorbing 1.2eV bandgap perovskite, $FA_{0.75}Cs_{0.25}Sn_{0.5}Pb_{0.5}I_3$, that can deliver 14.8 %…