相关论文: Fevering Interstellar Ices Have More CH3OD

Deuterium enrichment of interstellar methanol is reproduced experimentally for the first time via grain-surface H-D substitution in solid methanol at an atomic D/H ratio of 0.1. Although previous gas-grain models successfully reproduce the…

We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…

Context. The spatial distribution of molecules around starless cores is a powerful tool for studying the physics and chemistry governing the earliest stages of star formation. Aims. Our aim is to study the chemical differentiation in…

Low-mass protostars are the extrasolar analogues of the natal Solar System. Sophisticated physicochemical models are used to simulate the formation of two protoplanetary discs from the initial prestellar phase, one dominated by viscous…

High-mass stars are expected to form from dense prestellar cores. Their precise formation conditions are widely discussed, including their virial condition, which results in slow collapse for super-virial cores with strong support by…

Studies of deuterated isotopologues of complex organic molecules can provide important constraints on their origin in regions of star formation. In particular, the abundances of deuterated species are very sensitive to the physical…

Aim: In the past, observations of protostellar shocks have been able to set constraints on the formation route of formamide (NH2CHO), exploiting its observed spatial distribution and comparison with astrochemical model predictions. In this…

Recent interferometer observations have found that the D2O/HDO abundance ratio is higher than that of HDO/H2O by about one order of magnitude in the vicinity of low-mass protostar NGC 1333-IRAS 2A, where water ice has sublimated. Previous…

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Water is detected in environments representing every stage of star and solar system formation, but its chemical evolution throughout these stages remains poorly constrained. Deuterium ratios offer a means of probing chemical links between…

Quantifying the composition of the material in protoplanetary disks is paramount to determining the potential for exoplanetary systems to produce and support habitable environments. A key complex organic molecule (COM) to detect is methanol…

[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…

Column density ratios of complex organic molecules are generally constant across protostellar systems with some low-level scatter. However, the scatter in formamide (NH$_2$CHO) to methanol (CH$_3$OH) column density ratio is one of the…

Rate constants for the C(3P) + CH3OH reaction have been measured in a continuous supersonic flow reactor over the range 50 K to 296 K. C(3P) was created by the in-situ pulsed laser photolysis of CBr4, a multiphoton process which also…

We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…

Methanol (CH$_3$OH) is found to be abundant and widespread towards the Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin is, however, not fully understood. It was proposed that the high cosmic ray ionisation…

Methanol is a common component of interstellar and circumstellar ice mantles and is often used as an evolution indicator in star-forming regions. The observations of gas-phase methanol in the interiors of dense molecular clouds at…

Observational studies reveal that complex organic molecules (COMs) can be found in various objects associated with different star formation stages. The identification of COMs in prestellar cores, i.e., cold environments in which thermally…

The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history.…

During the formation of stars, the accretion of the surrounding material toward the central object is thought to undergo strong luminosity outbursts, followed by long periods of relative quiescence, even at the early stages of star…