相关论文: Polar magnetism and chemical bond in alpha-RuCl3
Compulsory Dirac multipoles in the bilayer perovskite Ca3Ru2O7 are absent in published analyses of experimental data. In a first step at correcting knowledge of the magnetic structure, we have analysed existing Bragg diffraction patterns…
The magnetic structure of RuO2 and the Ru atomic configuration are unknown. A magnetic structure is inferred by confronting measured and calculated Bragg diffraction patterns and adjusting the latter to achieve satisfactory agreement. An…
Rutile-type RuO2 likely supports a simple antiferromagnetic structure which can be verified by x-ray Bragg diffraction. Three magnetic motifs that do not break translation symmetry are explored in calculations of amplitudes suitable for…
Polarized neutron scattering experiments reveal the anisotropy of magnetic correlations in the candidate Kitaev material $\alpha$-RuCl$_3$. The anisotropy of the inelastic response at the magnetic Bragg positions is just opposite to the…
Defects are crucial in determining a variety of material properties especially in low dimensions. In this work, we study point defects in monolayer alpha-phase Ruthenium (III) chloride (alpha-RuCl3), a promising candidate to realize quantum…
Cerium electronic multipoles in trigonal symmetry viewed in magnetic neutron diffraction are investigated. Analytic expressions for all the magnetic multipoles, and radial integrals calculated with an established atomic code, are used to…
Chlorine covalently bonded to an open shell metal is present in many materials with desirable or intriguing physical properties. Materials include highly luminescent nontoxic alternatives to lead halide perovskites for optoelectronic…
$\alpha$-RuCl$_3$ is a candidate Kitaev material that exhibits zigzag antiferromagnetic ordering below 7 K. One contentious issue regarding this material is its bulk structure in the low-temperature phase. Recently, it has become generally…
Experimental techniques using Bragg diffraction may elucidate electronic and magnetic properties of ferric ions in multiferroic ScFeO3 that are puzzling. A collinear magnetic motif of dipole moments is not expected for s-state ions with an…
We submit that the magnetic space-group Cac (#9.41) is consistent with the established magnetic structure of BaFe2Se3, with magnetic dipole moments in a motif that uses two ladders [Caron J M et al 2011 Phys. Rev. B 84 180409(R)]. The…
The magnetic properties of materials hosting Eu2+(J = 7/2, 4f7) ions have attracted much attention in the science of strongly correlated electrons. In part because crystal electric field effects are impoverished for an s-state ion, as with…
The Mott insulator $\alpha$-RuCl$_3$ has generated great interest in the community due to its possible field-induced Kitaev quantum spin liquid state. Despite enormous effort spent trying to obtain the form of the low energy Hamiltonian,…
Uranium ions in sesquinitride alpha-U2N3 occupy independent acentric and centrosymmetric sites according to conventional x-ray diffraction patterns [R. Tro\'c, J. Solid State Chem. 13, 14 (1975)]. We submit that polar uranium multipoles in…
Magnetic axial and polar (Dirac) nickel multipoles contribute to resonant x-ray Bragg amplitudes in a symmetry informed analysis of monoclinic Li2Ni3P4O14 presented for future diffraction experiments. Magnetic long-range order below a…
Magnetic diffraction of polarized neutrons by the cubic Laves compound UAl2 in a magnetic field has unveiled weak Bragg spots that are nominally forbidden. On the one hand, they can be viewed as magnetic analogues of the basis-forbidden (2,…
{\alpha}-phase Ruthenium (III) chloride ({\alpha}-RuCl3) has attracted significant attention because of its potential for realizing Kitaev quantum spin liquid. In this work, we employ first-principles many-body perturbation theory to study…
Magnetization and high-resolution x-ray diffraction measurements of the Kitaev-Heisenberg material alpha-RuCl3 reveal a pressure-induced crystallographic and magnetic phase transition at a hydrostatic pressure of p=0.2 GPa. This structural…
We report a comparative neutron single crystal diffraction study of the structural and magnetic properties of layered halides CrCl$_3$ and $\alpha$-RuCl$_3$, which host a honeycomb arrangement of transition metal ions with distinct…
Magnetic dilution of a well-established Kitaev candidate system is realized in the substitutional Ru$_{1-x}$Rh$_x$Cl$_3$ series ($x = 0.02-0.6$). Optimized syntheses protocols yield uniformly-doped single crystals and polycrystalline…
The Landau free-energy of a compound that benefits from a linear coupling of an electric field and a magnetic field includes a product of the two fields, one polar and time-even and one axial and time-odd. In ME compounds, expectation…